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71.
72.
低压铝箔交流腐蚀研究 总被引:4,自引:2,他引:2
在30Hz频率下,通过铝箔在HCl+H2SO4+HNO3+H3PO4体系中的交流腐蚀,研究腐蚀液组成中腐蚀主体及缓蚀剂对铝箔腐蚀的作用,探讨腐蚀过程中电源频率、腐蚀液温度、电流密度及腐蚀时间对铝箔腐蚀的影响。腐蚀液组成的配比恰当,有利于比容的提高。在特定的频率下采用合适的腐蚀液温度、适宜的电流密度和腐蚀时间可以提高铝箔的静电容量。 相似文献
73.
In industrial systems, the formation of biofilms can cause many problems, such as an increase in the flow resistance of pipelines, energy losses in fluid transport and heat exchangers, product contamination, materials deterioration, and biocorrosion. As a result, biofilms contribute substantially to economic losses in the industry. Corrosion is particularly an issue in the petroleum industry and its implications range from down-hole completion through petroleum processing units. Much of this corrosion is attributed to microbial activities. This paper proposes a mathematical model for predicting substrate concentration for such microbial growth. Substrate concentrations in the system and near the biofilm surface are one of the parameters that has a great effect in determining the extent of the problems associated with biofilms. In this study, a convective-diffusion model under various flow conditions (stagnant, laminar, and turbulent) has been solved using the finite difference technique, employing the alternating direction implicit (ADI) method. The model assumes that a liquid containing substrate and bacteria is flowing in a pipeline with known concentrations at the inlet and then predicts the variation of the transient (as a function of time) substrate concentration along the pipeline and as a function of the pipe radius. The model is then used to predict and estimate the substrate concentration profiles on the biofilm surface under different environmental conditions. A parametric study was also conducted to study the effect of the different parameters influencing the substrate concentration profiles in the system and on the biofilm surface. 相似文献
74.
Xueyuan ZhangWenle He Inger Odnevall Wallinder Jinshan PanChristofer Leygraf 《Corrosion Science》2002,44(9):2131-2151
Instantaneous corrosion rates of naturally patinated copper of varying age (16 months, 138 and 145 years) have been determined during continuous rain events in the laboratory with electrochemical impedance spectroscopy using a two-electrode cell. The two-electrode cell was found to yield the same information in bulk rainwater as a conventional three-electrode cell.Relatively constant corrosion rates, between 0.2 and 0.6 μm/y, were determined for samples having a two-layer structure with an inner brownish layer of cuprous oxide and an outer greenish layer of basic copper salts (138, 145 years). Samples with cuprous oxide as the dominating phase of the patina (16 months) showed higher and somewhat increasing corrosion rates during a rain event (from 0.6 to 1.2 μm/y). During a continuous rain event, corrosion rates were found to be approximately 10 (brownish patina) and 25 times (greenish patina) lower than corresponding instantaneous runoff rates. The first flush phenomena of the runoff process, with an increased concentration during first flush and a relatively constant concentration during steady state, was indirectly seen as an increase in solution conductivity during the first rain volume followed by relative constant value. The contribution of the concentration in the first flush to the total annual runoff rate was significant for panels having a greenish layer (138, 145 years) whereas it was negligible for panels having a brownish layer (16 months). 相似文献
75.
In this work, the filiform corrosion behaviour of powder painted aluminium profiles was studied, and the coating barrier properties together with adhesion to the substrate were analysed. Samples coated with a traditional painting procedure (one powder layer application followed by curing), and other samples coated using a special cycle to obtain wood grain effect were compared using accelerated filiform corrosion tests. Moreover, in order to better understand the degradation mechanisms of painted metal substrates, thermal stresses were applied to accelerate the natural weathering. The effects of the thermal aging were analysed by electrochemical impedance spectroscopy. 相似文献
76.
Yu. V. Balaban-Irmenin N. G. Fokina 《Power Technology and Engineering (formerly Hydrotechnical Construction)》2007,41(5):306-312
The effect of internal-corrosion inhibitors on heating-system pipelines is investigated. Tests were conducted on a testing
device for polarization measurements under conditions corresponding to the Rostov Heat-Supply System. The concentration of
OEDP-zinc, which provides a high degree of protection from general corrosion, is determined. The reagent has been successfully
incorporated into the Rostov No. 2 TPP.
__________
Translated from élektricheskie Stantsii, No. 7, July 2007, pp. 37–43. 相似文献
77.
Yu. V. Balaban-Irmenin N. G. Fokina 《Power Technology and Engineering (formerly Hydrotechnical Construction)》2007,41(4):228-232
The reliability of heat-supply systems is determined primarily by internal corrosion of the pipelines. The concentration of
oxygen in the water exerts a major influence on the corrosion. In systems with a standard oxygen content, OéDF-Zn is a highly
effective corrosion inhibitor. However, there are systems in which the quality of deaeration of the make-up water of the heat-supply
system is low (or deaeration is nonexistent), and the concentration of oxygen is considerably above the standard value. Classed
among these systems, for example, are the HWS systems, which are incorporated into closed heat-supply systems. The oxygen
concentration in these systems is analyzed to assess the situation.
__________
Translated from élektricheskie Stantsii, No. 6, June 2007, pp. 35–39. 相似文献
78.
Melissa Kurtz 《Journal of Failure Analysis and Prevention》2007,7(3):175-178
Fuel system assemblies used on recreational watercraft failed after a short time in service in a seawater environment. Examination
of the assemblies revealed significant degradation of the polyacetal connectors of the wire subassemblies. Optical and microscopic
evaluations indicated the complete loss of connector material implying decomposition of the resin, along with mud-cracking
and a rough surface morphology signifying chemical attack. An elemental analysis performed on both an intact connector and
degraded connector suggested a potential chemical agent in the form of zinc chloride. At elevated temperatures, concentrated
zinc chloride solutions are known to decompose polyacetal resins. The source of the zinc chloride was established as corrosion
products that resulted during the dezincification of the internal brass connector through exposure to saltwater in the application. 相似文献
79.
Effects of austenitizing treatment temperatures on aqueous corrosion properties of martensitic stainless steels were investigated by electrochemical tests (potentiodynamic test, potentiostatic test and electrochemical impedance spectroscopy), and surface analyses (optical microscopy and XRD). The results of potentiodynamic test revealed that the breakdown potential increased with the increased austenitizing temperature, indicating increased relative resistance to initiation of localized corrosion. EIS measurements showed that MSS3 (1030 °C) exhibits larger polarization resistance value than MSS1 (970 °C) and MSS2 (1000 °C) at passive and breakdown states. This was caused by decreasing the amount of Cr-rich M23C6 carbide which acts as preferential sites for pitting corrosion. 相似文献
80.
复合绝缘子耐电腐蚀特点及其电蚀老化区域性的差异 总被引:6,自引:0,他引:6
为了了解复合绝缘子外绝缘材质电蚀老化状态和区域性的差异,对Al(OH)3耐电腐蚀机理、外绝缘材质中Al(OH)3颗粒分布状态和环境污湿因素的实际情况进行了研究。Al(OH)3颗粒分解成水蒸气、析出白色粉末状氧化铝,并催化生成二氧化碳,将使外绝缘材质逐渐微观减薄和加大表面的粗糙度,而引起电蚀老化的污湿环境因素,近期不可能得到改善,因此必然引起其电蚀老化出现区域性差异。此外,外绝缘憎水表面污珠场强变化引起的电晕也是促使电蚀老化的重要因素。 相似文献