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21.
Theprecipitationofpro eutectoidferritefromausteniteiscontrolledbydiffusioninFe Calloys .Withtheassumptionthatthemigratinginterfaceisalwaysinlocalequilibrium ,earlyin 194 9,ZenerC[1] explainedthediffusionalgrowthofpro eutec toidferritebyusingtheFick’slaw .Since… 相似文献
22.
原始组织及加热方式对Al-5.8wt%Cu合金熔化行为的影响 总被引:3,自引:0,他引:3
利用DSC分析手段,研究了具有3种不同凝固组织的Al-5.8wt%合金在7种不同加热方式下的熔化开始温度和熔化热,发现凝固组织中存在的非平衡共晶在加热过程中大部分扩散溶解,溶入基体,剩余部分参与共晶熔化,其熔化开始温度与组织状态无关,随加热速度的增大略有升高,溶解部分的体积分散与组织状态和加热方式有关,随加热时间和非平衡相表面积的增大而增大。 相似文献
23.
David Nistr Karin Keis Sten-Eric Lindquist Anders Hagfeldt 《Solar Energy Materials & Solar Cells》2002,73(4)
In this paper a transport equation is derived which describes the behaviour of the nanostructured metal oxide films in a photoelectrochemical cell. It is shown that a detailed analysis of the charge compensation mechanism necessarily leads to a transport equation with characteristics similar to but logically distinct from the pure diffusion equation. The studied phenomenon was named ambipolar diffusion in the early 1950s. It takes into account the fact that the diffusion processes of ions and electrons occur at different speeds. A weak electric field therefore couples the processes together to preserve charge neutrality. The electric field in turn affects the transport resulting in a deviation from purely diffusive behaviour. However, this has not been widely recognised in the literature for nanostructured semiconductor films until very recently. In this paper a detailed analysis is presented. It is based on the assumption that the current density is solenoidal. It is shown that application of the ambipolar diffusion model to a photoelectrochemical cell based on a nanostructured metal oxide film leads to an additional term in the transport equation, rather than only a new diffusion coefficient as in earlier work. It is also shown that the boundary conditions interact closely with the equation to form a transport model. 相似文献
24.
研究了18种具有不同孔结构参数的粒状铜基甲醇合成催化剂孔隙率对有效扩散系数的影响。结果发现,催化剂微孔孔隙率增大,曲节因子亦增大,扩散阻力增加。将孔隙率与催化剂曲节因子关联,得到了半经验方程,用它可估算催化剂的曲节因子。 相似文献
25.
T. RONALD A. MAGEE CAROLE P.D. WILKINSON 《International Journal of Food Science & Technology》1992,27(5):541-549
Investigation of the effects of varying air velocity, slice thickness, and pre-treatment with sodium chloride solutions and surface active agents on drying potato slices indicated that the drying occurred entirely in the falling rate period and was controlled by the mechanism of liquid diffusion. The rate of drying, and therefore the diffusion coefficients, increased with the addition of sodium chloride and surface active agents. Diffusion coefficients were also influenced by air velocity and slice thickness, suggesting that the rate of drying of potato slices is controlled by a combination of internal and external resistances. 相似文献
26.
本文研究了LF6铝合金的超塑性/扩散连接组合工艺,用变形和再结晶的方法细化晶粒,成功地进行了SPF/DB工艺试验,利用电子探针观察了扩散连接接头的界面微观区域,并从机理上分析了金属的超塑性/扩散连接两种工艺之间的内部联系及其金属学行为。 相似文献
27.
Oxygen Tracer Diffusion in Vitreous Silica 总被引:2,自引:0,他引:2
Joseph D. Kalen Rethia S. Boyce James D. Cawley 《Journal of the American Ceramic Society》1991,74(1):203-209
Oxygen diffusion in vitreous silica glass is studied using the gas exchange technique. The tracer concentration profiles are consistent with a model based on two mechanisms, one network and the other interstitial. These processes are coupled through limited network–interstitial exchange. Nuclear reaction analysis and secondary ion mass spectrometry techniques are performed and compared. These results are compared to experiments on transport in thin silica films grown on single-crystal silicon. 相似文献
28.
硅外延片中的杂质控制 总被引:2,自引:0,他引:2
有5类掺杂源影响硅的外延片中的杂质分布。主掺杂质控制外延层的杂质浓度,决定外延层的电阻率。固态外扩散、气相自掺杂和系统自掺杂影响衬底界面附近的外延层杂质浓度的深度分布。该文介绍了此3类掺杂源的掺杂过程和抑制方法。金属杂质在外延层中对器件有害,防止沾污和使用吸杂技术能降低金属杂质在外延层中的浓度。 相似文献
29.
J. M. P. Q. Delgado 《加拿大化工杂志》2006,84(6):651-655
In this article, a simple and inexpensive experimental technique easy to build in laboratory, for the measurement of tortuosity of a packed bed of inert particles, is described. Experimental values of the tortuosity were obtained with four different packed beds of sand. The experimental results obtained are in good agreement with the theoretical values of tortuosity in a porous media; and the data reported showed the tortuosity to increase with decrease in the void fraction of the packed bed as expected. 相似文献
30.
Ahmad Nozad Golikand Elaheh Lohrasbi Mohammad Ghannadi Maragheh Mehdi Asgari 《Journal of Applied Electrochemistry》2008,38(6):869-874
The effect of carbon surface oxidation on platinum supported carbon particles (Pt/C) with nitric acid was investigated by
cyclic voltammetry, electrochemical impedance spectroscopy, polarization experiments and chronoamperometry. Cyclic voltammograms,
polarization curves and electrochemical impedance spectra showed that the treated catalyst had much larger active surface
area and higher ionic conductivity than the untreated catalyst, and provided enhanced performance for oxygen reduction. The
formation of acidic groups was examined by IR spectra. The Pt/C surface oxidation had a large effect on the performance of
a gas diffusion electrode for oxygen reduction reaction. 相似文献