电镀镍铁合金高整平性光亮剂的研究

简述电镀镍铁合金工艺中光亮剂的发展概况,介绍高整平性光亮剂 ABSN 的研究。试验表明:ABSN 具有高整平性,高光亮性,出光速度快(3—5min),光亮范围宽(0.5—10A/dm~2),耗量低(60—80mL/kAh),产生的镀层韧性好。     

Alternative tribological coatings to electrodeposited hard chromium: a critical review

ABSTRACT

The traditional importance of hard chromium electroplating in surface engineering is recognised and the key features of this well-established technology are summarised. Despite the high hardness, corrosion protection and wear resistance of chromium electrodeposits, a number of alternative coating compositions and application techniques have been developed for specific applications in tribology. Environmental challenges associated with hard chromium electroplating are highlighted and the need to develop and evaluate alternative coatings is stressed. Key examples of the alternative coatings are described, including their method of application, microstructure and tribological performance in controlled service environments. Research needs requiring rapid development are highlighted. A summary is given of the most competitive coatings and those having the potential to match the performance of hard chromium in selected applications are identified.     

光亮碱性Zn-Al合金电镀工艺研究

在碱性锌酸盐镀锌液中加入铝盐，研究成功了一种光亮碱性锌铝合金电镀工艺。采用霍尔槽试验探讨了镀液成分和工艺条件对镀层质量的影响，检测了镀液和镀层性能。研究结果表明：镀液阴极电流效率达到80%以上，镀液分散能力和复盖能力好，镀层中铝含量为1．5％左右，所形成的Zn-Al合金镀层结晶细致、光亮度好、结合力好、耐蚀性优良，适用于作高耐蚀性镀层。     

Metallographic sample prepared by ion beam etching

Ion beam etching technique was used to reveal the metallograhpic microstructure and interface morphology of electroplating chromium coating, in particular, whose substrate surface layer was treated in advance by laser quenching. Chemical etchings were also conducted for comparison. The reveal microstructures were observed and analyzed by scanning electron microscopy. The results show that ion beam etching can reveal well the whole microstructures of composite coating-substrate materials.     

硬齿面齿轮珩齿刀制造新工艺的研究

开发了电镀CBN埋砂法结合高温热扩散法制做硬齿面齿轮珩齿刀的新工艺。对影响珩齿刀寿命的最大因素-CBN复合镀层与基体的结合力进行了研究。对电流密度，温度和pH值进行了合理选择。实验表明：在置砂中应将电流密度控制在0．25A/dm^2左右，温度控制在恒温40℃左右，pH值控制在3．5-6．0之间。在真空热扩散中，将最高温度控制在650℃以内，既使基体变形误差达到要求，又使CBN复合镀层与基体达到了“半冶金化”结合。在剃齿机上用所制作的珩齿刀加工齿轮的实验证明，达到所需的结合力。     

无氰电刷镀金技术在航天工业中的应用

应用FJY-18无氰电刷镀金技术制得的金镀层具有孔隙率低、色泽金黄、光亮、结合力好,镀厚能力大于20μm,显微硬度HV=130～150,施工温度范围宽、无毒等特点,该技术已用于航天工业中某一关键部件的表面减磨密封镀金.     

铝合金表面处理技术新进展

简要介绍了铝合金表面处理技术的新进展,重点介绍了铝合金的阳极氧化、电镀、化学镀和微弧氧化、激光熔覆等工艺.     

稳恒磁场下Ni-W合金镀膜的制备与耐蚀性

研究了施加稳恒磁场(0~1 T)对电镀Ni-W合金的影响。测定不同方向、不同强度稳恒磁场下的电流效率、合金组成及镀层的耐蚀性,并用扫描电镜和X射线衍射对镀层的微观形貌及结构进行了观察和分析。对实验结果进行了分析讨论,找出稳恒磁场对这些性能指标的影响规律。结果表明:与不施加磁场相比,施加磁场后镀层的表面更均匀、细致、平整;镀层的含钨量上升:当B⊥J,B=1.0 T时,含钨量上升了约7%;当B∥J,B=1.0 T时,含钨量上升了约9%;镀膜的非晶化程度增强;镀膜的耐蚀性提高;但Ni-W合金电镀的电流效率降低。     

摩擦喷射纳米Al2O3/Ni复合镀层的组织形貌及其性能研究

采用摩擦喷射电沉积工艺制备了纳米Al2O3／Ni复合镀层，考察了该镀层的表面和断面形貌，并对镀层性能进行了测试分析。研究表明，摩擦喷射纳米Al2O3／Ni复合镀层表面较为平整，镀层与基体结合紧密。一次性镀覆厚度达到1．40mm，远高于电刷镀纳米Al2O3／Ni复合镀层（0．35mm），镀层硬度达到650HV。在试验条件下，该镀层的耐磨性是摩擦喷射Ni镀层的1．44倍，是纳米Al2O3／Ni刷镀层的1．15倍，摩擦因数也低于摩擦喷射Ni镀层和电刷镀纳米Al2O3／Ni复合镀层。     

电镀废水处理站DTCR辅助氢氧化物沉淀工艺改造

某废水处理站改造前采用传统氢氧化物沉淀工艺处理高浓度含铬、氰镉电镀废水,运行不稳定,出水不能达标排放。工艺改造后增加了高分子重金属捕集沉淀剂DTCR辅助去除重金属,在含铬废水DTCR投加量为50 mg/L、含氰镉废水DTCR投加量为10 mg/L条件下,出水总铬、镉分别稳定在0.5 mg/L、0.2 mg/L以下,远低于《电镀污染物排放标准》(GB 21900—2008)限值。