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11.
《Ceramics International》2021,47(21):29681-29687
Inorganic piezoelectric ceramic composite is the potential sensing element for long-term structural health monitoring due to its excellent durability and compatibility. In this study, a Ceramicrete-based piezoelectric composite is proposed preliminarily, in which the magnesium potassium phosphate cement is used as the matrix and the lead zirconate titanate particle is utilized as the functional phase. Piezoelectric properties test and microstructure analysis are performed to evaluate the testing samples. Results show that the piezoelectric performance of the composite increase with the increase of piezoelectric ceramic particle size. The value of the piezoelectric strain factor (d33) can reach 83.8 pC/N, while the corresponding piezoelectric voltage factor (g33) is 50.1 × 10-3 V•m/N at the 50th day after polarization. Microstructure analysis illustrates that the interfacial transition zone (ITZ) between the matrix and the particles is dense. Moreover, the influence of aging on the composite is attributed to the continuous hydration after polarization. It indicates that the composites have a higher piezoelectric performance, which can be regarded as a promising sensing element material. 相似文献
12.
Xiaoyuan Sun Zixuan Liu Hao Qian Yunfei Liu Yinong Lyu 《Ceramics International》2021,47(17):24207-24217
A strategy that constructs the morphotropic phase boundary and manipulates the domain structure has been used to design the component of 0.96[Bi0.5(Na0.84K0.16)0.5Ti(1-x)NbxO3]-0.04SrTiO3 (BNKT-4ST-100xNb) to enhance the strain properties for actuator application. Non-equivalent Nb5+ donor doping modulates the phase transition from the mixture of rhombohedral and tetragonal phases to the pseudocubic phase and results in the coexistence of multiple phases. Moreover, the high-resolution TEM confirms the existence of polar nano regions that contribute to the macroscopic relaxor behaviour. The size of the domains is reduced with increasing Nb5+, resulting in an enhanced relaxor behaviour. The ferroelectric-relaxor transition temperature decreases from 85 to below 30 °C, implying a non-ergodic to ergodic relaxor transition. An improved strain of 0.56% and a giant normalized strain of 1120 pm/V were achieved for BNKT-4ST-1.5Nb, which were attributed to the unique domain structure in which nanodomains are embedded in an undistorted cubic matrix. Ferroelectric, antiferroelectric, and relaxor phases coexist. As the electric field is large enough, a reversible phase transition occurs. Furthermore, good temperature stability was obtained due to the stability of the nanodomains, and no degradation in strains was observed even after 104 cycles, which may originate from the reversible phase transition and dynamic domain wall. The results show that this design strategy offers a reference way to improve the strain behaviour and that BNKT-4ST-100xNb ceramics could be a potential material for high-displacement actuator applications. 相似文献
13.
Valentin Jolivet Yann Morizet Jonathan Hamon Michael Paris Tomo Suzuki-Muresan 《Journal of the American Ceramic Society》2021,104(3):1360-1369
The glass transition temperature (Tg) is a key parameter to investigate for application in nuclear waste immobilization in borosilicate glasses. Tg for several glasses containing iodine (I) has been measured in order to determine the I effect on Tg. Two series of glass composition (ISG and NH) containing up to 2.5 mol% I and synthesized under high pressure (0.5 to 1.5 GPa) have been investigated using differential scanning calorimetry (DSC). The I local environment in glasses has been determined using X-ray photoelectron spectroscopy and revealed that I is dissolved under its iodide form (I−). Results show that Tg is decreased with the I addition in the glass in agreement with previous results. We also observed that this Tg decrease is a strong function of glass composition. For NH, 2.5 mol% I induces a decrease of 24°C in Tg, whereas for ISG, 1.2 mol% decreases the Tg by 64°C. We interpret this difference as the result of the I dissolution mechanism and its effect on the polymerization of the boron network. The I dissolution in ISG is accompanied by a depolymerization of the boron network, whereas it is the opposite in NH. Although ISG corresponds to a standardized glass, for the particular case of I immobilization it appears less adequate than NH considering that the decrease in Tg for NH is small in comparison to ISG. 相似文献
14.
《International Journal of Hydrogen Energy》2022,47(19):10747-10761
To obtain the mixing enhancement mechanism of H2–Water combined jets in supersonic crossflows in a combustor with expanded section for rotating detonation ramjet, the flow field shape and spray structure were studied by experimental and numerical methods. The Eulerian–Lagrangian method was used to investigate the diffusion mechanism and H2–Water interaction law of combined jets with different sequences. At the same time, high-speed photography and the schlieren technique were used to capture the flow field. The effects of jet pressure drop, orifice diameter, orifice spacing, incoming Mach number, and other parameters on the penetration depth of water jets were studied. The results of experiment and simulation show that using H2–Water combined jets, the penetration depth of the jet spray can be greatly increased and the jet mixing effect can be significantly improved, which will contribute to the engine's ignition and stable combustion. In the case of pre-water/post-H2, the penetration depth of the hydrogen jet is greater. In the case of pre-H2/post-water, the hydrogen jet raises the water spray mainly by protecting the integrity of the water column. 相似文献
15.
《Journal of the European Ceramic Society》2020,40(1):56-62
In this work, 0.2 wt.% Mn-doped (1-x)AgNbO3-xBi0.5Na0.5TiO3 (x = 0.00–0.04) ceramics were synthesized via solid state reaction method in flowing oxygen. The evolution of microstructure, phase transition and energy storage properties were investigated to evaluate the potential as high energy storage capacitors. Relaxor ferroelectric Bi0.5Na0.5TiO3 was introduced to stabilize the antiferroelectric state through modulating the M1-M2 phase transition. Enhanced energy storage performance was achieved for the 3 mol% Bi0.5Na0.5TiO3 doped AgNbO3 ceramic with high recoverable energy density of 3.4 J/cm3 and energy efficiency of 62% under an applied field of 220 kV/cm. The improved energy storage performance can be attributed to the stabilized antiferroelectricity and decreased electrical hysteresis ΔE. In addition, the ceramics also displayed excellent thermal stability with low energy density variation (<6%) over a wide temperature range of 20−80 °C. These results indicate that Mn-doped (1-x)AgNbO3-xBi0.5Na0.5TiO3 ceramics are highly efficient lead-free antiferroelectric materials for potential application in high energy storage capacitors. 相似文献
16.
AbstractDifferent drying methods (spray drying (SD), vacuum drying (VD), microwave vacuum drying (MVD), and infrared vacuum drying (IFVD)) were applied in order to compare the hygroscopicity behavior of chicken powders. The hygroscopicity curves and glass transition temperature were used to evaluate the influence of ambient humidity and temperature on moisture absorption of powders. The results showed that the chicken powder dried by MVD had the lowest moisture absorption, followed by IFVD, VD, and SD. The hygroscopicity of SD chicken powders was different from other three kinds of chicken powders due to the physical properties of particles and the changes of protein secondary structure as detected by the Fourier transform-infrared spectrometer. For the three vacuum drying methods, the difference of protein secondary structure was the main reason of differences in hygroscopicity. Although MVD chicken powders were slightly inferior to SD chicken powders in taste, MVD chicken powders were the best in terms of smell and color as suggested by instrumental sensory parameter evaluations. It was found that MVD had a positive effect on reducing moisture absorption and maintaining sensory quality of chicken powders. 相似文献
17.
18.
This paper investigates the relationship between economic growth, carbon dioxide (CO2) emissions, and energy consumption with an aim to test the validity of the Environmental Kuznets Curve (EKC) hypothesis in five ASEAN (Association of South East Asian Nations) countries (Indonesia, Malaysia, Philippines, Singapore, and Thailand) by applying the panel smooth transition regression (PSTR) model as a new econometric technique. The PSTR model is more flexible and appropriate for describing cross-country heterogeneity and time instability. Our empirical results strongly rejected the null hypothesis of linearity, and the test for no remaining nonlinearity indicated a model with one transition function and two threshold parameters. The first regime (levels of GDP per capita below 4686 USD) showed that environmental degradation increases with economic growth while the trend was reversed in the second regime (GDP per capita above 4686 USD). The results also showed that energy consumption with either the first or the second regime lead to increase CO2. The overall results support the validity of the EKC hypothesis in the ASEAN countries. 相似文献
19.
Su-Il Ri Song-Il Hong Jong-Chol Kim Ju-Hyok Wi 《International Journal of Hydrogen Energy》2021,46(5):3319-3328
We investigated some properties of the hydride Mg2FeH6 substituted with yttrium by a first principles calculation. Some experimental results showed that 4d transition metal, yttrium serves as a good catalyst for magnesium based hydrogen storage alloys, but there are a few theoretical studies about magnesium based hydrides substituted with it. Mg2FeH6 is regarded as a cheaper material than pure MgH2, while it is crystalized into Fm3m structure (space group 225). Although it has high hydrogen storage capacity, many investigations have not been devoted to it due to its extremely high thermodynamic stability. The yttrium substituted Mg2FeH6 exhibits very low energy of formation, and its desorption temperature, 75 °C is very suitable for practical hydrogen storage applications. Our results showed that Mg2FeH6 is destabilized effectively by yttrium substitution and introducing vacancy defects has additive effect to the improvement of dehydrogenation performance. 相似文献
20.
Roberto Zefferino Claudia Piccoli Sante Di Gioia Nazzareno Capitanio Massimo Conese 《International journal of molecular sciences》2021,22(5)
Connexin- and pannexin (Panx)-formed hemichannels (HCs) and gap junctions (GJs) operate an interaction with the extracellular matrix and GJ intercellular communication (GJIC), and on account of this they are involved in cancer onset and progression towards invasiveness and metastatization. When we deal with cancer, it is not correct to omit the immune system, as well as neglecting its role in resisting or succumbing to formation and progression of incipient neoplasia until the formation of micrometastasis, nevertheless what really occurs in the tumor microenvironment (TME), which are the main players and which are the tumor or body allies, is still unclear. The goal of this article is to discuss how the pivotal players act, which can enhance or contrast cancer progression during two important process: “Activating Invasion and Metastasis” and the “Avoiding Immune Destruction”, with a particular emphasis on the interplay among GJIC, Panx-HCs, and the purinergic system in the TME without disregarding the inflammasome and cytokines thereof derived. In particular, the complex and contrasting roles of Panx1/P2X7R signalosome in tumor facilitation and/or inhibition is discussed in regard to the early/late phases of the carcinogenesis. Finally, considering this complex interplay in the TME between cancer cells, stromal cells, immune cells, and focusing on their means of communication, we should be capable of revealing harmful messages that help the cancer growth and transform them in body allies, thus designing novel therapeutic strategies to fight cancer in a personalized manner. 相似文献