Dynamic properties of carbon black filled chlorinated polyethylene/hindered phenol blends

Aggregates of carbon black (CB) in a polymer matrix have a tendency to form a CB network. The dynamic mechanical properties of binary systems of chlorinated polyethylene (CPE) and CB or 3,9‐bis{1,1‐dimethyl‐2[β‐(3‐tert‐butyl‐4‐hydroxy‐5‐methylphenyl)propionyloxy]ethyl}‐2,4,8,10‐tetraoxaspiro[5,5]‐undecane (AO‐80) and their ternary systems were investigated. It was found that the dynamic mechanical properties of those systems depend on the colloidal properties, surface oxides, and surface modification of CB. For binary systems of CPE and CB, oxidized CB gives a high modulus at low strain amplitude and a large Payne effect compared with untreated CB. In contrast, the reverse effect was observed for their ternary systems. Consequently, a good micro‐dispersion is obtainable by surface modification due to physical adsorption of AO‐80 on oxidized CB particles via hydrogen bonds. © 2003 Society of Chemical Industry     

郁江梯级水电站群联合优化调度初探

郁江梯级水电站群由西津、仙依滩和桂航3座水电厂组成。针对西津电厂出力变化频繁,加上西津下游两电厂装机容量较小,经常出现弃水,用增量动态规划法进行了联合优化调度探索,同时介绍马斯京根分段流量演算法。     

精馏塔静态仿真：Ⅰ.静动态混合数学模型的应用

本文为了克服精馏塔静态仿真不易收敛和初值难以给定等难题，巧妙地利用隐含数值积分方法的特点，将稳态与动态数学模型耦合起来，用以求解高难度的非理想精馏塔静态仿真问题。所得静动态混俣模型大大提高了精馏塔静态仿真的鲁棒性，对于高度非理想精馏塔的仿真尤为有效。通过对某丙烯腈萃取精馏塔的静态仿真，充分证明了这种混合模型化方法的可行性。     

预测控制算法的统一格式及其在电加热炉的应用

本文根据常用的两类预测控制算法推出一种新型预测控制算法。并将其应用于一双输入/双输出的力学持久机电加热炉的温度控制系统上,获得了满意的结果:控温精度为±1.5℃/300℃,且适用于非最小相位系统。     

Dynamic Survivability in WDM Mesh Networks Under Dynamic Traffic

Network survivability is a crucial requirement in WDM mesh networks. In this paper, we systematically consider the problem of dynamic survivability with dynamic single link failure in WDM networks under dynamic traffic demands. Specifically, we investigate various protection schemes, such as dedicated path protection (DPP), shared path protection (SPP), dedicated link protection (DLP), shared link protection (SLP), and two restoration schemes, path restoration (PR) and link restoration (LR). Moreover, two new shared protection methods are proposed, i.e., SRLG-based shared link protection (SRLG-SLP) and SRLG-based shared path protection (SRLG-SPP). The SRLG (shared risk link group) constraint defines the availability of protection resources to a working path, which requires that any two working paths sharing the same risk of failure (or in the same SRLG) cannot share the same protection resources. Furthermore, in our study, we consider a more practical dynamic single-link failure model, in which the link-failure-interarrival time and link-failure-holding time are considered as two independent parameters. Based on this link-failure model, extensive simulations are done to analyze and compare the dynamic survivable performance of various protection and restoration schemes. Resource utilization, protection efficiency, restoration efficiency, and service disruption ratio are employed as survivable performance metrics versus traffic load, link-failure frequency, and link-failure reparation time to evaluate the survivable performance. Many meaningful results are given. In addition, we show that the developed SRLG-SLP and SRLG-SPP protection schemes perform very well in terms of protection efficiency and service disruption ratio, while sacrificing some performance in terms of resource utilization.     

Electrocatalytic hydrogenation of cyclohexanone: Simple dynamic cell design

The electrocatalytic hydrogenation of cyclohexanone has been investigated with catalytic powder particles made of metal nanoaggregates deposited on a nonconductive material such as activated carbon and alumina. The catalytic powder particles were suspended in the solution under vigorous stirring conditions. The brief contact of the powder particles with a porous carbon cathode was sufficient to form adsorbed hydrogen on the metallic nanoaggregates through water electrolysis and initiate the electrohydrogenation process. It is demonstrated that the key parameters of the electrohydrogenation process are both the nature of the metallic nanoaggregates and the nature of the non-conductive material. The hydrodynamics of the solution under vigorous stirring conditions have also been studied for the particular cell used in the present study.     

基于高速摄像的ESPI全场动态特性测量

采用高速摄像与ESPI技术相结合,将运动中的被测物位移随时间变化的状态以序列图像的形式实时记录,并运用图像处理技术,成功地实现了ESPI动态测量。测量了悬臂梁的自由振动过程,获得了悬臂梁的振动周期、振动频率和阻尼系数等动态特性,实验结果与理论计算值相吻合。     

基于概念网络的文本信息监控技术

由于网上信息的迅速增长,文本信息监控已经成为网上信息管理中的热点研究课题。本文在模糊集和语义网络的理论基础上,构建了模糊值动态约束性概念网络,介绍了该概念网络的基本构建方法,并提出了基于概念网络的文本分析算法。     

Characterization of resol resins modified by the addition of PVC plastisols

Plastisols, which are a blend of poly(vinyl chloride) resin and a plasticizer (DEHP), were used as a toughening agent of a resol resin in order to improve the mechanical properties. It was not possible to formulate resol blends by adding more than 10 % of plastisol owing to a lack of apparent homogeneity in the systems, which also showed many air bubbles. The relationship between dynamic mechanical, mechanical and thermal properties and the amount of plastisol added was studied. It was determined from the infrared spectroscopy and dynamic mechanical results that the resol–plastisol blends seem to be formed by a reaction between the phenol and PVC giving a higher crosslinked structure. An improvement in the thermal resistance of the blends at lower temperatures was observed with an increase in the percentage of plastisol. Flexural analysis showed the elastic behaviour of the systems. However, it was not possible to observe the effect of the plasticizer (DEHP) owing to the low quantity of plastisol that was added to the resol. Copyright © 2004 Society of Chemical Industry     

Decomposition of Time Series Dynamic Linear Models

This paper derives the admissible decompositions for a time series dynamic linear model, assuming only that the model is observable. The decompositions depend on factorizations of the characteristic polynomial of the state evolution matrix G into relatively prime factors. This generalizes the method of West (1997 ) which considers one decomposition in the particular case where G is diagonalizable. Conditions are derived for a decomposition to be independent. These results show that no autoregressive process of order d has an independent decomposition for any integer d . Two illustrations of this procedure are discussed in detail.