Optimization Techniques for Improving the Performance of Silicone‐Based Dielectric Elastomers

Dielectric elastomers are possible candidates for realizing products that are in high demand by society, such as soft robotics and prosthetics, tactile displays, and smart wearables. Diverse and advanced products based on dielectric elastomers are available; however, no elastomer has proven ideal for all types of products. Silicone elastomers, though, are the most promising type of elastomer when viewed from a reliability perspective, since in normal conditions they do not undergo any chemical degradation or mechanical ageing/relaxation. Within this review, different pathways for improving the electro‐mechanical performance of dielectric elastomers are highlighted. Various optimization methods for improved energy transduction are investigated and discussed, with special emphasis placed on the promise each method holds. The compositing and blending of elastomers are shown to be simple, versatile methods that can solve a number of optimization issues. More complicated methods, involving chemical modification of the silicone backbone as well as controlling the network structure for improved mechanical properties, are shown to solve yet more issues. From the analysis, it is obvious that there is not a single optimization technique that will lead to the universal optimization of dielectric elastomer films, though each method may lead to elastomers with certain features, and thus certain potentials.

     

The Modeling of Magnetorheological Elastomers: A State-of-the-Art Review

The magnetorheological elastomers (MREs) are novel multifunctional materials wherein their viscoelastic properties can be varied instantly under an application of applied magnetic field. Due to their field-dependent stiffness and damping properties, MREs are widely used in the development and design of MRE-based adaptive vibration isolators and absorbers and also biomedical engineering. Moreover, MREs due to their inherent magnetostriction effect have enormous potential for the development of soft actuators. The dynamic behavior of MREs is affected by various material parameters (e.g., matrix and particle types, particle concentration, additives) as well as mechanical and magnetic loading parameters (e.g., frequency, amplitude, temperature, magnetic flux density). Understanding and predicting the effect of materials and loading parameters on the response behavior of MREs are of paramount importance for the design of MRE-based adaptive structures and systems. This review paper mainly aims to provide a comprehensive study of material constitutive models to predict the nonlinear magnetomechanical behavior of MREs. Particular emphasis is paid to physics-based models including continuum- and microstructure-based models. Moreover, phenomenological models describing the dynamic magnetoviscoelastic behavior of MREs as well as the effect of temperature on the magnetomechanical behavior of such materials are properly addressed.     

On solving large strain hyperelastic problems with the natural element method

In this paper, an extension of the natural element method (NEM) is presented to solve finite deformation problems. Since NEM is a meshless method, its implementation does not require an explicit connectivity definition. Consequently, it is quite adequate to simulate large strain problems with important mesh distortions, reducing the need for remeshing and projection of results (extremely important in three‐dimensional problems). NEM has important advantages over other meshless methods, such as the interpolant character of its shape functions and the ability of exactly reproducing essential boundary conditions along convex boundaries. The α‐NEM extension generalizes this behaviour to non‐convex boundaries. A total Lagrangian formulation has been employed to solve different problems with large strains, considering hyperelastic behaviour. Several examples are presented in two and three dimensions, comparing the results with the ones of the finite element method. NEM performs better showing its important capabilities in this kind of applications. Copyright © 2004 John Wiley & Sons, Ltd.     

Finite Element Analysis for the Structure Optimization Design of the CPUE Load－Bearing Wheel of Tracked Vehicle

A new kind of material cast polyurethane elastomers (CPUE) is introduced to take the place of rubber on load-bearing wheel for the first time. Based on load-bearing wheel dimensions, material properties and operat-ing conditions, the structure of wheel flange is optimized by zero-order finite element method. A detailed three-di-mensional finite element model of flange of load-bearing wheel is developed and utilized to optimize structure of wheel flange. Its service life, which is affected by flange structure parameter, is analyzed by comparing the opti-mization results with those of prototype of wheel. The results of optimization are presented and the stress field of loar-bearing wheel in optimal dimension obtained by using finite element analysis method is demonstrated. The fi-nite element analysis and optimization results show that the CPUE load-bearing wheel is feasible and suitable for the tracked vehicle and has a guiding value in practice of the weighting design of the whole tracked vehicle.     

Flexible Low-Melting Point Radiation Shielding Materials: Soft Elastomers with GaInSnPbBi High-Entropy Alloy Inclusions

A polydimethylsiloxane (PDMS) matrix soft elastic composite material with low-melting-point GaInSnPbBi high-entropy alloy (LHEA) inclusions is prepared to evaluate its radiation shielding performance. The LHEA is composed of two different three-component eutectic microstructures, which are grown in a mixed manner to form a complex eutectic structure. The inclusions have excellent mechanical properties that matched the deformation of the PDMS matrix. To evaluate the interaction of the shielding material with photons, the Monte Carlo N-Particle Extended and XCOM codes are used to determine the shielding parameters of the LHEA/PDMS composites, such as mass attenuation coefficient, linear attenuation coefficient, half-value layer, tenth value layer, mean free path, and effective atomic number. The composite with 50-vol% LHEA has the best radiation shielding properties, validated by medical X-ray imaging experiments. The excellent shielding properties of the flexible lightweight composites are attributed to the higher mass attenuation coefficient of the LHEA inclusions than that of lead.     

Low-cycle fatigue behavior of flexible 3D printed thermoplastic polyurethane blends for thermal energy storage/release applications

Thermal energy storage (TES) materials constituted by a microencapsulated paraffin having a melting temperature of 6°C and a thermoplastic polyurethane (TPU) matrix were prepared through fused deposition modeling. Scanning electron microscope (SEM) micrographs demonstrated that the microcapsules were homogeneously distributed within the matrix, with a rather good adhesion within the layers of 3D printed specimens, even at elevated concentrations of microcapsules. The presence of paraffin capsules having a rigid polymer shell lead to a stiffness increase, associated to a decrease in the stress and in the strain at break. Tensile and compressive low-cycles fatigue tests showed that the presence of microcapsules negatively affected the fatigue resistance of the samples, and that the main part of the damage occurred in the first fatigue cycles. After the first 10 loading cycles at 50% of the stress at break, a decrease in the elastic modulus ranging from 60% for neat TPU to 80% for composite materials was detected. This decrease reached 40% of the original value at 90% of the stress at break after 10 cycles. Differential scanning calorimetry tests on specimens after fatigue loading highlighted a substantial retention of the original TES capability, in the range of 80%–90% of the pristine value, even after 1000 cycles, indicating that the integrity of the capsules was maintained and that the propagation of damage during fatigue tests took probably place within the surrounding polymer matrix. It could be therefore concluded that it is possible to apply the developed blends in applications where the materials are subjected to cyclic stresses, both in tensile and compressive mode.     

Cholesteric monomer and elastomers containing menthyl groups: Synthesis and phase behavior

The synthesis of a new cholesteric monomer ( M_LC) containing menthyl groups and a series of cholesteric elastomers ( LCE₁−LCE₄ ) is described. Their chemical structures and purity were characterized by FTIR, ¹H-NMR, and elemental analyses. The phase behavior and thermal stability were investigated by differential scanning calorimetry, polarizing optical microscopy, X-ray diffraction, and thermogravimetric analysis. By inserting a flexible spacer between the mesogenic core and the terminal menthyl groups, mesomorphism of M _LC was realized. LCE₁−LCE₄ with low content of crosslinking unit exhibited cholesteric phase because of the introduction of the nematic crosslinking unit. This indicates that low levels of chemical crosslinking do not significantly affect the phase behavior and mesomorphism of the elastomers, and reversible mesophase transitions can be observed. In addition, with increasing the content of crosslinking unit, the corresponding T_g decreased for LCE₁−LCE₄ , whereas their T_i did not remarkable change. © 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012     

Enhanced soft dielectric composite generators: the role of ceramic fillers

A notable issue in the field of dielectric elastomers is the characterization of composite materials with improved electromechanical coupling destined for mechanical-to-electrostatic energy converters. To this aim, random composites, where ceramic fillers with high dielectric constant are dispersed in a silicone matrix, represent an interesting option. Currently, the most promising reinforcing materials to be immersed in a silicone matrix, already tested for soft dielectric actuators, are lead magnesium niobate–lead titanate (PMN–PT) and lead zirconate-titanate (PZT). To estimate the performance improvement entailed by the composite device with respect to the homogeneous matrix, a typical four-phase cycle is considered in the model, where nominal load and electric charge are alternately held constant. Different materials are being studied: a composite consisting of a matrix in poly-dimethyl-siloxane (PDMS) reinforced with PMN–PT, assuming a filler concentration of 10% in volume and a PDMS–PZT composite with a 1% volume fraction of the ceramic component. In comparison with pure PDMS, the PDMS–10%PMN–PT allows an increase of more than 60% in the harvested energy per unit volume, while the PDMS–1%PZT composite, entailing a minor improvement, here in the range 23.5–37.4%, exhibits a better performance in terms of generated energy per unit weight. These results provide a guide for the choice and design of materials suitable for the realization of enhanced energy harvesters.     

Crystallization-Directed Anisotropic Electroactuation in Selectively Solvated Olefinic Thermoplastic Elastomers: A Thermal and (Electro)Mechanical Property Study

Dielectric elastomers (DEs), a class of soft electroactive polymers that change size upon exposure to an external electric field, constitute an increasingly important class of stimuli-responsive polymers due primarily to their large actuation strains, facile and low-cost fabrication, scalability, and mechanical robustness. Unless purposefully constrained, most DEs exhibit isotropic actuation wherein size changes are the same in all actuation directions. Previous studies of DEs containing oriented, stiff fibers have demonstrated, however, that anisotropic actuation along a designated direction is more electromechanically efficient since this design eliminates energy expended in nonessential directions. To identify an alternative, supramolecular-level route to anisotropic electroactuation, we investigate the thermal and mechanical properties of novel thermoplastic elastomer gels composed of a selectively solvated olefinic block copolymer that not only microphase-separates but also crystallizes upon cooling from the solution state. While these materials possess remarkable mechanical attributes (e.g., giant strains in excess of 4000%), their ability to be strain-conditioned enables huge anisotropic actuation levels, measured to be greater than 30 from the ratio of orthogonal actuation strains. This work establishes that crystallization-induced anisotropic actuation can be achieved with these DEs.