Photopolymerization of N,N‐dimethylaminoethylmethacrylate studied by photocalorimetry

Photopolymerization of dimethylaminoethylmethacrylate (DMAEMA) is studied in bulk and in solutions in the presence of different photoinitiators using differential photocalorimetry (DPC). The rate of DMAEMA photopolymerization is slow compared to that of alkylmethacrylates. Bimodal DPC curves of DMAEMA photopolymerization in bulk are obtained. The type I photoinitiators (IRGACURE® 651 and IRGACURE® 1700), which produce free radicals by homolytic fragmentation of photoexcited molecules, are more effective in promoting photopolymerization of DMAEMA. The type II photoinitiators (benzophenone and IRGACURE® 500), which initiate DMAEMA photopolymerization through an H‐abstraction mechanism involving an amino group from the monomer (polymer), are less efficient and favor the formation of partly crosslinked products. The effects of the photoinitiator concentration, temperature, and solvent on the kinetic data are evaluated and discussed. A scheme of photopolymerization of DMAEMA, including the formation of intermediate DMAEMA based macromonomers, is proposed. The main point of the suggested scheme is a high chain transfer to the DMAEMA monomer. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 579–588, 2002     

Ionomer composites based on sepiolite/hydrogenated poly(styrene butadiene) block copolymer systems

Ionomeric composites based on sepiolite and hydrogenated poly(styrene butadiene) block copolymer were obtained and characterized from a microstructural and electrical point of view. Before blending, because of the high silanol group concentration in the sepiolite, the latter could be organophilized with suitable coupling agents. The resulting materials were easily processed into thin films or membranes 0.2–0.4 mm thick, their conductivity in some cases approaching 10^?1 S/cm. Their suitability for film formation and good electrical properties indicate potential applications as electrolytes in polymer fuel cells. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3512–3519, 2002     

一种视频信号压缩编码方法的研究

文章采用自适应预测编码加熵编码的复合编码方法，对视频信号进行压缩编码。计算机模拟结果表明，压缩比为3.5：1（2.25bits／Pixel）时可获得良好的图像质量，因此，可实现在PCM三次群信道上传输一路彩色电视信号。     

BCC金属Nb的重离子辐射损伤研究

采用81 MeV碳离子辐照,模拟中子注量为10~(23)/cm~2的堆中子在Nb中产生的辐射损伤,用时间微分扰动角关联和正电子湮没二种方法研究辐射损伤及其高温退火效应。实验发现经注量2.5×10~(16)/cm~2的碳离子辐照后,在BCC金属Nb中产生单空位和双空位二种缺陷。随退火温度升高,双空位分解,单空位的总浓度逐步减小,经过1058K退火后,在Nb中由辐射损伤造成的缺陷消失。     

关于蒸汽疏水器规格尺寸选择的探讨

本文依据疏水器作用原理和实践经验对影响选择疏水器规格尺寸的主要因素进行了分析。提出:选择疏水器应排凝水量大,选择倍率适当,符合产品样本的最大、最小工作压力,准确确定其前后压力。     

磁偏转电子枪研制核靶

文章叙述了磁偏转电子枪的原理和结构以及用ＥＱＤ－３型电子枪研制各种核靶的工艺过程。     

群时延精确设计的全差分四阶Bessel滤波器

采用MOS管有源电阻,提出了一种全差分R-MOSFET-C四阶Bessel有源低通滤波器,.通过调节工作于亚阈值区的CMOS管的沟道导纳补偿电阻值的大小,能抵消集成电路制造工艺中电阻值的一致偏差,实现Bessel有源滤波器群时延的精确设计.根据无源滤波器的状态方程完成有源滤波器的综合,应用3.3V,0.5μm CMOS工艺完成了群时延大小为0.75μs的四阶Bessel低通滤波器的管极计算机仿真,仿真结果表明所提电路正确有效,适于全集成.     

Mathematical analysis of viscometric (polymer) flow fields in capillaries: Taylor dispersion revisited

A general formulation for capillary flow of two miscible fluids – one a dilute plug of polymer fluid inserted into a fully developed Poiseuille flow of the other, a Newtonian stream – is examined for its long time behavior. Phenomenologically, the system evolves from an initial state, that of a plug within the boundaries of sharp, well defined fronts inside a Newtonian stream, to a more homogenized state in the very long time scale. This problem was addressed by G.I. Taylor but with regard to a system of two Newtonian fluids, leading to the well-known results commonly described as `Taylor axial dispersion'. In this paper, a general and systematic perturbation analysis is presented from which Taylor's result is recovered as a special case of a more general solution which applies to fluids incorporating elastic properties. In particular, the influence of viscoelasticity and (polymer) diffusivity on the observed pressure profile in the capillary conduit is examined. This effect is clearly separated out for small Peclet number flows using asymptotic and numerical analysis. The results identify the influence of fluid viscosity, elasticity, and diffusivity on the observed pressure profile and form the basis for the improved characterization of polymeric elasticity using capillaries – a finding that is of significant scientific and commercial interest. These results were obtained by the authors as a class of observations resulting from the perturbation analysis of forced-flow capillary devices in viscoelastic fluid property investigation.     

水平井眼轨迹对气井出砂趋势及工作制度的影响

出砂是影响油气井正常生产的重要因素之一。借助FEPG有限元程序自动生成平台，建立了三维应力场弹塑性地层出砂模型，并运用有限元法计算分析了不同轨迹的裸眼井井壁周围的有效塑性应变分布规律及出砂趋势，研究了气藏压力衰竭对完井方式的影响。研究表明，水平井眼轨迹对出砂有重要的影响，同一地应力环境下向不同方位延伸的水平井在投产时应该采取不同的生产压差和不同的生产制度，水平井眼轨迹对出砂的影响程度随着3个地应力差异的增大而加剧。气藏压力衰竭对井壁的稳定性和出砂趋势都有重要影响。随着气藏压力的衰竭，井壁稳定性将变得越来越差，最终导致井筒出砂。因此，对气井完井不仅应该考虑到气藏开发初期地层的稳定性状况，而且还应该考虑到气藏压力衰竭后可能出现的井壁失稳问题。     

苯和甲苯差分吸收光谱方法的实验室测量研究

本文介绍了差分光学吸收光谱法(DOAS)测量大气污染气体浓度的基本原理。DOAS方法就是利用氙灯发出的紫外—可见光，经望远镜准直后再经过一段距离的传输，由望远镜来接收．在传输中，由于各种不同的分子在不同的波段对光有不同的吸收特征，使光谱具有了污染物的特征，再通过与光源发出的光进行比较，反演这些气体在大气中浓度．我们将DOAS方法应用在监测有机物上，在分析光谱的过程中，应用多项式拟合和最小二乘法，从而精确地从测量光谱中来反演出大气中污染气体的浓度．文中用DOAS方法测量了苯和甲苯的样品，并分析了结果，结果和理论吻合．可为环境中有机污染物监测提供可靠的方法。