中间包CaO质陶瓷过滤器滤除夹杂效果的研究

对鞍钢三炼钢厂中间包应用的CaO质陶瓷过滤器进行了实验研究，从装有陶瓷过滤器和未装陶瓷过滤器的挡墙侧水口上方及各自的连铸坯中取样，并用电解法和吸收光度法测定了夹杂物的总含量及分量。实验结果表明，陶瓷过滤器对于滤除钢液中的Al2O3、SiO2夹杂作用显著。     

聚合物分解法制备微波介质陶瓷粉体的研究

对采用聚合物分解（Ｐｅｃｈｉｎｉ）法制备ＭｇＴｉＯ＿３粉体进行了研究。通过对聚合中间产物进行红外光谱分析，研究了聚合物分解法制备ＭｇＴｉＯ＿３陶瓷粉体的聚合反应过程及产物。并与用传统固相反应法制备粉体工艺进行对比．从而证明用聚合物分解法可获得单一ＭｇＴｉＯ＿３相材料．并可降低粉体的煅烧温度。     

氧化铈对改善ZTM陶瓷性能的作用

工业用电熔莫来石原料中含有钾、钠等杂质，而化学法制备的高纯莫来石中这些杂质含氏，因而以氧化锆增韧这两种莫来石制备陶瓷，发现其力学性能温度的变化趋势有较大差异。后者随温度升高力学性能反而有所增长。研究发现这一变化与原料中杂质含量有关。     

陶瓷企业公共关系与市场营销

公共关系是提高企业形象竞争力的法宝,企业将公共关系运用于营销活动之中,能够与社会公众建立、维持和发展良好的互利关系,通过树立良好的企业形象和信誉,从而为企业市场营销创造一个和谐的环境。从公共关系与市场营销的内涵入手,对市场营销中公共关系的作用和具体应用进行了初步的分析,希望通过这些分析,能够引起陶瓷企业在营销活动中对公共关系的注意。     

复相陶瓷导电性与其粒径级配的关系研究

通过对无序渗流模型的修正，建立了具有不同特征尺寸的两相无序体系的导电模型，推导了相关关系式，将其结果与相复合导电陶瓷的实验结果进行了比较，结论相当一致。由此揭示了陶瓷生料的两相粒径分布对复合导电陶瓷导电性的影响。     

Dielectric behaviour of glasses and glass ceramics in the system BaO-PbO-TiO2-B2O3-SiO2

Glasses with varying molar ratios of PbO/BaO in the system BaO-PbO-TiO₂-B₂O₃-SiO₂ were prepared keeping (BaO + PbO)/TiO₂ ratio equal to one. The glasses were ceramized by two-stage heat treatment. X-ray diffraction indicates that PbTiO₃ crystallizes in lead-rich glasses while BaTiO₃ precipitates in barium-rich compositions. Solid solution (Ba, Pb)TiO₃ does not seem to crystallize over the entire range of compositions. Simultaneous presence of PbO and BaO in the initial glass composition reduces the yield of ferroelectric phase. Dielectric properties have been interpreted in terms of microstructural features.     

A panoramic view of Li7P3S11 solid electrolytes synthesis,structural aspects and practical challenges for all-solid-state lithium batteries

The development of an inorganic electrochemical stable solid-state electrolyte is essentially responsible for future state-of-the-art all-solid-state lithium batteries (ASSLBs). Because of their advantages in safety, working temperature, high energy density, and packaging, ASSLBs can develop an ideal energy storage system for modern electric vehicles (EVs). A solid electrolyte (SE) model must have an economical synthesis approach, exhibit electrochemical and chemical stability, high ionic conductivity, and low interfacial resistance. Owing to its highest conductivity of 17 mS·cm^-1, and deformability, the sulfide-based Li₇P₃S₁₁ solid electrolyte is a promising contender for the high-performance bulk type of ASSLBs. Herein, we present a current glimpse of the progress of synthetic procedures, structural aspects, and ionic conductivity improvement strategies. Structural elucidation and mechanistic approaches have been extensively discussed by using various characterization techniques. The chemical stability of Li₇P₃S₁₁ could be enhanced via oxide doping, and hard and soft acid/base (HSAB) concepts are also discussed. The issues to be undertaken for designing the ideal solid electrolytes, interfacial challenges, and high energy density have been discoursed. This review aims to provide a bird's eye view of the recent development of Li₇P₃S₁₁-based solid-state electrolyte applications and explore the strategies for designing new solid electrolytes with a target-oriented approach to enhance the efficiency of high energy density all-solid-state lithium batteries.     

Effect of Ca2+ and Mg2+ ions on the sintering and spectroscopic properties of cr-doped yttrium aluminum garnet ceramics

In this work, we investigated the effects of Ca²⁺ and Mg²⁺ ions and annealing temperature on the spectroscopic parameters of chromium-doped yttrium aluminum garnet ceramics (Cr:YAG). Samples were obtained with either a separate or a simultaneous addition of calcium and magnesium oxides. To achieve this, aqueous suspensions were prepared using Y₂O₃, Al₂O₃, Cr₂O₃, MgO, and CaO high-purity powders as raw materials. The obtained suspensions were freeze-granulated, pressed into pellets, debinded, and subjected to reactive sintering in vacuum at 1715°C for 6 h. Each material was annealed in air with temperatures between 1300 and 1700°C. Samples were also compared to Cr:YAG ceramics with the addition of silica as a sintering aid. All the materials obtained were then exposed to 445 nm excitation, and emission spectra in the visible and infrared wavelengths were recorded. The results showed that the emission spectra of Cr:YAG ceramics varied according to the annealing conditions: as-sintered samples exhibited strong emissions of around 680 nm and, after air annealing, of around 1400 nm. This phenomenon is attributed to the Cr³⁺→Cr⁴⁺ transition. Samples doped solely with MgO exhibited the highest emission intensity in the infrared region. Thus, Mg²⁺ ions provided the best conversion efficiency of chromium ions.     

掺杂对PZT压电陶瓷的影响及研究进展

在介绍掺杂PZT压电陶瓷材料制备的基础上,总结出生产掺杂PZT材料的最佳掺杂条件,以及配方对压电陶瓷性能的影响,只要工艺合适,性能完全能再提高,对压电陶瓷材料的发展趋势进行了展望。     

Relaxor behavior and superior ferroelectricity of Y2O3-doped (Ba0.98Ca0.02) (Ti0.94Sn0.04Zr0.02)O3 lead-free ceramics

To upgrade the electric properties of lead-free piezoceramics, (1–x)(Ba_0.98Ca_0.02Ti_0.94Sn_0.04Zr_0.02)O₃-xY₂O₃ (abbreviated as (1–x)BCTSZ-xY, x = 0 mol%, 0.02 mol%, 0.04 mol%, 0.06 mol%, 0.08 mol% and 0.1 mol%) ceramics were successfully synthesized by traditional solid-state sintering method. The phase structure and microstructure of ceramics were investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and piezoresponse force microscopyeramics (PFM). The electric properties of ceramics were researched through piezoelectric, dielectric and ferroelectric test instruments. The results show that all samples have pure perovskite structure and favorable electric properties. The optimal electric properties which especially include superior ferroelectric properties are gained when Y₂O₃ content is 0.06 mol% (d₃₃ = 419 pC/N, k_p = 52%, T_c = 89.5 °C, ε_r = 26900, tanδ = 2.86%, P_r = 14.41 μC/cm², E_c = 1.8 kV/cm). Moreover, the temperature-dependent dielectricity of samples shows apparent relaxor behavior under different frequencies. The Curie–Weiss law further proves that all samples are typical relaxor ferroelectrics, and the relaxor degree of samples decreases with increase of Y₂O₃ content. In conclusion, Y₂O₃ plays a significant role in enhancing electric properties of BCTSZ ceramics.