Composite‐Structure Material Design for High‐Energy Lithium Storage

High‐energy storage devices are in demand for the rapid development of modern society. Until now, many kinds of energy storage devices, such as lithium‐ion batteries (LIBs), sodium‐ion batteries (NIBs), and so on, have been developed in the past 30 years. However, most of the commercially exploited and studied active electrode materials of these energy storage devices possess a single phase with low reversible capacity or unsatisfied cycle stability. Continuous and extensive research efforts are made to develop alternative materials with a higher specific energy density and long cycle life by element doping or surface modification. A novel strategy of forming composite‐structure electrode materials by introducing structure units has attracted great attention in recent years. Herein, based on previous publications on these composite‐structure materials, some important scientific points focusing on the design of composite‐structure materials for better electrochemical performances reveal the distinction of composite structures based on average and local structure analysis methods, and an understanding of the relationship between these interior composite structures and their electrochemical performances is discussed thoroughly. The lithiation/delithiation mechanism and the remaining challenges and perspectives for composite‐structure electrode materials are also elaborated.     

用于纤维材料表面耐磨涂层的制备与性能表征

为使涤纶织物应用范围更广,更耐磨,本文制备了一种有机硅树脂基纳米硼化钛碳化钛复合涂层,通过正交实验法得到最佳的涂层方案,并尝试将其应用于涤纶织物,以改善涤纶织物的表面结构,进而实现涤纶织物表面优异的耐磨性能.为测试涂层对涤纶织物性能的影响, 采用泰伯式耐磨仪、液滴形状分析仪、电子织物强力机、扫描电子显微镜(SEM)研究了涂层织物的耐磨性能、疏水性能、物理机械性能和磨损织物的表面微观形态.研究表明：当有机硅树脂与无水乙醇质量比为75: 25,含量(质量分数)为93%;超分散剂含量为1.5%;乙醇增稠剂含量为1.5%;纳米硼化钛和碳化钛质量比为2: 1,含量为4%时,所得涂层溶液应用于涤纶织物后会形成一层包覆层,耐磨性能最优.对于涂覆量为15 g/m²的涤纶,拉伸断裂强力由573.92 N提高到620.48 N,顶破强力由652.34 N提高到790.07 N,撕裂强力由9.87 N降低到5.78 N,疏水性能有较大提高,接触角可达到120°以上.     

45钢表面Ni/WC复合熔覆层的形成机制

采用真空熔覆技术在45钢表面制备Ni +WC复合熔覆层并进行阶段性取样,研究镍基复合涂层的形成机制。结果表明：在45钢表面生成与基体冶金熔合、WC硬质颗粒分布均匀的Ni基复合熔覆层。整个熔覆层由4 mm厚的复合层、1 mm厚的过渡层、20 μm厚的扩散熔合区以及250 μm厚的扩散影响区组成。复合层区由WC和分解形成的富W复相碳化物包围在Ni颗粒周围组成;复合熔覆层的主要组成相有γ-Ni固溶体、Cr₇C₃、Ni_2.9Cr_0.7Fe_0.36、Cr₂₃C₆、Ni₃Fe、Ni₃Si、Ni₃B、W₂C以及C等;真空熔覆过程包括：镍基合金颗粒达到熔点(900℃)前升温阶段颗粒间微烧结颈的形成、升温达到熔点(1020℃)开始的镍基合金颗粒熔融以及保温阶段(1060℃)的熔合扩散与WC颗粒微区位置的调整。     

直接Z-型立方/六方ZnIn2S4复合光催化剂的制备及其光催化性能

通过水热反应方法制备出立方相ZnIn₂S₄和六方相ZnIn₂S₄和系列不同摩尔比的复合相ZnIn₂S₄光催化剂,使用X射线衍射、扫描电子显微镜、电子能谱、透射电子显微镜、光致发光光谱、N₂吸附-脱附法及紫外-可见光漫反射等手段表征了样品的晶体结构、显微结构及吸光特性并在可见光照射下进行了甲基橙降解实验。结果表明,复合相ZnIn₂S₄样品都具有比立方相、六方相和机械混合的ZnIn₂S₄更好的可见光催化活性,当复合相ZnIn₂S₄样品中立方相与六方相摩尔比为3:7时体系的催化活性最高。这种样品被可见光照射30 min后,甲基橙的降解率达到95.2%。其降解机理与样品较大的比表面积以及样品中的立方相与六方相之间的密切接触而形成直接Z-型光催化过程有关。     

可伸缩复合材料悬臂梁的非线性动力学建模及分析

首先,根据Reddy给出的考虑高阶剪切效应的层合理论,气动弹性活塞理论,利用Hamilton原理,对考虑采用基于活塞理论的一阶非线性气动力和面内参数激励的联合作用下的轴向可伸缩复合材料悬臂梁进行非线性动力学进行建模,得到其偏微分动力学控制方程.然后对控制方程无量纲化,利用Galerkin方法对控制方程进行了截断,得到三个可反映可伸缩悬臂梁横向振动的无量纲形式的常微分非线性动力学方程,只要选取适合的复合材料及其相关参数,使用数值方法就对模型在外伸和回收过程中的相关振动特性进行了分析.     

红外隐身防护材料研究进展

目的 综述近年来国内外先进的红外隐身防护材料技术的研究进展,并对红外隐身材料的未来进行展望。方法 从红外探测技术与红外隐身原理出发,着重介绍低发射率材料、控温材料、新型智能红外隐身材料以及协同复合材料等一系列有优异性能的材料。结果 红外隐身可通过降低物体表面温度及降低物体表面辐射率来实现,依据这两方面原理研制的红外隐身防护材料具有良好的隐身效果。结论 不同种类的红外隐身材料具有不同的特点,已广泛运用于军事装备、织物等方面,但依然存在一些不足,未来要针对不同应用环境要求进一步优化,以期满足现代化战争需求。     

多孔PDMS基底复合柔性互连导线拉伸时3D变形行为研究

目的 探究多孔聚二甲基硅氧烷(PDMS)基底复合柔性互连导线的透气性能和延展性能,以使其更好地应用在医疗领域。方法 本文采用三维数字图像相关(3D-DIC)方法检测了25 ℃下不同孔隙率的多孔PDMS基底复合柔性互连导线单轴拉伸过程中导线与基底的面内应变失配和离面位移特征。在此基础上,本文引入平均位移(wm)和位移幅(wa)作为量化表征复合柔性电子离面变形的指标,并结合多孔PDMS基底的气密性实验结果评价了不同导线样品。结果 研究结果表明,多孔PDMS材料作为基底能显著降低复合柔性电子的离面变形程度,并使复合柔性电子具有良好的透气性。在相同拉伸载荷(20 N)和拉伸距离下,PDMS与去离子水质量比为6∶1时的多孔PDMS基底复合柔性互联导线具有稳定的离面变形变化量。结论 多孔PDMS基底复合柔性电子不仅具有良好的透气性,而且可以有效地增强金属互联层与柔性基底的粘连程度。本文所获得的PDMS与去离子水最佳掺杂质量比,可为制造高延展性多孔基底柔性电子器件提供参考。     

茶末/CMC-Na/AL-Na复合膜制备及性能测定

目的 为改善传统保鲜膜带来的环境污染问题,开发出具有较好力学性能和抗菌性的食品包装材料提供理论依据。方法 采用海藻酸钠(AL-Na)和羧甲基纤维素钠(CMC-Na)为主要成膜材料,辅助添加茶末通过流延成膜法制备复合膜,以拉伸强度、断裂伸长率等为依据,通过单因素和响应面试验确定茶末/CMC-Na/AL-Na复合膜的最佳工艺。结果 当CMC-Na与AL-Na的体积比为84∶16、茶末添加量为1.43%、干燥温度为50 ℃、干燥时间为7 h时,复合膜综合性能最优,拉伸强度为16.60 N/mm²,断裂伸长率为19.11%,具有较好的力学性能、耐水性、抗氧化性和抑菌性。结论 制备的茶末/ CMC-Na/AL-Na复合膜具有较好的力学性能和抗氧抑菌性能。     

Using Selective Electron Beam Melting to Enhance the High-Temperature Strength and Creep Resistance of NiAl–28Cr–6Mo In Situ Composites

By increasing the density of interfaces in NiAl–CrMo in situ composites, the mechanical properties can be significantly improved compared to conventionally cast material. The refined microstructure is achieved by manufacturing through electron beam powder bed fusion (PBF-EB). By varying the process parameters, an equiaxed or columnar cell morphology can be obtained, exhibiting a plate-like or an interconnected network of the (Cr,Mo) reinforcement phase which is embedded in a NiAl matrix. The microstructure of the different cell morphologies is investigated in detail using scanning electron microscope, transmission electron microscopy, and atom probe tomography. For both morphologies, the mechanical properties at elevated temperatures are analyzed by compression and creep experiments parallel and perpendicular to the building direction. In comparison to cast NiAl and NiAl–(Cr, Mo), the yield strength of the PBF-EB fabricated specimens is significantly improved at temperatures up to 1,027 °C. While the columnar morphology exhibits the best improved mechanical properties at high temperatures, the equiaxial morphology shows nearly ideal isotropic mechanical behavior, which is a substantial advantage over directionally solidified material.