全文获取类型
收费全文 | 3058篇 |
免费 | 561篇 |
国内免费 | 26篇 |
专业分类
电工技术 | 37篇 |
综合类 | 76篇 |
化学工业 | 2758篇 |
金属工艺 | 7篇 |
机械仪表 | 6篇 |
建筑科学 | 16篇 |
矿业工程 | 6篇 |
能源动力 | 16篇 |
轻工业 | 177篇 |
石油天然气 | 153篇 |
武器工业 | 5篇 |
无线电 | 51篇 |
一般工业技术 | 241篇 |
冶金工业 | 3篇 |
原子能技术 | 91篇 |
自动化技术 | 2篇 |
出版年
2024年 | 15篇 |
2023年 | 31篇 |
2022年 | 40篇 |
2021年 | 141篇 |
2020年 | 135篇 |
2019年 | 71篇 |
2018年 | 89篇 |
2017年 | 126篇 |
2016年 | 152篇 |
2015年 | 160篇 |
2014年 | 200篇 |
2013年 | 223篇 |
2012年 | 164篇 |
2011年 | 170篇 |
2010年 | 132篇 |
2009年 | 136篇 |
2008年 | 121篇 |
2007年 | 154篇 |
2006年 | 168篇 |
2005年 | 178篇 |
2004年 | 166篇 |
2003年 | 169篇 |
2002年 | 116篇 |
2001年 | 91篇 |
2000年 | 86篇 |
1999年 | 69篇 |
1998年 | 67篇 |
1997年 | 51篇 |
1996年 | 22篇 |
1995年 | 26篇 |
1994年 | 29篇 |
1993年 | 24篇 |
1992年 | 22篇 |
1991年 | 23篇 |
1990年 | 14篇 |
1989年 | 8篇 |
1988年 | 8篇 |
1987年 | 8篇 |
1986年 | 7篇 |
1985年 | 9篇 |
1984年 | 10篇 |
1983年 | 5篇 |
1982年 | 8篇 |
1951年 | 1篇 |
排序方式: 共有3645条查询结果,搜索用时 15 毫秒
141.
Preparation and characterization of innovative cellulose diacetate/epoxy resin blends modified by isophorone diamine
下载免费PDF全文
![点击此处可从《应用聚合物科学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Cellulose diacetate (CA)/epoxy resin (EP) blends with excellent mechanical performance were prepared with simple blending followed by curing with isophorone diamine (IPDA). The reaction between the amino groups of IPDA and epoxide groups of EP was confirmed by Fourier transform infrared spectroscopy. Scanning electron microscopy revealed that the cured EP particles gradually became larger and closer to each other to form semi‐interpenetrating polymer networks in the CA matrix; this contributed to the improved mechanical properties of the CA/EP blends. Dynamic rheological experiments indicated that the CA/EP blends with semi‐interpenetrating polymer networks retained processability. After the introduction of a low content (5–10 phr) of IPDA, the mechanical properties of the CA/EP blends were significantly enhanced. With the addition of 20–30‐phr IPDA, the CA/EP blend exhibited a tensile strength of 77 MPa, a flex strength of 65 MPa, a flex modulus of 2.6 GPa, and a hardness of 94 HD; these values were much higher than those of the pristine CA/EP binary blend. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44151. 相似文献
142.
Stepwise cure and properties of silicone resin for high‐ultraviolet‐transmission optical elements
下载免费PDF全文
![点击此处可从《应用聚合物科学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Zhiyong Lv Chonggang Wu Jing Li Xiao Fang Dongdong Yu Huchuan Qin Peng Yu Xuhuang Chen 《应用聚合物科学杂志》2016,133(16)
A new high‐ultraviolet (UV)‐transmission silicone‐resin polymeric material was prepared via curing during hydrosilylation of tetramethyltetravinylcyclotetrasiloxane with tetramethylcyclotetrasiloxane by a liquid‐surface supernatant method, using a stepwise heating program to avoid spontaneous combustion of the reaction mixture. The relationships were investigated in detail between reactive groups, cross‐linking density, mechanical and UV‐transmission properties. For this purpose, UV transmittance and dynamic mechanical properties, respectively, of the silicone resin were measured with UV–visible spectrophotometry and dynamic mechanical thermal analysis. In addition, surface roughness was evaluated with an atomic force microscope as well as an interferometer. The curing process was monitored by Fourier transform infrared spectroscopy and rotational rheometry. The cyclic silicone oils were compared with linear ones in structure and product properties. The results indicated that stepwise temperature control during curing process was particularly indispensible due to the presence of active Si? H bonds, and that the silicone resin of high modulus, high UV transmittance (92.7%) and low surface‐roughness was largely homogeneous in cross‐linking points distribution. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43308. 相似文献
143.
Dual crosslinked carboxymethyl sago pulp/pectin hydrogel beads as potential carrier for colon‐targeted drug delivery
下载免费PDF全文
![点击此处可从《应用聚合物科学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Hui Li Tan Li Shan Tan Yeon Yin Wong Saravanan Muniyandy Kamaruddin Hashim Janarthanan Pushpamalar 《应用聚合物科学杂志》2016,133(19)
Carboxymethyl sago pulp (CMSP)/pectin hydrogel beads were synthesized by calcium crosslinking and further crosslinked by electron beam irradiation to form drug carrier for colon‐targeted drug. Sphere‐shaped CMSP/pectin 15%/5% hydrogel beads is able to stay intact for 24 h in swelling medium at pH 7.4. It shows pH‐sensitive behavior as the swelling degree increases as pH increases. Fourier transform infrared spectroscopy analysis confirmed the absence of chemical interaction between hydrogel beads and diclofenac sodium. Differential scanning calorimetric and X‐ray diffraction studies indicate the amorphous nature of entrapped diclofenac sodium. The drug encapsulation efficiency is up to about 50%. Less than 9% of drug has been released at pH 1.2 and the hydrogel beads sustain the drug release at pH 7.4 over 30 h. This shows the potential of CMSP/pectin hydrogel beads as carrier for colon‐targeted drug. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43416. 相似文献
144.
Improving properties of silicone rubber composites using macromolecular silane coupling agent (MMSCA)
下载免费PDF全文
![点击此处可从《应用聚合物科学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Honggang Mei Guowen Chen Qingzeng Zhu Peng Dong Dannan Zhao Waqas Ahmed Raza 《应用聚合物科学杂志》2016,133(19)
Two types of vinyl silicone oil (VSO), allyl‐capped hyperbranched polycarbosilane (HBP), and triethoxysilane (TES) were employed to synthesize macromolecular silane coupling agent (MMSCA) by hydrosilylation. VSOs, HBP, and the hydrosilylated products were used as crosslinker, respectively, to improve weak mechanical properties of silicone rubber (SR). Structures of the crosslinkers were studied by gel permeation chromatography (GPC), Fourier transform infrared spectroscopy (FTIR), and nuclear magnetic resonance (NMR). Crosslinking density test and scanning electron microscope (SEM) observation showed an increased interaction between silicone rubber and fumed silica by the use of MMSCA. Mechanical properties of the resulted composites using MMSCAs were increased to varying degrees compared with those possessing crosslinkers without ethoxy group. MMSCAs were effective for further property enhancements of composites. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43415. 相似文献
145.
Influence of the coupling agent and graphene oxide on the thermal and mechanical behavior of tea dust–polypropylene composites
下载免费PDF全文
![点击此处可从《应用聚合物科学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
In this study, the effects of a coupling agent and additive on the physicomechanical (morphological, mechanical, thermal, and swelling) properties of tea dust (TD)–polypropylene (PP) composites were studied. TD–PP composites were prepared with untreated tea dust (UTD) and tetraethylsilane (TES)‐treated TD or silanated tea dust (STD) particles at ratios of 0:100, 10:90, 20:80, 30:70, and 40:60 w/w. Initially, TD particles were grafted by TES as a coupling agent, and these STD particles were then modified with graphene oxide (GO) as an additive to study their effects on the STD–PP composites; these were compared to the STD–PP and UTD–PP composites in accordance with a study of improvements in the mechanical properties. All of the TD–PP composites were analyzed with Fourier transform infrared spectroscopy, scanning electron microscopy, and mechanical, thermal, and physical tests. The thermal and mechanical properties of both the STD–PP and GO‐modified STD–PP composites were found to be improved as compared to those of the UTD–PP composites. So, the recycling of a large amount of TD as a waste material could be useful in the preparation of TD–PP composites. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 42927. 相似文献
146.
Stabilized electrospinning of heat stimuli/in situ crosslinkable nanofibers and their self‐same nanocomposites
下载免费PDF全文
![点击此处可从《应用聚合物科学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
We present a strategy for stabilizing the morphological integrity of electrospun polymeric nanofibers by heat stimuli in situ crosslinking. Amorphous polymer nanofibers, such as polystyrene (PS) and its co‐polymers tend to lose their fiber morphology during processing at temperatures above their glass transition temperature (Tg) typically bound to happen in nanocomposite/structural composite applications. As an answer to this problem, incorporation of the crosslinking agents, phthalic anhydride (PA) and tributylamine (TBA), into the electrospinning polymer solution functionalized by glycidylmethacrylate (GMA) copolymerization, namely P(St‐co‐GMA), is demonstrated. Despite the presence of the crosslinker molecules, the electrospinning polymer solution is stable and its viscosity remains unaffected below 60 °C. Crosslinking reaction stands‐by and can be thermally stimulated during post‐processing of the electrospun P(St‐co‐GMA)/PA‐TBA fiber mat at intermediate temperatures (below the Tg). This strategy enables the preservation of the nanofiber morphology during subsequent high temperature processing. The crosslinking event leads to an increase in Tg of the base polymer by 30 °C depending on degree of crosslinking. Crosslinked nanofibers are able to maintain their nanofibrous morphology above the Tg and upon exposure to organic solvents. In situ crosslinking in epoxy matrix is also reported as an example of high temperature demanding application/processing. Finally, a self‐same fibrous nanocomposite is demonstrated by dual electrospinning of P(St‐co‐GMA) and stabilized P(St‐co‐GMA)/PA‐TBA, forming an intermingled nanofibrous mat, followed by a heating cycle. The product is a composite of crosslinked P(St‐co‐GMA)/PA‐TBA fibers fused by P(St‐co‐GMA) matrix. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44090. 相似文献
147.
Graphite oxide (GO) produced by Hummers method was added to epoxy for strengthening purpose. Generally the E‐modulus was increased due to the GO addition; however, depending on the treatment of the GO an increase or decrease was observed for the glass transition temperature. The change in glass transition was a result of changes in the curing behavior. Addition of GO initially increased the curing speed; however, the final curing degree was lower and was dependent on the type of GO added. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43591. 相似文献
148.
It is demonstrated for the first time that an epoxy thermoset resin can be cured at temperatures well below its Tg∞. This study compared the use of a uniform variable frequency microwave (VFM) field to standard oven curing at temperatures above and below Tg∞. Using Tg, tan δ, modulus, and FTIR measurements, it is shown that the reaction of BFDGE with MDA to attain a product with Tg∞ of 133 °C is achieved by VFM at temperatures from 100 to 140 °C; in contrast, the thermal cure normally requires 170 °C to attain the same Tg∞ and the same extent of cure. By following the pregel cure reaction with 13C‐NMR spectroscopy, it was determined that the lower cure temperatures of VFM cure predominately lead to chain extension and smaller amounts of crosslinking compared to the thermal cure. To explain these results, it is suggested that, after gelation, with VFM cure there is higher mobility from dipole rotations that continues the cure to completion without vitrification. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44222. 相似文献
149.
Effect of copper sulfate pentahydrate on the structure and properties of poly(vinyl alcohol)/graphene oxide composite films
下载免费PDF全文
![点击此处可从《应用聚合物科学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Poly(vinyl alcohol) (PVA)/graphene oxide (GO)/copper sulfate pentahydrate (CuSO4·5H2O) composite films were prepared by the solution casting method, and the effect of CuSO4·5H2O on the structure and properties of the PVA/GO composites was investigated. Fourier transform infrared (FTIR) analysis proved the crosslinking interaction between CuSO4·5H2O and the ? OH group of PVA. The crystallinity of the composite films increased first and then decreased. For the composite films, the tensile strength, Young's modulus, and yield stress values improved with increasing CuSO4·5H2O, whereas the elongation at break decreased compared with that of the neat PVA/GO composite film. The thermogravimetric analysis (TGA) and derivative thermogravimetry (DTG) patterns of the PVA/GO/CuSO4·5H2O composite films showed that the thermal stability decreased; this was consistent with the TGA–FTIR analysis. A remarkable improvement in the oxygen‐barrier properties was achieved. The oxygen permeability coefficient was reduced by 60% compared to that of the neat PVA/GO composite film. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 44135. 相似文献
150.
Kinetics modeling of carbon‐fiber‐reinforced bismaleimide composites under microwave and thermal curing
下载免费PDF全文
![点击此处可从《应用聚合物科学杂志》网站下载免费的PDF全文](/ch/ext_images/free.gif)
This article focuses on the analysis of the curing kinetics of carbon‐fiber‐reinforced bismaleimide (BMI) composites during microwave (MW) curing. A nonisothermal differential scanning calorimetry (DSC) method was used to obtain an accurate kinetic model. The degree of curing, chemical characterization, and glass‐transition temperature of the resin and composites cured by thermal and MW heating were analyzed with DSC, Fourier transform infrared spectroscopy, and dynamic mechanical analysis. The experimental results indicate that MW accelerated the crosslinking reaction of the BMI resin and had different effects on the reaction processes, especially for the glass‐transition temperature and chemical bonds. However, the curing reaction rate of the BMI resin decreased when the carbon fibers were added to the BMI resin during thermal and MW curing. According to the experimental results, the curing kinetic model of the BMI composite was used to provide a theoretical foundation for MW curing analysis. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133, 43770. 相似文献