Synthesis of nano particle of inorganic oxides by polymer matrix

Ultrafine (⩽ 150 nm) powders of spinels [MFe₂O₄ where M = Ni(II), Co(II) and Zn(II)]; rare-earth orthoferrites [RFeO₃ where R = Sm, Nd and Gd], and rare-earth garnets [R₃Fe₃O₁₂ where R = Sm, Nd and Gd] with good purity and chemical homogeneity were prepared through two new versatile chemical routes. The first route involved the coprecipitation of the desired metal nitrates from their aqueous solution, in presence of a water soluble polymer-polyvinyl alcohol (PVA), by triethyl ammonium carbonate solution. The other process involved complete evaporation of a mixture of optimum amounts of PVA and the desired aqueous metal nitrate solutions, with and without the addition of optimum amounts of urea when the mixture was evaporated to a pasty mass. In addition, detailed study on the reported potassium ferricyanide route was also carried out for the production of the rare-earth orthoferrite powders. The various precursor as well as the heat-treated mixed-oxide powders, prepared through each of the routes, were compared by the physical characterization studies involving thermal gravimetry and differential scanning calorimetry, infrared spectroscopy, X-ray powder diffraction, transmission electron microscopy, and room temperature magnetic measurements.     

Surface tailoring of an ethylene propylene diene elastomeric terpolymer via plasma‐polymerized coating of tetramethyldisiloxane

In the research presented here, we explore the use of a low‐energy plasma to deposit thin silicone polymer films using tetramethyldisiloxane (TMDSO) (H(CH₃)₂? Si? O? Si? (CH₃)₂H) on the surface of an ethylene propylene diene elastomeric terpolymer (EPDM) in order to enhance the surface hydrophobicity, lower the surface energy and improve the degradation/wear characteristics. The processing conditions were varied over a wide range of treatment times and discharge powers to control the physical characteristics, thickness, morphology and chemical structure of the plasma polymer films. Scanning electron microscopy (SEM) shows that pore‐free homogeneous plasma polymer thin films of granular microstructure composed of small grains are formed and that the morphology of the granular structure depends on the plasma processing conditions, such as plasma power and time of deposition. The thicknesses of the coatings were determined using SEM, which confirmed that the thicknesses of the deposited plasma‐polymer films could be precisely controlled by the plasma parameters. The kinetics of plasma‐polymer film deposition were also evaluated. Contact angle measurements of different solvent droplets on the coatings were used to calculate the surface energies of the coatings. These coatings appeared to be hydrophobic and had low surface energies. X‐ray photoelectron spectroscopy (XPS) and photoacoustic Fourier‐transform infrared (PA‐FT‐IR) spectroscopy were used to investigate the detailed chemical structures of the deposited films. The optimum plasma processing conditions to achieve the desired thin plasma polymer coatings are discussed in the light of the chemistry that takes place at the interfaces. Copyright © 2004 Society of Chemical Industry     

缝洞型碳酸盐岩油藏流动单元概念和研究方法探讨

流动单元对于提高油田采收率具有很大的实际意义,该项研究在砂岩油藏研究中已取得较大进展。对于缝洞型碳酸盐岩油藏,由于岩石结构构造、成岩后生作用、构造断裂作用、溶蚀作用等多因素对储集空间的影响,已有的流动单元概念及研究技术方法难于应用。以塔河油田为例,针对缝洞型碳酸盐岩地质特征,论证了碳酸盐岩储层渗流屏障的存在及其类型,探索性提出区别于砂岩油藏的缝洞型碳酸盐岩储层流动单元的概念。提出的研究思路和方法包括;油藏压力趋势分析法、井间生产干扰分析法、流体性质差异分析法、井间干扰试井法。结合储层发育特征,初步建立了缝洞型碳酸盐岩流动单元的划分标准。     

翅片式空气冷却器改造

针对茂名石化乙烯工业公司全密度聚乙烯装置翅片式空气冷却器存在的问题。结合生产实际要求进行了改造。将原设备换热芯由不可拆结构改为可抽芯结构。原圆形换热管更换为椭圆管。材质由SS304不锈钢更换为铜，并对改造后的空气冷却器进行了传热核算。理论和实践证明，改造是成功的。     

Effect of fluoropolymer antidripping agent on the microstructure and properties of polyesters

Poly(ethylene terephthalate) (PET) is of excellent mechanical properties and melt processability and is widely used as raw material for textile fibers. However, the flame retardant properties of PET were rather poor, and both reactive and additive phosphorus- and halogen-containing compounds have been employed to enhance the reaction-to-fire properties while the meltdripping behaviour during burning hasn’t been handled properly with the flame retardants. In this work, fluoropolymer was blended with both pure PET (pPET) and reactive phosphorus-containing flame retarded copolyester (fPET), and the flame retardance and char formation and mechanical properties of the resulted pPET and fPET blends were investigated. The tensile strengths of modified pPET samples were worsen whereas those of modified fPET samples were improved at low concentrations. The initial thermal degradation in nitrogen was accelerated remarkably for the two polyesters with fluoropolymer. The oxygen indices of the all modified samples were reduced while char formation and meltdripping suppression were encouraged. The apparent melt viscosity and elasticity for the two polyesters were gained much with antidripping agent. Therefore, fluoropolymer improved char formation of the two polyesters based on the gaseous phase mechanism while the partial suppression of meltdripping behavior and the decrease of mechanical properties mainly originated from the increase of melt viscosity via fibrillation for pPET.     

对我厂防治加热管内碳酸钙垢的思索

分析了我厂两碱法原卤净化后,加热管内壁结碳酸钙垢的原因,探讨了我厂采取加盐酸、加阻垢剂、用超声波阻垢器的方法,以及对加热管内碳酸钙垢防治的情况和存在的问题.     

Synthesis and applications of heterobifunctional poly(ethylene oxide) oligomers

Poly(ethylene oxide) (PEO) oligomers are employed extensively in pharmaceutical and biomedical arenas mainly due to their excellent physical and biological properties, including solubility in water and organic solvents, lack of toxicity, and absence of immunogenicity. PEO can be chemically modified and reacted with, or adsorbed onto, other molecules and surfaces. Sophisticated applications for PEO have increased the demand for PEO oligomers with tailored functionalities, and heterobifunctional PEOs are often needed. This review discusses the synthesis and applications of heterobifunctional PEO oligomers possessing amine, carboxylate, thiol, and maleimide functional groups.     

世界乙烯工业及其进展

阐述了世界乙烯产能需求现状，近扑扩能增产预测，乙烯原料分析以及乙烯生产的技术进展。     

乙烯裂解炉对流段局部结构设计改进

介绍了乙烯裂解炉对流段的结构功能,各部件局部结构的改善设计。