Understanding heterogeneous catalysis on an atomic scale: a combined surface science and reactivity investigation for the dehydrogenation of ethylbenzene over iron oxide catalysts

In order to study the dehydrogenation of ethylbenzene to styrene, epitaxial iron oxide model catalyst films with Fe₃O₄(111), -Fe₂O₃(0001) and KFe _x O _y (111) stoichiometry were prepared in single crystal quality on Pt(111). They were investigated using surface science techniques before and after atmospheric pressure reaction experiments in a newly designed single crystal flow reactor. As expected from low-pressure measurements, Fe₃O₄(111) is catalytically inactive. The catalytic activity of -Fe₂O₃(0001) starts after an activation period of about 45 min. After that, the surface is essentially clean but shows a high concentration of defects. On the potassium-promoted films, however, the activation period is much longer, the activity then is higher and the surface gets covered completely with carbon and oxygen during reaction. This indicates a different reaction pathway on the promoted films with a carbon–oxygen species as catalytically active species.     

湍流化学反应的分形数值模拟

基于涡串唯象概念和分形理论,建立了能够表达湍流多尺度结构物理特性的分形湍流化学反应模型,针对Steckler室内燃烧过程进行了数值模拟研究.湍流流动采用浮力修正的κ-ε双方程模型来模拟,辐射由Rosseland模型描述,整个模拟过程由ANSYS-CFX10.0实现.将模拟结果与Steckler的燃烧实验数据进行对比,并与EDC燃烧模型及文献中EBU燃烧模型的模拟结果进行对比.结果表明,FM燃烧模型模拟得出的温度、速度场分布与实验数据能够较好地吻合,是一种有前途的湍流化学反应模拟方法.     

二氧化氯的生产和应用评述

详细评述了 2 0世纪二氧化氯的主要生产工艺和制备方法及二氧化氯作为漂白剂、消毒杀菌剂、水处理剂等在多种行业中的应用 ,分析展望了 2 1世纪二氧化氯的生产和应用前景 ,认为应在我国大力发展二氧化氯的生产并促进其应用。     

固体推进剂燃烧机理诊断方法的研究进展

介绍和评述了诊断含能材料热分解和推进剂燃烧波结构的方法、仪器和研究进展,以及含能材料和推进剂热分解和燃烧波结构的研究结果,探讨了燃烧机理研究方法的发展方向。提出需要不断完善和更新推进剂燃烧的诊断方法,以获得更为全面的接近真实条件下推进剂燃烧的有效信息。附参考文献14篇。     

全球催化剂工业动向

介绍了在全球范围内催化剂工业的现状,包括市场需求及经营形势。由于美国及其他国家环保法规日趋严格迫使炼油工业采用清洁燃料催化剂,导致炼油催化剂需求量上升,聚烯烃催化剂工业获得较大发展,炼油催化剂技术推陈出新。特种化学品产品催化剂和精细化工领域的催化剂工业将面临挑战。     

Fuzzy PID control of space manipulator for both ground alignment and space applications

Considering gravity change from ground alignment to space applications, a fuzzy proportional-integral-differential (PID) control strategy is proposed to make the space manipulator track the desired trajectories in different gravity environments. The fuzzy PID controller is developed by combining the fuzzy approach with the PID control method, and the parameters of the PID controller can be adjusted on line based on the ability of the fuzzy controller. Simulations using the dynamic model of the space manipulator have shown the effectiveness of the algorithm in the trajectory tracking problem. Compared with the results of conventional PID control, the control performance of the fuzzy PID is more effective for manipulator trajectory control.     

铜陵一冶环保治理工程的设计

介绍冶炼烟气制本系统环保治理工程的工艺设计及生产运行情况。污水处理系统采用中和曝气加铁盐除砷工艺，引进了戈尔膜过滤器。尾气处理系统，采用石灰中和法，引进动波洗涤技术和关键设备。环保治理工程投产后，废气均达标排放。     

智能虚拟环境中基于MAS的智能Agent体系结构

智能虚拟环境是人工智能和虚拟现实相结合的产物。由于多Agent系统具有可扩展性、自治性、主动性、可重构性和敏捷性等特点,已成为目前最感兴趣的AI技术之一。本文提出一种IVE中基于多Agent系统的智能Agent体系结构,着重于智能Agent内部机制的研究与设计,通过Agent的内部机制来提升系统的整体性能。     

基于OpenShift的非均衡数据完整性评估

设计并实现了一个基于OpenShift云计算环境的数据质量评估平台,对非均衡数据的完整性常规指标和专用指标具有评估功能。     

化学工业与循环经济

现代化学工业在很大程度上成就了目前"大规模生产和大规模消费"的发展模式,其行业性质也决定了它必将在循环经济建设中扮演重要的角色。在阐述循环经济内涵和国际经验基础上,论述了绿色化学与循环经济的关系,并提出了一些初步的发展建议。