The initial behaviour of freshly etched copper in moderately acid, aerated chloride solutions

When freshly etched samples of various types of copper were exposed in moderately acid, aerated chloride solutions, two phenomena were observed. First the corrosion potential and the pH of the solution decreased over a shorter time, then the potential increased over a long period (600-1500 min), following an s-shaped pattern. Increase in pH during the second stage was avoided using a pH-stat. The corrosion rate increased little or not at all over the entire period. A tentative interpretation of the short-term behaviour is presented with some reservation. The long-term development of the potential suggests phase formation or transformation following the Avrami pattern. By suitable derivations it was possible to fit the development of potentials to the Avrami equation. Subsequent examinations by Auger spectroscopy proved the presence of thin layers of Cu₂O on the copper surfaces, increasing in thickness with exposure time. The dissolution kinetics can be described in terms of two parallel electrochemical reactions and a simultaneous non-electrochemical dissolution reaction.     

长输管道外防护层的选择与应用

文章介绍了目前国内外长输管道外防护技术的特点和防护层应用的现状,分析了常用防腐蚀材料的防腐蚀性能。指出在山区复杂地形条件下,应考虑环境条件和施工条件,并通过技术经济分析对管道外防腐蚀层进行合理选择。     

Co-evolution as a computational and cognitive model of design

Co-evolutionary design has been developed as a computational model that assumes two parallel search spaces: the problem space and the solution space. The design process iteratively searches each space using the other space as the basis for a fitness function when evaluating the alternatives. Co-evolutionary design can also be developed as a cognitive model of design by characterizing the way in which designers iteratively search for a design solution, making revisions to the problem specification. This paper presents the computational model of co-evolutionary design and then describes a protocol study of human designers looking for evidence of co-evolution of problem specifications and design solutions. The study shows that co-evolutionary design is a good cognitive model of design and highlights the similarities and differences between the computational model and the cognitive model. The results show that the two kinds of co-evolutionary design complement each other, having strengths in different aspects of the design process. Electronic Publication     

直扩接收机基带迟早门跟踪环的简化设计

针对要求设计简化、资源有限的设备和系统 ,通过对直扩接收机基带迟早门跟踪环的性能分析 ,在扩频增益比较大时 ,提出了一种简化设计结构 ,用两个由扩频码的部分序列构成的相关器分别替代原来早门和迟门的完全序列相关器。仿真表明该结构在给定足够的相关值情况下 ,性能略有恶化 ,但资源却得到较大节约 ,设计可大大简化。     

High‐Tech‐Cellulose‐Funktionspolymere nach dem ALCERU®‐Verfahren

Functional High‐Tech‐Cellulose materials by the ALCERU® process Cellulose is one of the eldest materials of mankind. While the use of cellulose in former times was focused on application as a more construction or as a more textile material at present time the application profile turns to a more functional material using the ALCERU® process. Shaping of pure cellulose dissolution in NMMNO permits the manufacturing of materials for upholstery, filtration or biodegradable film strips having an uniform cross section. Fibreds, which can be applied in several packaging materials, are available using different techniques for regeneration cellulose. A great field of innovative functional cellulose materials is opened up by addition of several functional additives to cellulose dissolution. In this way piezo‐electrical conductive cellulose fibres (PZT) or high‐temperature filtration membranes are to be generated if one adds special types of ceramic powders. Above all PZT green fibres are applied in more recent uses as sensors or actuators. Electrically conductive cellulose fibres or filaments, which can be also used in the textile chain, can be prepared adding conductive carbon black to a cellulose dope on the same way, too. Cellulose material having adapted conductivity to different application is available by adding an exact defined amount of carbon black to cellulose dissolution. Finally cellulose beads can be manufactured by means of varied shaping technique. The beads are showing variable particle sizes and narrow pore size distribution. These properties open up very interesting application in the field of human blood purification or chromatography.     

水工钢闸门聚酯玻璃钢复合防腐处理方法

水环境的恶化，使水工钢闸门腐蚀加重，传统的防腐工艺保护效果下降。聚酯玻璃钢复合防腐层的水工钢闸门防腐工艺具有使用设备少，工艺简单、防腐效果好、成本低等优点，适用于在各种水环境中作各种形式的水工钢闸门防腐，效果良好。该文结合江苏省淮海农场工程施工经验，提出了水工钢闸门聚酯玻璃钢复合防腐层结构设计、施工工艺及质量标难，为今后的推广应用提供了一定的参考依据。     

估计小波系数方差邻域大小的研究

利用小波变换去噪时小波系数方差的估计对去噪结果影响很大。自然图像小波分解后得到的系数在不同的分辨率中差异很大,所以利用邻域估计中心点方差时,不同分辨率应有不同大小的邻域。首先对在邻域中利用极大似然准则估计中心点方差进行分析,再结合自然图像小波分解后的系数在不同分辨率子带中,根据平稳性和重要性选择邻域的大小。最后进行去噪实验,并取得正交小波分解下理想的去噪性能。     

Accidents,often the result of an ‘uncontrolled business process’—a study in the (Dutch) chemical industry

Often companies in the (petro‐) chemical industry claim that all possible countermeasures against potential accidents have been taken and therefore accidents are unforeseeable. In this paper we question this statement by analysing the pre‐warning signals (precursors) preceding a number of industrial accidents. 17 accidents that occurred in the (petro‐) chemical industry have been investigated by exploring FACTS, an accident database containing information about industrial accidents worldwide. This paper will demonstrate that the existence of precursor information could have been used to foresee and even prevent these accidents if a proper control action had been initiated. The accidents are analysed further, according to a control model, which was adapted from that of C. Argyris. It demonstrates the ineffectiveness of several elements of business process control loops and that the so‐called ‘double‐loop learning’ cycle is more important than the ‘single‐loop learning’ cycle if one considers safety improvement. Copyright © 2003 John Wiley & Sons, Ltd.     

骑马岭水电站砂石加工系统规划设计

介绍了骑马岭水电站砂石加工系统的料源规划、系统规划设计、系统工艺流程及环保措施。该加工系统采用的典型的二段破碎工艺，对中小型水电站混凝土骨料生产系统的设计具有一定的参考价值。同时，该加工系统在废水处理水回收利用及细砂与石粉回收、防尘、降低噪声，以及固体废弃物处置等方面，均采取了相应的环保措施，以减少其对施工人员和周围环境的影响。     

塔里木河流域源流及干流水均衡分析

通过对塔里木河流域源流及干流的径流变化和水均衡分析 ,表明塔里木河源流来水基本稳定 ,由于源流灌区引水以及渗漏蒸发等损失加剧 ,干流水量存在减少趋势 ,并加剧了水量的时间分配不均 ,不利于干流农业的可持续发展和生态环境的维护与改善