以Cu-Ti复合渗镀为先导的Si3N4陶瓷/金属钎焊连接

提出一种陶瓷表面多元离子复合渗镀合金化方法,采用该方法对Si3N4陶瓷表面进行Cu-Ti复合渗镀,然后在复合渗镀真空设备中进行渗镀Cu-Ti的Si3N4陶瓷与金属的钎焊.对Si3N4陶瓷表面的Cu-Ti渗镀合金层进行了EDS、XRD、SEM、OM测试分析和声发射划痕试验.结果表明,渗镀层中含有Cu、Ti、Fe、Si及Al元素,Cu、Ti分布比较均匀,渗镀合金层由Cu、CuTi2、TiSi2组成;声发射划痕试验结果表明,在100 N的最大载荷下,渗镀合金层与陶瓷基体未发生剥离和崩落现象.在100倍的光学显微镜及5000倍的电子显微镜下,钎焊接头中陶瓷/金属界面接合良好,无明显的宏观和微观缺陷.可在较低的真空度下实现陶瓷/金属钎焊,为陶瓷/金属钎焊连接提供了一个新方法.     

Flame-Sprayed Glaze Coatings: Effects of Operating Parameters and Feedstock Characteristics Onto Coating Structures

Many substrates do not sustain the conventional glazing process (i.e., vitreous glazing) due to the relatively high temperature required by this treatment (i.e., up to 1400 °C in some cases) to fuse glazes after their application on the surface to be covered. Flame spraying could appear as a solution to circumvent this limitation and to avoid thermal decomposition of substrates. This contribution describes some structural attributes of glaze coatings manufactured by flame spraying. It also discusses the influence of the feedstock powder morphology and some of its physical properties on coating characteristics. This article is an invited paper selected from presentations at the 2007 International Thermal Spray Conference and has been expanded from the original presentation. It is simultaneously published in Global Coating Solutions, Proceedings of the 2007 International Thermal Spray Conference, Beijing, China, May 14-16, 2007, Basil R. Marple, Margaret M. Hyland, Yuk-Chiu Lau, Chang-Jiu Li, Rogerio S. Lima, and Ghislain Montavon, Ed., ASM International, Materials Park, OH, 2007.     

高温模具表面激光熔覆耐磨合金

用2kw CO 激光和送粉工艺,在4Cr5MoV_1Si 钢表面熔覆一层高温耐磨合金(Ni 基高温合金+WC),并应用于轧钢机导向板工作面。用扫描电子显微镜、电子探针和 x 射线衍射技术分别进行熔覆层的组织形态观察,微区成分分析和物相的鉴定。结果表明,熔覆层显微组织主要有许多弥散分布的 W_2C、(W,Ti)C_(1-x)、WC 和共晶态的 M_(12)C 及γ(f、c、c)母体相组成。室温及高温硬度测试结果表明,熔覆层有适中的室温硬度和相对较高的高温硬度。实际生产考核结果表明,激光熔覆导向板使用寿命大大提高,每对可轧钢1000～1100吨,而4Cr_5MoV_1Si 和普碳钢分别为400～500吨和200吨。     

聚氨酯涂料的技术动向

叙述聚氨脂涂料的类型,各类聚氨脂涂料的特性、聚氨脂涂料的合成及目前聚氨脂涂料的技术进步动向。     

Metallurgical characterization and determination of residual stresses of coatings formed by thermal spraying

This work presents an experimental determination of residual stresses in 35CrMo4 (Euronorm) low alloyed steel substrates with thermally sprayed coatings. Two different materials were separately deposited. The first one consisted of a blend of two superalloys: Cr-Ni steel and Cr-Mn steel, designated 55E and 65E, respectively. The second material was molybdenum. In a first part, basic characteristics of the deposited layers (metallographic analysis, hardness, and adhesion) are presented. In a second part, the determination of the residual stresses, in both substrate and thermal sprayed layers is performed using an extensometric method in combination with a simultaneous progressive electrolytic polishing. The influence of a nickel-aluminum (80:20%) bond-coat and/or a post-annealing at 850 °C in air for 1 h is studied.     

添加SnO_2组元对RuO_2 SnO_2 TiO_2/Ti钛阳极组织形貌的影响

通过溶胶凝胶 (Sol gel)法经涂刷、烧结、退火等工艺制备了添加不同含量SnO2 的RuO2 SnO2 TiO2 /Ti三元涂层钛阳极。并通过X射线衍射 (XRD)、差热分析 (DTA)、透射电子显微 (TEM )分析了SnO2 组元对RuO2 TiO2 SnO2 /Ti阳极涂层组织、晶粒尺寸和外观形貌的影响。结果表明 ,所获三元涂层颗粒尺寸细小 ,均为纳米结构 ,且添加SnO2 组元后有显著细化涂层晶粒的效果。在不同退火温度下 ,随SnO2 含量的增加 ,涂层晶粒均能发生一定程度的细化。所获三元阳极涂层主要组成物相为金红石 (Ru ,Sn ,Ti)O2 固溶体 ,SnO2 组元含量较高的涂层出现不同成分金红石相共存的现象 ;当涂层退火温度由 45 0℃升高至 6 0 0℃后 ,SnO2 组元不能阻止 (Ru ,Sn ,Ti)O2 固溶体脱溶分解 ,并析出六方晶系Ru单质 ;添加SnO2 组元的RuO2 SnO2 TiO2 涂层晶粒外观呈较理想等轴状特征     

试谈覆盖层上水工建筑物的安全评价

根据覆盖层上水工建筑物实际运行状况及近年覆盖层上水工建筑物安全评价的实践,总结深覆盖层上水工建筑物坝址选择、坝轴线选择、枢纽布置、覆盖层复合地基的承载能力、各种型式防渗措施的防渗效果、防冲蚀、防地震液化处理措施及覆盖层应力、变形、渗流等特点。探讨覆盖层上水工建筑物的特点及存在的风险,并针对这些风险提出覆盖层上水工建筑物安全评价的关注点,以期在现有已取得巨大成就的基础上,进一步提高覆盖层上水工建筑物的设计、建设与安全评价水平。     

Total-FETI domain decomposition method for solution of elasto-plastic problems

In this paper we present an algorithm for the parallel solution of the rate-independent elasto-plastic problems with kinematic hardening. We assume the von Mises plastic criterion and the associated plastic flow rule. The time discretization is based on the implicit Euler method. The corresponding one-time-step problem is formulated in the incremental form with respect to the unknown displacement and discretized spatially by the finite element method. We use an ‘external’ algorithm based on a linearization of the elasto-plastic stress–strain relation by the corresponding tangential operator and we parallelize the arising linearized problem by the Total-FETI method. The numerical experiments were carried out using our novel C/C++ library FLLOP (FETI Light Layer On top of PETSc) at HECToR supercomputer located at EPCC, UK.     

基于直接评分与间接评分的协同过滤算法

协同过滤面临着用户评分数据极为稀疏的问题,为改善不同稀疏程度数据上的推荐效果,提出基于直接评分与间接评分的协同过滤算法。针对直接评分,定义加权用户相似性和加权项目相似性度量标准,构造直接推荐用户集合与直接推荐项目集合,给出直接评分权重的计算方法;针对间接评分,构造相似评分集合,定义评分相似性度量标准。定义综合评分权重,在直接评分与间接评分的基础上得到最终推荐结果。大量实验结果表明,该算法在不同稀疏程度的数据上均具有较高的推荐质量。     

物联网移动节点直接匿名漫游认证协议

无线网络下传统匿名漫游协议中远程域认证服务器无法直接完成对移动节点的身份合法性验证,必须在家乡域认证服务器的协助下才能完成,导致漫游通信时延较大,无法满足物联网感知子网的快速漫游需求.针对上述不足,提出可证安全的物联网移动节点直接匿名漫游认证协议,远程域认证服务器通过与移动节点间的1轮消息交互,可直接完成对移动节点的身份合法性验证.该协议在实现移动节点身份合法性验证的同时,具有更小的通信时延、良好的抗攻击能力和较高的执行效率.相较于传统匿名漫游协议而言,该协议快速漫游的特点更适用于物联网环境.安全性证明表明,该协议在CK安全模型下是可证安全的.