碳酸二甲酯的市场需求和生产技术进展

介绍了碳酸二甲酯的价格、生产情况及国内外市场需求 ,指出碳酸二甲酯在我国具有极大的市场潜力。综述了生产碳酸二甲酯的三类主要方法 ,介绍了光气法、酯交换法和氧化羰基化法的各种具体方法及尚未实现工业化仍在研究中的其他方法。并对各种工业化的生产方法从技术、经济和清洁性的角度进行了分析 ,指出适合我国采用的工业合成方法是气相氧化羰基化法和甲醇与 CO2 直接合成法     

汉白玉废料制备球形纳米碳酸钙的研究

将汉白玉废料通过高温煅烧分解得到氧化钙,再用氯化铵循环液溶解氧化钙制得碱性氯化钙溶液,除去其中的Mg、Fe等杂质得到氯化钙精制溶液,利用化学方法合成得到碳酸钙粉体.用X射线衍射(XRD)、扫描电镜(SEM)及激光粒度分析仪、白度仪对碳酸钙产品的晶相组成、形貌、粒度分布、白度及化学组成进行了分析,所得产品为纯度达98.5%以上、白度达97%以上、平均粒度为80nm左右的球形纳米级碳酸钙.并对碳化反应速率及合成球形纳米碳酸钙的影响因素进行了分析.实验中循环使用NH4Cl,氨的排放量小,减少了环境污染.     

SEISMIC FACIES ANALYSIS BASED ON 3D MULTI-ATTRIBUTE VOLUME CLASSIFICATION, DARIYAN FORMATION, SE PERSIAN GULF

Interpretation of recently acquired 3D seismic data from the adjacent Sirri C and D oilfields in the SE Persian Gulf indicates that a 3D interpretation of seismic facies is crucial to resolve the internal stratal geometries of the Aptian Dariyan Formation. This carbonate formation passes southward into the Shu'aiba Formation, a prolific reservoir rock of similar facies in the UAE. Lack of exposures and limited cored intervals have forced reliance on the seismic data for evidence of the depositional environment and the internal architecture of potential reservoir rocks. The progradational nature of the Dariyan Formation and the occurrence of carbonate build‐ups within it make this stratal geometry complex. The complex internal heterogeneity of the build‐ups and presence of seismic noise make mapping of the build‐ups in 3D space using conventional seismic interpretation tools difficult, despite the availability of high‐quality 3D seismic data covering the area. The high quality seismic and limited well data from this field is one of the few datasets of this kind presented in the literature. A procedure for the hierarchical multi‐attribute analysis of seismic facies using Paradigm's Seis Facies software is used in this study to provide a 3D interpretation of the stratal patterns. Principal component analysis reduces the noise and redundant data by representing the main data variances as a few vector components in a transformed coordinate system. Cluster analysis is performed using those components which have the greatest contribution to the maximum spread of the data variability. Six seismic attribute volumes are used in this study and the result is a single 3D classified volume. Important new information obtained from within the Dariyan Formation gives new insights into its stratigraphic distribution and internal variability. This method of processing seismic data is a step towards exploring for subtle stratigraphic traps in the study area, and may help to identify exploration targets.     

矿物溶解动力学与全球环境

硅酸盐矿物和碳酸盐矿物是构成地壳的主要造岩矿物,论述了两类矿物溶解动力学的研究现状与展望,指出两类矿物的溶解和沉积过程中CO2吸收和释放,对全球环境有重要影响。     

Preparation and properties of poly(ethylene oxide) star polymers

Poly(ethylene oxide) (PEO) star polymers were prepared by anionic polymerization of methacryloyl chloride and glyceryl trimethacrylate with sec‐butyllithium in cyclohexane. The ensuing polymers were grafted with poly(ethylene glycol) of molecular weight 400. The final product was washed with methylene chloride and analyzed with infrared spectroscopy, differential scanning calorimetry, and thermogravimetry. Star polymers of PEO were also prepared by anionic polymerization of glycidol with sec‐butyllithium in cyclohexane. The initiator was chosen so as to yield a polymer of 10,000 molecular weight. The resulting polymers were analyzed by nuclear magnetic resonance, infrared spectroscopy, and thermogravimetry. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 322–327, 2003     

环氧乙烷合成乙二醇的研究进展

介绍了环氧乙烷合成乙二醇的主要生产方法，包括以壳牌、联碳化学公司以及Halcon—SD公司为代表的环氧乙烷直接水合法，环氧乙烷催化水合法和碳酸乙烯酯法，后两种乙二醇生产方法是目前国内外研究开发的热点。催化剂体系是催化水合法工艺的关键，重点介绍了国内外各主要公司对催化剂体系的研究进展及使用效果；碳酸乙烯酯法分为乙二醇和碳酸二甲酯联产法以及碳酸乙烯酯水解法，详细介绍了国内外各主要公司对该技术的研究进展，包括工艺流程、催化剂体系等方面。将3种乙二醇生产方法进行技术经济比较，结果表明，催化水合法和碳酸乙烯酯法在原料消耗和能耗方面占优势。并对我国乙二醇生产工艺技术提出建议。     

Flow of solutions of hydroxypropyl guar-poly(ethylene oxide) mixtures through a porous medium

Summary In flow through porous media, solutions of poly(ethylene oxide) (PEO) exhibit extension thickening, whereas hydroxypropyl guar (HPG) solutions are shear-thinning at high concentrations. The results show that the extension-thickening exhibited by PEO solutions becomes less critical with increasing flow rate as the concentration of HPG in the solution is increased. At high concentrations of HPG, the presence of PEO inhibits the shear-thinning behaviour, without increasing the apparent viscosity of the solution. The presence of HPG reduces the rate and extent of degradation of PEO in the flowing solution.     

用屏蔽暂堵技术封堵水平井裂缝性漏层

克拉玛依油田HW702水平井的大斜度段和水平段,将穿越纵向裂缝发育的二叠系佳木河组储层。为安全钻进和保护油层,用超细碳酸钙和磺化沥青复配后加入复合离子钻井液中成屏蔽暂堵的堵漏钻井液。室内用岩心试验,屏蔽暂堵后渗透率可降为0,暂堵深度小于3cm,可用酸化和射孔解堵。现场使用效果也很好,使HW702水平井顺利完钻,并获得工业油气流。     

Synthesis of nano particle of inorganic oxides by polymer matrix

Ultrafine (⩽ 150 nm) powders of spinels [MFe₂O₄ where M = Ni(II), Co(II) and Zn(II)]; rare-earth orthoferrites [RFeO₃ where R = Sm, Nd and Gd], and rare-earth garnets [R₃Fe₃O₁₂ where R = Sm, Nd and Gd] with good purity and chemical homogeneity were prepared through two new versatile chemical routes. The first route involved the coprecipitation of the desired metal nitrates from their aqueous solution, in presence of a water soluble polymer-polyvinyl alcohol (PVA), by triethyl ammonium carbonate solution. The other process involved complete evaporation of a mixture of optimum amounts of PVA and the desired aqueous metal nitrate solutions, with and without the addition of optimum amounts of urea when the mixture was evaporated to a pasty mass. In addition, detailed study on the reported potassium ferricyanide route was also carried out for the production of the rare-earth orthoferrite powders. The various precursor as well as the heat-treated mixed-oxide powders, prepared through each of the routes, were compared by the physical characterization studies involving thermal gravimetry and differential scanning calorimetry, infrared spectroscopy, X-ray powder diffraction, transmission electron microscopy, and room temperature magnetic measurements.     

Surface tailoring of an ethylene propylene diene elastomeric terpolymer via plasma‐polymerized coating of tetramethyldisiloxane

In the research presented here, we explore the use of a low‐energy plasma to deposit thin silicone polymer films using tetramethyldisiloxane (TMDSO) (H(CH₃)₂? Si? O? Si? (CH₃)₂H) on the surface of an ethylene propylene diene elastomeric terpolymer (EPDM) in order to enhance the surface hydrophobicity, lower the surface energy and improve the degradation/wear characteristics. The processing conditions were varied over a wide range of treatment times and discharge powers to control the physical characteristics, thickness, morphology and chemical structure of the plasma polymer films. Scanning electron microscopy (SEM) shows that pore‐free homogeneous plasma polymer thin films of granular microstructure composed of small grains are formed and that the morphology of the granular structure depends on the plasma processing conditions, such as plasma power and time of deposition. The thicknesses of the coatings were determined using SEM, which confirmed that the thicknesses of the deposited plasma‐polymer films could be precisely controlled by the plasma parameters. The kinetics of plasma‐polymer film deposition were also evaluated. Contact angle measurements of different solvent droplets on the coatings were used to calculate the surface energies of the coatings. These coatings appeared to be hydrophobic and had low surface energies. X‐ray photoelectron spectroscopy (XPS) and photoacoustic Fourier‐transform infrared (PA‐FT‐IR) spectroscopy were used to investigate the detailed chemical structures of the deposited films. The optimum plasma processing conditions to achieve the desired thin plasma polymer coatings are discussed in the light of the chemistry that takes place at the interfaces. Copyright © 2004 Society of Chemical Industry