缝洞型碳酸盐岩油藏流动单元概念和研究方法探讨

流动单元对于提高油田采收率具有很大的实际意义,该项研究在砂岩油藏研究中已取得较大进展。对于缝洞型碳酸盐岩油藏,由于岩石结构构造、成岩后生作用、构造断裂作用、溶蚀作用等多因素对储集空间的影响,已有的流动单元概念及研究技术方法难于应用。以塔河油田为例,针对缝洞型碳酸盐岩地质特征,论证了碳酸盐岩储层渗流屏障的存在及其类型,探索性提出区别于砂岩油藏的缝洞型碳酸盐岩储层流动单元的概念。提出的研究思路和方法包括;油藏压力趋势分析法、井间生产干扰分析法、流体性质差异分析法、井间干扰试井法。结合储层发育特征,初步建立了缝洞型碳酸盐岩流动单元的划分标准。     

翅片式空气冷却器改造

针对茂名石化乙烯工业公司全密度聚乙烯装置翅片式空气冷却器存在的问题。结合生产实际要求进行了改造。将原设备换热芯由不可拆结构改为可抽芯结构。原圆形换热管更换为椭圆管。材质由SS304不锈钢更换为铜，并对改造后的空气冷却器进行了传热核算。理论和实践证明，改造是成功的。     

Effect of fluoropolymer antidripping agent on the microstructure and properties of polyesters

Poly(ethylene terephthalate) (PET) is of excellent mechanical properties and melt processability and is widely used as raw material for textile fibers. However, the flame retardant properties of PET were rather poor, and both reactive and additive phosphorus- and halogen-containing compounds have been employed to enhance the reaction-to-fire properties while the meltdripping behaviour during burning hasn’t been handled properly with the flame retardants. In this work, fluoropolymer was blended with both pure PET (pPET) and reactive phosphorus-containing flame retarded copolyester (fPET), and the flame retardance and char formation and mechanical properties of the resulted pPET and fPET blends were investigated. The tensile strengths of modified pPET samples were worsen whereas those of modified fPET samples were improved at low concentrations. The initial thermal degradation in nitrogen was accelerated remarkably for the two polyesters with fluoropolymer. The oxygen indices of the all modified samples were reduced while char formation and meltdripping suppression were encouraged. The apparent melt viscosity and elasticity for the two polyesters were gained much with antidripping agent. Therefore, fluoropolymer improved char formation of the two polyesters based on the gaseous phase mechanism while the partial suppression of meltdripping behavior and the decrease of mechanical properties mainly originated from the increase of melt viscosity via fibrillation for pPET.     

对我厂防治加热管内碳酸钙垢的思索

分析了我厂两碱法原卤净化后,加热管内壁结碳酸钙垢的原因,探讨了我厂采取加盐酸、加阻垢剂、用超声波阻垢器的方法,以及对加热管内碳酸钙垢防治的情况和存在的问题.     

Synthesis and applications of heterobifunctional poly(ethylene oxide) oligomers

Poly(ethylene oxide) (PEO) oligomers are employed extensively in pharmaceutical and biomedical arenas mainly due to their excellent physical and biological properties, including solubility in water and organic solvents, lack of toxicity, and absence of immunogenicity. PEO can be chemically modified and reacted with, or adsorbed onto, other molecules and surfaces. Sophisticated applications for PEO have increased the demand for PEO oligomers with tailored functionalities, and heterobifunctional PEOs are often needed. This review discusses the synthesis and applications of heterobifunctional PEO oligomers possessing amine, carboxylate, thiol, and maleimide functional groups.     

世界乙烯工业及其进展

阐述了世界乙烯产能需求现状，近扑扩能增产预测，乙烯原料分析以及乙烯生产的技术进展。     

从混联法生产中提取镓的研究

针对联合法厂家资源的分布特点,提出采用化学法和树脂吸附法相结合的方式实现同时回收烧结法和拜尔法循环母液中镓的新工艺,并通过小试和扩试结果分析,阐述了该工艺的可行性。     

乙烯裂解炉对流段局部结构设计改进

介绍了乙烯裂解炉对流段的结构功能,各部件局部结构的改善设计。     

乙烯裂解炉辐射段炉顶密封结构优化设计

乙烯裂解炉的炉顶密封效果关系到装置的安全、稳定运行.针对现行的密封结构,进行了合理的技术改造和优化设计,并经实际投入使用,效果良好,也可进一步推广到类似的炉型上.