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21.
Statistical studies of branched ester latex and paint properties 总被引:3,自引:0,他引:3
R. A. Prior W. R. Hinson O. W. Smith D. R. Bassett 《Progress in Organic Coatings》1996,29(1-4):209-224
Vinyl versatate, butyl acrylate and 2-ethylhexyl acrylate were compared as comonomer, for colloid-stabilized vinyl acetate latex polymers to assess their impact on latex coating properties. Vinyl versatate afforded advantages in scrub resistance, gloss, hydrophobicity and higher glass transition temperatures. Butyl acrylate developed better wet adhesion efficiency, gel content and hiding efficiency. 2-Ethylhexyl acrylate offered performance comparable to butyl acrylate in hiding efficiency, lowering copolymer glass transition temperatures, and gloss development. Combinations of these monomers, in many instances, afforded a better balance of performance properties than individual monomers alone. In the subject study, a simplex-centroid design was utilized to statistically map polymer compositions for determining the effect of comonomer composition on latex and paint film properties. In addition to developing contour maps of polymer and paint properties as a function of composition, a technique for studying structure-property relationships is presented. 相似文献
22.
提出了一种计算积分方程的新方法——改进的逐次逼近解法 (MSAM) ,并用该方法计算了轴对称二维井间电磁场。与传统的逐次逼近解法 (SAM)相比 ,该方法收敛性强 ,应用范围广 ,可适用于高电导率对比地层。由于不必进行直接的大型矩阵求逆运算 ,因此与积分方程的直接解法 (IE)相比 ,该方法计算速度更快 ,所需内存更少。采用矩阵求逆方法计算了成层介质中的二维 Green函数 ,并对含 Green函数的积分进行了简化 ,从而加快了计算速度。数值计算结果显示 ,在地层电导率对比度达到 2个数量级时 MSAM仍收敛 ,且计算结果与直接求解积分方程的结果一致 ,因此 MSAM是一种有效的计算轴对称二维井间电磁场的方法 相似文献
23.
横流均匀环境中三维线源型正负浮力射流特性研究 总被引:2,自引:2,他引:0
本文利用混合有限分析法及交错网格。对横流均匀环境中三维线源型正负浮力射流及负浮力射流的特性进行研究,分析了不同工况下流速,温度和湍动能在断面上的分布及影响射流轨迹线的因素,讨论了轨迹线上温度的变化及浮力射流的贴壁现象。对三维长线源型负浮力射流,分析了流速比,喷口弗汝德数对负浮力射流的影响。 相似文献
24.
Tatsuro Kijima Kouji Ohshima Hideo Kise 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》1994,59(1):61-65
Racemic amino acid esters were optically resolved via hydrolysis in organic solvents by the catalysis of an industrial alkaline protease, “Alcalase”. The products which were composed mainly of L-amino acids were insoluble and easily separated by filtration. The activity of the enzyme and enantiomeric excess of the products were significantly dependent on the nature of solvent and the water content in the reaction media. Generally, high values of enantiomeric excess were obtained at low water contents. Many natural and unnatural amino acids were resolved by this method. 相似文献
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Agnieszka J Klemm Piotr Klemm Kazimierz Rozniakowski Tomasz W Wojtatowicz 《Building and Environment》2002,37(12):1221-1232
This paper present the results of the investigation into a potential application of laser radiation for the detection of phase transition processes occurring on the surface layers of porous materials. An attempt was made to discuss in the approximation equations, the relationships between coefficients of the reflected light, the temperature and humidity of the surrounding environment. Laser light reflected from the porous surface carries information about the roughness of the structure. The presence of water microdrop on the surface of the porous material, as a result of condensation and thus a phase transition, leads to the phase displacement of individual rays, which is represented by different images. Therefore, a comprehensive analysis of the reflected light parameters allows a dynamic study of the phase transition phenomena without mechanical intervention. 相似文献
28.
Philip M. Stone Yong-Ki Kim J. P. Desclaux 《Journal of research of the National Institute of Standards and Technology》2002,107(4):327-337
Electron-impact excitation cross sections are presented for the dipole- and spin allowed transitions from the ground states to the np
2P states for hydrogen and lithium, and to the 1snp
1P states for helium, n = 2 through 10. Two scaling formulas developed earlier by Kim [Phys. Rev. A 64, 032713 (2001)] for plane-wave Born cross sections are used. The scaled Born cross sections are in excellent agreement with available theoretical and experimental data. 相似文献
29.
Lutein and lutein esters in marigold flowers was quantitatively determined by high performance chromatography (HPLC) with ODS-C18 column. A mixture of CH3CN-CH3OH-CH3COOCH2CH2 with volume ratio of 55:1:44 was used as mobile phase at a flow rate of 1.0mL/min and detection was carried out at 480 nm. The column temperature was about 20℃. The contents of lutein and lutein esters were determined by analytical curve of lutein since lutein and lutein esters have the same spectral characteristics. Determination results of hexane extracts and saponified samples of lutein show that the saponification transforms the esters into free lutein. The increase of the content of dipalmitate and palmitate stearate reveals that the reaction includes transesterifications. 相似文献
30.