2,5-二巯基-1,3,4-噻二唑的电化学性能

以二硫化碳和水合肼为原料合成了2,5-二巯基-1,3,4-噻二唑(DMcT),并通过元素分析、Raman光谱和红外(IR)光谱对DMcT的结构进行了表征。DMcT的两对氧化还原峰电位差分别为0.96V和1.33V,这表明在室温下氧化还原反应速度很慢。酸碱对DMcT氧化还原反应有很大的影响:加入三乙胺之后,DMcT的氧化反应更加容易,还原峰电流增加,但对还原峰电位影响不大;相反,甲磺酸存在时,DMcT的氧化反应更难进行,而还原反应变得更加容易。     

气动工具的噪声防治

气动工具在我国机械制造等各行业广泛应用的同时,工作时的排气噪声对周围环境也造成了一定的污染。介绍了治理噪声所采用的消声装置及设计方法,通过消声后的试验数据及噪声频譜对比分析,用正交试验法解决功率与噪声的矛盾,通过这种方法使噪音降低最大,功率损耗最小,这种消声装置原理治理噪声效果显著。     

O2,金属电极/YSZ界面的电化学研究

本文利用交流阻抗和直流极化的电化学方法，比较了200～500℃氧在Pt、Ag、Au、Ag－Pd四种化学镀电极上的扩散，350～600℃氧在金属电极／YSZ界面的电化学反应速度以及阴阳电荷传递系数；计算了350～600℃四种电极的界面阻抗；研究了400℃时O2在Ag－Pd电极界面的交换电流密度Io与氧分压Po2的定量关系．     

Electrochemical analysis of dye adsorption on aligned carbon nanofiber arrays coated with TiO2 nanoneedles for dye-sensitized solar cell

An electrochemical method has been developed to analyze dye absorption on the aligned carbon nanofiber arrays coated with TiO2 nanoneedles for dyesensitized solar cell. The unique nanostructure with the roughness factor of 90.6 provides a large effective surface area for dye adsorption. The experimental results showed that the dye molecules cover 39.7% of the TiO2 surface area which influences the performance of dye-sensitized solar cell. The electrochemical method provides the information of the coverage of dye molecules which is a key issue to optimize solar cell performance.     

Effect of ultrasound treatment of AlSi5 liquid alloy on corrosion resistance

The application of power ultrasound to liquid alloys can be a simple and cost effective method to induce both degassing and grain refinement in a single step, without the need of inert gas or inoculants additions. In this paper, the treatment of liquid hypoeutectic AlSi5 alloy by ultrasound waves and its effects on microstructure were investigated. The corrosion behavior of ultrasound treated samples was compared to that of the non‐treated ones by means of immersion and electrochemical tests. It was observed that the ultrasound treated alloy offers better quality, higher mechanical properties and improved corrosion resistance, as a consequence of a more uniform distribution of the solute.     

Unscented Kalman filtering in the additive noise case

The unscented Kalman filter(UKF) has four implementations in the additive noise case,according to whether the state is augmented with noise vectors and whether a new set of sigma points is redrawn from the predicted state(which is so-called resampling) for the observation prediction.This paper concerns the differences of performances for those implementations,such as accuracy,adaptability,computational complexity,etc.The conditionally equivalent relationships between the augmented and non-augmented unscente...     

同步相量测量装置的一种异地校核方法

提出利用对晶振信号进行整数分频并结合GPS同步时钟生成相量测量装置(PMU)异地同步校核中基准信号的方法。通过分析可知,只要晶振频率足够高,生成的基准信号就有足够高的精度,而且信号的参量具有良好的可调节性。该方法可有效解决PMU测量网络中异地同步校核和自校核问题。     

Realization of nth-order series impedance function using only (n-1) current-feedback amplifiers

A new configuration for realizing a higher-order series impedance function using current-feedback amplifiers (CFAs) is presented. The nth-order series impedance function employs only (n–1) CFAs and (2n–1) passive elements. The higher order series impedance function can be applied to realize various higher-order highpass and lowpass filters. The passive element values can be easily decided from the coefficients of the filter transfer functions. The use of CFAs simplifies the circuit implementation and makes the proposed circuit attractive for application. Experiments and simulation results are given to confirm the theoretical analysis.     

基于VMD和BP神经网络的轨道病害诊断方法

针对从非线性、非稳态的轨枕振动信号中提取病害特征困难的问题,文中提出一种基于变分模态分解和多尺度排列熵的轨道病害特征提取方法,并采用BP神经网络病害诊断模型进行病害识别.利用变分模态分解方法将采集到的振动加速度信号进行分解,得到若干个本征模态分量.计算这些本征模态分量的多尺度排列熵值,将其作为轨道病害的高维特征向量,以...