采用注视控制器实现复杂运动的仿真

注视控制器是3DS MAX软件的众多控件之一，它能使多个物体彼此间产生运动约束。通过使用注视控制器功能，笔者成功制作出八足爬壁式仿生机械昆虫的运动场景动画，并使该仿生机械昆虫各足的行走动作符合机械零件作平面复杂运动时所应遵守的正确运动规律。由此证明，3DS MAX软件注视控制器对正确模拟特殊机械装置的复杂运动可产生极大作用。     

含钡合金在钢液中的脱氧行为研究

在MoSi2炉上采用MgO质坩蜗对钢管进行了含钡合金脱氧行为的研究。实验中钡系合金主要选取SiAUBa、SiCaBa、SiAlBaCa、SiAlBeCaSr及用于钙处理的SiCa包芯线，选用Al作为对比脱氧剂，考察了钡系合金脱氧的全氧含量，脱氧产物的分布、尺寸和形貌，探讨了钡系合金脱氧和对夹杂物变性作用的机理。     

微波介质谐振器介电参数的测量

本文讨论了微波介质谐振器介电参数测试技术。用研制的测试装置对多个介质样品进行了实测，结果表明，本文的分析与实际值是吻合的。该测试技术可对微波介质谐振器的复介电常数进行迅速、准确、可靠、宽频带、无损伤、自动化和批量检测，具有较强的实用性。     

地震复合波地质属性的研究方法

在地震资料解释中,地震复合波的地质属性问题一直没有得到很好地解决。本文针对松辽盆地砂泥岩薄互层的地质特点,提出了用波形合成追踪法研究地震复合波地质属性的方法。该方法在地震复合波正演合成过程中有五个可以识别的特征界面,其中 C 界面是地震复合波形成的主导界面;C 至 D 界面间的地层为形成地震复合波的主要地层。因此,找准 C 界面深度是建立地震复合波与钻孔地层间有机联系的关键,对地震地质层位准确标定和利用地震剖面复合波波形信息进行岩性预测极为重要。文中的应用实例表明,用该方法在松辽盆地较好地建立了地震信息与地质信息间的对应关系,解决了一些疑难地质问题,取得了较好的勘探效果。     

Epoxidation of olefines with PDMS membranes containing zeolite occluded manganese diimine complexes

A new composite catalyst for selective epoxidation of olefins with tert-butyl hydroperoxide (tBHP) is reported. The catalyst contains manganese diimine complexes (cis-Mn bis-2,2′-Bipyridyl), occluded within a NaY zeolite, in turn incorporated in a polydimethylsiloxane membrane (cis-[Mn(bpy)₂]²⁺-NaY-PDMS). The three-step synthesis consists of a Mn²⁺exchange of NaY, ligand sorption to form cis-[Mn(bpy)₂]²⁺-NaY and incorporation of the latter in a PDMS membrane. The major differences between [Mn(bpy)₂]²⁺-NaY as such and occluded in PDMS are observed in the sorption and catalytic characteristics. With the membrane system, the use of a solvent becomes obsolete. Whereas optimal cyclohexene oxidation with [Mn(bpy)₂]²⁺-NaY occurs with hydrogen peroxide in acetone, tBuOOH proves to be a better oxidant for [Mn(bpy)₂]²⁺-NaY-PDMS. The reactions in batch and fed-batch reactors are discussed. A simple regeneration procedure, monitored by FT-IR spectroscopy is proposed.     

“镍”催化酰氯和有机锡试剂交叉偶联反应的研究

镍络合物催化酰氯与有机锡试剂交叉偶联合成有机酮的反应,其反应选择性强,反应彻底,转化率高,工艺简单。在有机锡过量的情况下,对不同催化剂的催化活性和包括投料比,反应温度,反应时间,反应溶剂等反应条件进行了考察。     

Bisensors for amino acids

Two kinds of biosensors for amino acids (one with nonspecific enzyme as bioelement, the other with specific enzyme(s) as bioelement), including their principles, applications, recent researches and future trends were discussed in detail. 61 references were given. A part of work for gaining Ph. D in chemical and biochemical application at FPMs (Mons, Belgique) Synopsis of the first author Xia Jinlan, Male, born in 1963, now at Facult’e Polytechnique de Mons, Belgique     

Immobilization of an endopectinlyase on γ-alumina: Study of factors influencing the biocatalytic matrix stability

Endopectinlyase (EC 4.2.2.10) from Aspergillus japonicus was immobilized on to γ-alumina. Adsorption performed at pH 5·0 and a subsequent cross-linking phase using 0·1% glutaraldehyde were the chosen immobilization conditions. The comparison between the main biochemical parameters of the immobilized and free form of the enzyme showed that the immobilization procedure used did not affect the enzyme biochemical properties. The interactions between the carrier and the enzyme are essentially secondary bonding. In fact they depend on the pH and on the presence of phosphate ions in the medium. A tentative chemical model of the biocatalytic matrix thus obtained is proposed.     

Synthesis and characterization of chitosan/poly(acrylic acid) polyelectrolyte complex

Polyelectrolyte complex based on chitosan and acrylic acid monomer by photoinitiated free‐radical polymerization in the absence of crosslinker showed a large transition in swelling in response to changes in pH of surrounding medium. Their ability to swell arises from polyelectrolyte interactions and molecular structure of the complex. The main properties of interest that related to the molecular structure, swelling volumes, glass transition temperature, and elastic modulus of the complex were investigated. The effect of water content, the only variable in the sample component, played an important role in molecular structure of the complex and as a consequence, the extent of intermolecular linkage, especially amide bonds which in turn governed the degree of swelling of the polyelectrolyte complex in this study. The decreased degree of swelling and higher temperature shift of glass transition temperature was found with increased water content, whereas increased modulus of elasticity of dry complex was found in lower water content of synthesis component. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 83: 1025–1035, 2002     

片式多层电容电阻复合元件的研制

采用低温共烧陶瓷(LTCC)技术将电容、电阻元件集成在多层陶瓷基板里,构成了一种新型的片式多层复合元件,并研究了其制造工艺性能和频率特性。结果表明,片式多层电容电阻复合元件制造工艺适合批量化生产,并为片式多层LC滤波器、LTCC基板及器件的研发提供了极好的参考价值。