HIPS/HDPE制备工艺对共混物机械性能的影响

以高抗冲聚苯乙烯(HIPS)/高密度聚乙烯(HDPE)=70/30(质量比)作为研究对象,利用DCP及SEBS的协同作用,考察了不同加料方式,DCP,SEBS含量,加工温度,螺杆转速等条件对共混物性能的影响。结果表明:m(HIPS)/m(HDPE)/m(SEBS)=70/30/10,DCP用量为HIPS和HDPE总质量的0 06%,挤出加工温度(后部)为185℃,螺杆转速为80r/min时,共混物性能较高。     

高分子链柔顺性及链活动能力对辐射交联反应的影响

高分子分子链的柔顺性是影响辐射交联的重要因素，分子链柔顺性好的高分子容易交联，凝胶化剂量低，反之分子链较僵硬的高分子辐射交联较困难，某此特别僵硬分子链的高分子，必须在高温下，分子链有一定的活动力后才能进行辐射交联反应。分子链的柔顺性还影响裂解度和辐照剂量的关系，在溶胶分数和辐射剂量的关系式中引入表征分子链柔顺性的β因子，从而修正了Charlesby-Pinner关系式，得到适用范围更广的新的溶胶分数和辐射剂量的关系式。分子链的柔顺性亦影响辐射交联反应机理，从多种高分子实例看出，柔顺性好的高分子Tg较低，分子内旋转位阻因子小，这类高分子辐射交联反应机理以H型为主；而僵硬链高分子Tg较高，分子内旋转位阻因子大，这类高分子辐射交联反应机理以T型（或称Y型）为主。     

中小企业硅烷交联聚乙烯绝缘单线制造的探索

硅烷交联聚乙烯绝缘单线制造可以借鉴聚氯乙烯绝缘单线的制造,然而,其对导体制品的要求和绝缘挤出工艺存在着很多不同之处。本文通过比较和分析,探索传统生产聚氯乙烯绝缘电线电缆的中小型企业,通常产品的产量较小、品种较多、一机多用或品种变化频繁的条件下,增加硅烷交联电线电缆生产时,在绝缘单线制造中应采取相应的对策和注意事项,指出了导体制造、绝缘挤出和交联工艺中质量控制要点。     

聚丙烯酸/聚乙烯醇共混物结构研究

将丙烯酸／丙烯酰胺二元共聚物与聚乙烯醇共混后经热交联处理得到吸水性较好的聚丙烯酸／聚乙烯醇共混树脂，利用傅立叶红外光透射谱图(FT-IR)、热重谱图(TG-DTA)和动态力学分析温度谱图(DMA)详细分析了树脂的结构和热性能、结果表明，共混物大分子间形成了有效的化学交联点且二元共聚物与聚乙烯醇间存在相互作用、     

Grafting maleic anhydride onto EVA and effect on the physical and rheological properties of PETG/EVA-g-MAH blends

Maleic anhydride (MAH) was grafted onto ethylene vinyl acetate copolymer (EVA) in the internal mixer in the presence of dicumyl peroxide (DCP), and a prepared reactive compatibilizer, MAH-g-EVA, was blended with Poly (ethylene glycol-co-cyclohexane-1,4-dimethanol terephthalate) (PETG). The gel content determination and element analysis (EA) was performed to confirm the grafting reaction. It was found that grafting reaction of MAH on to EVA could compete with crosslinking reaction of DCP during the modification process. In addition, the introduction of small amount of MAH showed a great effect on reducing gel content by decreasing crosslink reaction. As MAH content increased, grafted MAH concentration increased, whereas the grafting yield decreased. It was also confirmed that MAH-g-EVA acted as a reactive compatibilizer in the blend with PETG, and enhanced compatibility by reacting with the hydroxyl end groups, OH, of PETG. Addition of EVA in the blend leads a plastic deformation of PETG, and MAH had a great effect on enhancing interfacial adhesion resulting in significant increasing of % strain; however, improved compatibility could not be changed much in low strain tensile strength and Young's modulus. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Cholesteric monomer and elastomers containing menthyl groups: Synthesis and phase behavior

The synthesis of a new cholesteric monomer ( M_LC) containing menthyl groups and a series of cholesteric elastomers ( LCE₁−LCE₄ ) is described. Their chemical structures and purity were characterized by FTIR, ¹H-NMR, and elemental analyses. The phase behavior and thermal stability were investigated by differential scanning calorimetry, polarizing optical microscopy, X-ray diffraction, and thermogravimetric analysis. By inserting a flexible spacer between the mesogenic core and the terminal menthyl groups, mesomorphism of M _LC was realized. LCE₁−LCE₄ with low content of crosslinking unit exhibited cholesteric phase because of the introduction of the nematic crosslinking unit. This indicates that low levels of chemical crosslinking do not significantly affect the phase behavior and mesomorphism of the elastomers, and reversible mesophase transitions can be observed. In addition, with increasing the content of crosslinking unit, the corresponding T_g decreased for LCE₁−LCE₄ , whereas their T_i did not remarkable change. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Chitosan‐based hydrogels: recent design concepts to tailor properties and functions

Chitosan (CS) has received much attention as a functional biopolymer for designing various hydrogels for biomedical applications. This review provides an overview of the different types of CS‐based hydrogels, the approaches that can be used to fabricate hydrogel matrices with specific features and their applications in controlled drug delivery and tissue engineering. Emphasis is laid on the recent design concepts of hybrid hydrogels based on mixtures of CS and natural or synthetic polymers, interpenetrating polymer networks as well as composite hydrogels prepared by embedding nanoparticles into CS matrices. © 2017 Society of Chemical Industry     

Dextrin crosslinked with poly(lactic acid): A novel hydrogel for controlled drug release application

A new class of biodegradable crosslinked hydrogel, consisting of hydrophobic polylactic acid (PLA) and hydrophilic dextrin in presence of crosslinker N,N‐methylene bisacrylamide (MBA) has been synthesized by free‐radical polymerization technique using potassium persulfate (KPS) as initiator. By variation of crosslinker concentration, a series of hydrogels have been prepared and the optimized grade has been selected on the basis of higher crosslinking efficiency as well as lower equilibrium swelling characteristics, XRD analysis. The hydrogels have been characterized by FTIR spectra, ¹³C‐NMR spectra, CHN analysis, SEM analysis, swelling characteristics, and toxicity study. In vitro release study of model drugs (ciprofloxacin and ornidazole) from hydrogel matrix has been performed in various buffer solutions at 37°C. The drug release kinetics and mechanism have been studied using zero order, first‐order kinetic models, Korsemeyar–Peppas model, Higuchi model, Hixson–Crowell model, and nonlinear Kopcha model. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2014 , 131, 40039.