石墨炉原子吸收测定化探样品中痕量金的研究

采用以王水分解样品,泡沫塑料富集,硫脲解脱,石墨炉原子吸收分光光度计测定微量金。研究了测定时干燥温度和时间的选择,原子化温度和时间的选择,灰化温度和时间的选择,以及王水体积分数对吸附效果等条件对测定结果的影响。该方法检出限为0.2×10-9,经国家一级分析标准样品验证,结果与标准值相符。     

Interface Characteristics and Laboratory Constructability Tests of Novel Fiber-Reinforced Polymer/Concrete Piles

Conventional pile materials such as steel, concrete, and timber are prone to deterioration for many reasons. Fiber-reinforced polymer (FRP) concrete composites represent an alternative construction material for deep foundations that can eliminate many of the performance disadvantages of traditional piling materials. However, FRP composites present several difficulties related to constructability, and the lack of design tools for their implementation as a foundation element. This paper describes the results of an experimental study on frictional FRP/dense sand interface characteristics and the constructability of FRP–concrete composite piles. An innovative toe driving technique is developed to install the empty FRP shells in the soil and self-consolidating concrete is subsequently cast in them. The experimental program involves interface shear tests on small FRP samples and uplift load tests on large-scale model piles. Two different FRP pile materials with different roughness and a reference steel pile are examined. Static uplift load tests are conducted on different piles installed in soil samples subjected to different confining pressures in the pressure chamber. The results showed that the interface friction for FRP materials compared favorably with conventional steel material. It was shown that toe driving is suitable for installation of FRP piles in dense soils.     

土层地基上建筑结构混合控制的减震效率

研究土 -结构相互作用对结构混合控制减震效能的影响。首先建立了土层地基上结构混合控制的运动方程 ,通过不同输入地震波、不同土层剪切波速、不同结构参数等条件下的数值分析 ,讨论了桩基础对结构混合控制减震效率的影响规律。数值结果表明 :对于土 -结构相互作用体系 ,采用混合控制的减震效率明显要强于单一的 TL D的减震效率 ;在土层较为坚硬的情况下 ,混合控制仍具有较高减震效能 ;随着土层变软 ,土 -结构相互作用减小结构地震反应的效应趋于明显 ,混合控制的减震效率明显降低 ,因此 ,对软土地基上的结构实施混合控制时 ,必须先要正确分析土 -结构体系的地震反应。     

Finite element simulations of crack propagation in functionally graded materials under flexural loading

Cracks in stepped and continuously graded material specimens under flexural loading were investigated via finite element analysis. Calculation of mechanical energy release rates and propagation angles with crack-opening displacement correlation and the local symmetry (K_II = 0) criterion, respectively, provided results most efficiently and accurately, as compared with compliance and J-integral approaches and other deflection criteria. A routine was developed for automatic crack extension and remeshing, enabling simulation of incremental crack propagation. Effects of gradient profile and crack geometry on crack-tip stresses and crack propagation path are examined, and implications of these for optimal design of graded components against failure by fast fracture are discussed.