Interactions between Cytochrome c and DNA Strands Self-Assembled at Gold Electrode

In this work, we reported the investigation on the interaction between DNA strands self-assembled at gold electrodes and an electron transfer protein, cytochrome c. We observed that cytochrome c exhibited well-defined electrochemistry in both double-stranded and single-stranded DNA films. This suggested that the electron transfer reaction of cytochrome c arose possibly due to the electron hopping along DNA strands rather than wiring along the double helix. We also compared the heterogeneous electron transfer rate of cytochrome c with that of a ruthenium complex, which further confirmed this mechanism.     

基于SOA的建筑设备物联网体系架构研究

为解决建筑设备物联网系统集成异构的建筑自动化子系统（如：中央空调系统、恒压供水系统、门禁系统等）和整合数据信息资源等问题,文中针对建筑设备物联网系统的自身特点,提出一种基于SOA的建筑设备物联网体系架构模型。重点阐述了该模型的架构组成和层次结构,并将该架构模型应用于建筑用电设备的物联网系统中。实验结果表明,基于SOA架构的建筑设备物联网能够有效整合物联网系统异构平台,且能够提高系统的安全性、可扩展性和互操作性。     

基于循环自相关的NC-OFDM信号参数的盲估计

在认知无线电(CR)环境中,频率资源不足的问题越来越严重,非连续正交频分复用（NC-OFDM）能够工作在非连续的频谱环境,针对NC-OFDM信号的参数估计重要问题,提出用循环自相关的方法。该方法首先分析循环平稳信号特点,然后根据NC-OFDM信号的循环自相关在循环频率α以及时延τ切面图具有离散谱线特征进行参数估计,最后对NC-OFDM信号的循环自相关进行数值仿真。仿真结果表明在低信噪比下,能有效估计NC-OFDM信号的参数及识别零前缀的正交频分复用信号（ZP-OFDM）,且实验证明关闭近90%的子载波数目,都能够实现NC-OFDM信号的参数的盲估计。     

取代基及分子量对非离子型纤维素醚表面特性的影响

根据Washburn的浸渍理论(Penetration Theory)和van Oss-Good- Chaudhury的组合理论(Combining Theory)及应用柱状灯芯技术(Column Wicking Technique),对几种非离子型纤维素醚,如甲基纤维素、羟丙基纤维素和羟丙基甲基纤维素的表面特性进行了测试。由于这些纤维素醚的取代基、取代度和分子量不同,所以它们的表面能及其组成部分有着明显的差异。数据说明,非离子型纤维素醚Lewis碱大于Lewis酸,表面自由能的主要成分是Lifshitz-van der Waals力。羟丙基的表面能及其成分都大于羟甲基。而在相同取代基和取代度的前提下,羟丙基纤维素的表面自由能正比于分子量;而羟丙基甲基纤维素的表面自由能则正比于取代度,反比于分子量。实验还发现非离子型纤维素醚中的取代基羟丙基和羟丙基甲基的表面能似乎都大于纤维素的表面能,而实验证明所测试得出的纤维素的表面能及其成分的数据是与文献所吻合的。     

A study on cashew nut oil composition

Eight samples of cashew nut oil were assayed, and the component triacylglycerols, fatty acids and several unsaponifiable compounds were analyzed by gas chromatography (GC) and high-performance liquid chromatography (HPLC). Total lipid amount, unsaponifiable percentage, fatty acids, sterols, triterpene alcohols and tocopherols are reported here. The combination of GC and HPLC enhanced the resolution of compound classes.     

花岗岩残积土-土工格栅界面的后循环剪切行为研究

花岗岩残积土在华南、东南沿海、南岳、新疆等地区广泛分布,前人的研究多集中在结构性及微观特性上,后循环加载、位移演化、土壤密度等因素对筋-土界面的剪切特性及加筋作用效果的影响评估研究较少。从循环试验剪切刚度这一重要参数入手,以加载次数、加载频率值、位移振幅值、土壤重度值为自变量,应用控制变量法,通过设计循环直剪试验,得到加筋花岗岩残积土的剪切应力与剪切位移、垂直位移与剪切位移关系曲线进行观察对比,结果表明:花岗岩残积土土工格栅界面剪切刚度受位移半振幅、土壤干重度影响很大,受加载频率影响很小,循环加载并没有弱化后循环界面剪切强度,剪切位移与位移半振幅呈负相关关系。     

陶瓷部件挤出成型工艺

本文以蜂窝陶瓷生产工艺为例，讨论了陶瓷部件挤出成型过程中，塑性泥料的制备、成型、干燥和烧成等工艺技术和装备问题。     

The Bromine Electrode. Part I: Adsorption Phenomena at Polycrystalline Platinum Electrodes

A cyclic voltammetric study of the behaviour of Br^– and Br^– ₃ at Pt electrodes, in the potential range between hydrogen and oxygen evolution, is described. Different experiments were carried out, in the presence of Br^– and Br^– ₃, in which the ratio between the species has been kept constant and equal to 1. The halide concentration was varied between 4 × 10^–6 and 1 × 10^–3 and mol dm^–3, at constant ionic strength, in 1 M HclO₄ as well as in 1 M NaClO₄ adjusted to a pH of 2. Underpotential deposition of Br is observed at potentials as low as –0.125 V vs SCE. The adsorption parameters of Br species were determined from the adsorption/desorption peak pair in the hydrogen adsorption/desorption region, and from the oxide reduction peak data. In the absence of oxygen adsorption, a relatively high coverage of the electrode surface is attained. A Langmuir-type adsorption is observed under the different experimental conditions.     

纳米超强酸SO4^2TiO2催化合成苯乙酮环乙二缩酮

以纳米固体超强酸SO42-/TiO2为催化剂,通过苯乙酮和乙二醇反应合成苯乙酮环乙二缩酮。实验结果表明,纳米固体超强酸SO42-/TiO2是合成苯乙酮环乙二缩酮的良好催化剂,最佳反应条件如下:酮醇物质的量比为1∶1.2,催化剂用量为0.5g/0.1mol苯乙酮,反应时间为80min,产率可达99.3%。     

现代汽车非金属部件的修补涂装

介绍了汽车塑料件的识别、预处理和修补涂装。