乙二醇合成工艺的研究进展

对国内外乙二醇合成的传统工艺:直接水合法、催化水合法和碳酸乙烯酯法进行了介绍;对乙二醇合成的新工艺,包括乙二醇和碳酸二甲酯联产法和C1化学法的工艺流程和发展前景进行了综述,其中,C1化学法主要分为乙烯合成法、合成气合成法和甲醛、甲醇合成法。作为合成气合成法之一的合成气偶联合成法,具有工艺要求不高、反应条件温和等优点,是目前最有希望大规模工业化生产乙二醇的工艺路线。     

Highly active lanthanum doped nickel anode for solid oxide fuel cells directly fuelled with methane

Lanthanum doped nickel and YSZ composite anode (LaNi–YSZ) exhibited a greatly reduced polarization resistance and high performance for electrochemical oxidation of hydrogen and methane, which resulted from a fine anode structure with a high dispersion of nickel catalyst and a high catalytic activity towards methane.     

B2O3/TiO2-ZrO2催化剂上环己酮肟的气相Beckmann重排反应

用共沉淀法制备了TiO2-ZrO2复合氧化物载体，BET，DTA，XRD表征结果表明，该复合载体具有较大的比表面和较好的热稳定性，对于环己酮肟气相Beckmann重排反应制己内酰胺，用复合载体制备的B2O3／TiO2-ZrO2催化剂，比分别以TiO2,ZrO2为载体所制备的B2O3/TiO2和B2O3／ZrO2催化剂具有更高的活性和选择性，实验表明，催化剂表面中等强度的酸位是环己酮肟气相Beckmann重排反应的有效活性中心。     

Comparative hall measurements on wet- and dry-oxidized 4H-SiC MOSFETs

Hall measurements have been used to compare the properties of 4H-SiC inversion-mode MOSFETs with “wet” and “dry” gate oxides. While the field-effect mobilities were approximately 3–5 cm²/Vs, the Hall mobilities in 4H-SiC MOSFETs in the wet and dry oxide samples were approximately 70–80 cm²/Vs. The dry-oxidized metal oxide semiconductor field effect transistors (MOSFETs) had a higher transconductance, improved threshold voltage, improved subthreshold slope, and a higher inversion carrier concentration compared to the wet-oxidized MOSFETs. The difference in characteristics between the wet- and the dry-oxidized MOSFETs is attributed to the larger fixed oxide charge in the dry oxide sample and a higher interface trap density in the wet oxide sample.     

两江水利枢纽泄洪洞出口右侧高边坡锚喷支护施工技术

锚喷支护作为地质灾害治理中山体过坡支护的一杆方法．具有安全、优质、高效、灵活等特点，本文以吉林省安图县两江水利枢纽泄洪洞出口右侧高边坡治理工程为例．对锚喷支护施工技术作一简单介绍。     

关于混联梯级水电站经济调度的研究

提出采用具有附加线性约束的网络规划法，可把混联梯级水电站分解为几个子网络，简化了每个子网络的求解计算，从而加速大电网复杂的经济调度的计算速度。     

复电阻率测井方法及其应用

复电阻率测井是以两频或多频测量地层电阻率的新方法 ,它可用来有效地识别油气层和确定水淹油层的水淹程度。简要介绍了复电阻率测井的测量原理、仪器设计。胜利油田 9口井的现场测井资料初步验证了该方法的可行性和有效性     

天线方向图的复射线仿真

根据复射线理论，利用复源点高斯波束场来模拟天线的远场方向图。本文提出三种模拟方法，即主瓣匹配法，峰值匹配法和逐点匹配法，给出了多种方向图的仿真结果。数值分析和优化结果表明，复射线峰值匹配法是一种精确实用的天线方向图仿真技术。     

Sol-gel processing: A versatile concept for special glasses and ceramics

The various parameters related to sol-gel processing are discussed with special reference to those which usually attract less attention but depending on the final product in mind, can play important roles. The versatility of the sol-gel technique in materials preparation is demonstrated by discussing the various products developed at the author’s laboratory by using this processing method.     

A detailed analysis of ambipolar diffusion in nanostructured metal oxide films

In this paper a transport equation is derived which describes the behaviour of the nanostructured metal oxide films in a photoelectrochemical cell. It is shown that a detailed analysis of the charge compensation mechanism necessarily leads to a transport equation with characteristics similar to but logically distinct from the pure diffusion equation. The studied phenomenon was named ambipolar diffusion in the early 1950s. It takes into account the fact that the diffusion processes of ions and electrons occur at different speeds. A weak electric field therefore couples the processes together to preserve charge neutrality. The electric field in turn affects the transport resulting in a deviation from purely diffusive behaviour. However, this has not been widely recognised in the literature for nanostructured semiconductor films until very recently. In this paper a detailed analysis is presented. It is based on the assumption that the current density is solenoidal. It is shown that application of the ambipolar diffusion model to a photoelectrochemical cell based on a nanostructured metal oxide film leads to an additional term in the transport equation, rather than only a new diffusion coefficient as in earlier work. It is also shown that the boundary conditions interact closely with the equation to form a transport model.