全文获取类型
收费全文 | 22514篇 |
免费 | 2906篇 |
国内免费 | 2061篇 |
专业分类
电工技术 | 2252篇 |
综合类 | 2128篇 |
化学工业 | 2282篇 |
金属工艺 | 2474篇 |
机械仪表 | 1677篇 |
建筑科学 | 619篇 |
矿业工程 | 375篇 |
能源动力 | 601篇 |
轻工业 | 400篇 |
水利工程 | 112篇 |
石油天然气 | 670篇 |
武器工业 | 325篇 |
无线电 | 5765篇 |
一般工业技术 | 3680篇 |
冶金工业 | 531篇 |
原子能技术 | 257篇 |
自动化技术 | 3333篇 |
出版年
2024年 | 140篇 |
2023年 | 472篇 |
2022年 | 568篇 |
2021年 | 746篇 |
2020年 | 852篇 |
2019年 | 739篇 |
2018年 | 678篇 |
2017年 | 922篇 |
2016年 | 974篇 |
2015年 | 1029篇 |
2014年 | 1441篇 |
2013年 | 1434篇 |
2012年 | 1781篇 |
2011年 | 1863篇 |
2010年 | 1406篇 |
2009年 | 1497篇 |
2008年 | 1259篇 |
2007年 | 1589篇 |
2006年 | 1484篇 |
2005年 | 1163篇 |
2004年 | 989篇 |
2003年 | 921篇 |
2002年 | 657篇 |
2001年 | 558篇 |
2000年 | 474篇 |
1999年 | 370篇 |
1998年 | 265篇 |
1997年 | 267篇 |
1996年 | 163篇 |
1995年 | 193篇 |
1994年 | 108篇 |
1993年 | 105篇 |
1992年 | 75篇 |
1991年 | 66篇 |
1990年 | 54篇 |
1989年 | 46篇 |
1988年 | 34篇 |
1987年 | 22篇 |
1986年 | 18篇 |
1985年 | 7篇 |
1984年 | 11篇 |
1983年 | 6篇 |
1982年 | 10篇 |
1980年 | 4篇 |
1978年 | 2篇 |
1962年 | 2篇 |
1959年 | 3篇 |
1958年 | 1篇 |
1957年 | 1篇 |
1951年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
This paper deals with the problem of piecewise auto regressive systems with exogenous input(PWARX) model identification based on clustering solution. This problem involves both the estimation of the parameters of the affine sub-models and the hyper planes defining the partitions of the state-input regression. The existing identification methods present three main drawbacks which limit its effectiveness. First, most of them may converge to local minima in the case of poor initializations because they are based on the optimization using nonlinear criteria. Second, they use simple and ineffective techniques to remove outliers. Third, most of them assume that the number of sub-models is known a priori. To overcome these drawbacks, we suggest the use of the density-based spatial clustering of applications with noise(DBSCAN) algorithm. The results presented in this paper illustrate the performance of our methods in comparison with the existing approach. An application of the developed approach to an olive oil esterification reactor is also proposed in order to validate the simulation results. 相似文献
92.
该文利用多壁碳纳米管(MWCNTs)和聚(2-乙酰基-5-溴噻吩)复合纳米材料修饰电极,用于同时检测对苯二酚(HQ)、邻苯二酚(CC)和对甲苯酚(PC)。通过循环伏安法(CV),示差脉冲伏安法(DPV)和透射电镜(TEM)表征了该复合纳米材料的电化学性能和表面形貌。结果表明该电极对HQ、CC和PC具有较高的灵敏度和选择性。DPV峰电流与HQ、CC和PC的浓度在1.0×10-5~8.0×10-4mol/L,5.0×10-6~5.5×10-4mol/L和5.0×10-6~7.5×10-4mol/L范围内分别呈良好的线性关系,且检测限分别为3.0×10-6 mol/L,1.7×10-6 mol/L和2.0×10-6mol/L。 相似文献
93.
94.
Deconvolution of the electrolytic manganese dioxide (EMD) discharge curve has indicated the presence of a number of energetically different reduction processes. This has been used to determine the contribution of each reduction process to the total discharge. Using step potential electrochemical spectroscopy (SPECS), the i-t data were modelled as the sum of the discharge of the individual reduction processes. From this, A√ D for each reduction process as a function of degree of discharge was determined. The maximum A√ D values for each process ranged from 2.3×10−2 to 4.0×10−4 cm3 s−1/2 g−1 values are consistent with previously reported values for A√ D, although in this case we have determined values for the entire compositional range. 相似文献
95.
ABSTRACT This study explores an electrochemical adsorption method on the regeneration of aqueous drilling fluid waste. Response surface analysis was applied to investigating the electrochemical factors on the adsorption performance. The response surface polynomial model optimized the preferred electrochemical adsorption conditions with adsorption time of 20 min, spacing electrodes of 5 cm, adsorption concentration of 5% and NaCl concentration of 2 g/L. The model calculated electrochemical adsorption amount of drilling fluid showed only 1.3% deviation from the experimental results. Thus, the model could provide effective support for the device design and application of drilling fluid electrochemical adsorption process. 相似文献
96.
This paper deals with the problem of single-channel noise reduction in the short-time Fourier transform (STFT) domain. Many algorithms have been developed to solve this important problem, most of which generally assume that the STFT coefficients in different frequency bands are uncorrelated, so the noise reduction is achieved by applying a gain function to the STFT of the noisy speech in each frequency band. However, this assumption is not accurate and the STFT coefficients of speech signals between neighboring frequency bands are correlated in practice due to the use of small lengths of the fast Fourier transform (FFT) and overlap add/save techniques in implementation. This paper formulates the noise reduction problem by taking into account the interband correlation using the so-called bifrequency spectrum. Based on this formulation, a single-channel minimum variance distortionless response (MVDR) filter is derived, which is shown to be able to significantly improve the signal-to-noise ratio (SNR) and meanwhile maintain the desired speech not much distorted. Simulations are presented to justify the claimed merits of the developed MVDR filter. 相似文献
97.
98.
Charge transfer on boron doped diamond (BDD) electrodes was studied by cyclic voltammetry and electrochemical impedance spectroscopy.
The diamond films of 5 μm thickness and boron content between 200 ppm and 3000 ppm were prepared by the hot filament CVD technique
on niobium substrate and mounted in a Teflon holder as rotating disk electrodes. The electrochemical measurements were carried
out in aqueous electrolyte solutions of 0.5 M Na2
SO
4 + 5 mM K3[Fe(CN)6]/K4[Fe(CN)6]. Significant deviation in the redox behaviour of BDD and active Pt electrodes was indicated by a shift of the peak potentials
in the cyclic voltammograms with increasing sweep rate and lower limiting diffusion current densities under rotating disk
conditions. In the impedance spectra an additional capacitive element appeared at high frequencies. The potential and rotation
dependence of the impedance spectra can be described quantitatively in terms of a model based on diffusion controlled charge
transfer on partially blocked electrode surfaces. Direct evidence for the non-homogeneous current distribution on the diamond
surface was obtained by SECM measurements. 相似文献
99.
应用PULSE测试分析系统中阶次跟踪法,测试分析某型乘用车车内四个位置的噪声水平随发动机转速变化的关系.揭示了该型汽车在测试工况下,不同的转速对车内噪声的贡献规律.为降低车内行驶噪声和振动响应提供了重要的分析依据和参考. 相似文献
100.
The use of electrochemical noise methods (ENM) to study thick, high impedance coatings 总被引:2,自引:0,他引:2
Gordon P. Bierwagen Carol S. Jeffcoate Junping Li S va Balbyshev Dennis E. Tallman Douglas J. Mills 《Progress in Organic Coatings》1996,29(1-4):21-29
Thick, high impedance organic coatings are those class of coatings used to provide corrosion protection to naval vessels, pipelines, gasoline storage tanks, and other large structures such as bridges and plant structures. These coatings, especially the newest generations now being used in practice, can provide exceptional protection and lifetime of performance such that properly and accurately assessing and differentiating among competing coatings is a very difficult task. The standard protocol of salt fog testing (ASTM B117), immersion testing, and outdoor exposure in a corrosive environment with subjective evaluation of a coating's performance durings and after testing, does not adequatcly rank and predict coating lifetimes for new coating systems, especially for the environmentally compliant coating systems such as powder coatings (especially the thick, fusion bonded epoxy (FBE) coatings used for pipelines), two component epoxy and urethane coatings and waterborne coatings. New, objective test methods are desperately needed by users and manufacturers of coatings. A relatively new electrochemical test procedure, electrochemical noise methods (ENM), as developed by Skerry and Eden, has been shown in our laboratory to be very successful in the ranking and prediction of relative coating performance. We have used the method successfully on naval ship coatings, several pipeline coatings and other related systems, and Skerry has used them successfully on industrial maintenance coatings. We have used these methods in conjunction with electrochemical impedance spectroscopy, d.c. resistance measurements and cyclic salt fog testing of the ProhesionTM type. In our studies of pipeline coatings, we needed to investigate thermal effects because of their extended range of use temperature. In these studies, we have discovered that electrochemical methods can be used for an in situ measurement of the Tg of coatings in electrolyte immersion. Further, the ‘plasticizing’ effect of aqueous electrolyte absorption as well as its relative irreversibility has been shown. For all coatings studied, ENM provided useful, objective, numerical data which rapidly ranks coatings and provides useful information on the relative lifetime prediction of coatings which may provide up to 30 years of service. 相似文献