Influence of alloy ingredients on mechanical properties of ternary boride hard alloy clad materials

Using Mo, B-Fe alloy and Fe powders as raw materials, and adding C, Cr and Ni ingredients, respectively, or C, Cr and Ni mixed powders, ternary boride hard alloy clad materials was prepared on Q235 steel substrate by means of in-situ reaction and vacuum liquid phase sintering technology. The influence of alloy ingredients on the mechanical properties of ternary boride hard alloy clad materials was investigated. The results indicate that a mixture of 0.8% C, 5% Cr and 2% Ni ingredients gives a ternary boride hard alloy clad material with optimal mechanical properties, such as high transverse rupture strength, high hardness and good wear resistance.     

Formation of an amorphous phase in thermally sprayed WC-Co

A WC-Co coating was sprayed by the high-velocity oxyfuel process using a feedstock of tungsten carbide clad with cobalt. The structure of the sprayed coating was characterized by x-ray diffraction (XRD), differential scanning calorimetry (DSC), and differential thermal analysis (DTA). It was found that an amorphous phase of Co-W-C ternary alloy observed as a large, broad peak in the XRD pattern can be formed in the as-sprayed WC-Co coating. The DSC, DTA, and XRD analyses revealed that the amorphous phase crystallized at a temperature of around 873 K to metallic cobalt, Co₆W₆C, and tungsten with appreciable precipitation of free carbon. The heat treatment of as-sprayed WC-Co coating at a high temperature of 1173 K suggests that annealing at a temperature higher than about 1104 K will promote the reaction of tungsten and cobalt with carbon to form the complex carbide C₀₆W₆C.     

偏晶合金液-液相变过程模拟

建立了能描述在弥散相液滴形核、扩散长大、碰撞凝并及两液相空间分离等因素共同作用下，偏晶合金液-液相变过程中组织演变过程的数学模型。将计算的温度场和浓度场与控制凝固组织演变的动力学方程相耦合，模拟研究了单向冷却条件下Al-Pb合金液-液相变过程中的组织演变过程。结果表明，随着冷却的进行，液-液相变区不断由试样底部向试样顶部推进，直至贯穿整个试样。由于在凝固过程中弥散相液滴进行Marangoni迁移和Stokes运动，试样中的某些部位会出现液滴贫化、过饱和度增加和多次形核现象。     

FORMATION OF MANGANESE SILICIDE THIN FILMS BY SOLID PHASE REACTION

1. IntroductionThe transition metal silicides have attraeted much attention because of their potentialapplicatiOIl in very large scale integration (VLSI) de.ice[1]. Near-noble metal silicides canbe used as Schottky al1d ohn1ic col1tacts in silicon-based d…     

APPLICATION OF MOLECULAR ORBITAL THEORY TO ANALYSIS OF PHASE STABILITY FOR ALLOYS

The critical _d vahues ( _ ) of the γ/(γ+σ).γ/(γ+μ) and γ/(γ+γ') phase boundaries insome ternar alloy phase diagrams at various temperatures are calculated by averaging the _d values of sererai selected characteristic points at the phase boundaries.Approxmateequations for the temperature dependence of the critical _d of γ/(γ+σ).γ/(γ+μ) andγ/(γ+γ') phase boundaries are established.The accuracy of the analysis is discussed in detail.It is found for the first time that the average value of the bondorder _ at the phase boundaries ts also approximatelr a constant and therefore a criticalaverage bond order _ like - can be introduced for the analysts of phase stability     

填隙Ti2Ni相形成条件的模式识别分析

在多维键参数空间中对填隙Ti_2Ni相化合物的形成条件做模式识别分析,由于前过渡金属原子组成的八面体空穴中填入C,N.O原子使Ti_2Ni结构稳定化,此结构的分布区扩大,邻近的Al_2Cu,MoSi_2结构分布区减小。     

Bi-Pb-Tl三元系相图

用室温、高温X射线衍射及淬火的方法,测定了Bi-Pb-Tl三元系25℃的等温截面及该体系中的相结构。     

化合物TbMn6Sn6的磁性和磁相变

采用分子场理论模型对稀土-过渡族金属间化合物的磁性、自旋重取向相变和场诱导的一级磁相变进行了研究.从理论上计算了TbMn6Sn6的易磁化方向随温度的变化以及不同温度时的磁化曲线,描述了自旋重取向相变和场诱导的一级磁相变.基于单离子模型计算了Tb离子和化合物的一阶和二阶磁晶各向异性常数及其随温度的变化,得到了和实验数据基本一致的结果.结果表明:Mn次晶格和Tb次晶格磁晶各向异性能之间的相互竞争是导致自旋重取向相变的物理机制,而稀土离子的四阶晶场项对场诱导的一级磁相变产生很大的影响.     

WZ型系列真空铝钎焊炉的研制

简要介绍了WZ型系列真空铝钎焊炉型号，规格等技术参数，并以WZLQH－30型真空铝钎焊炉为例介绍了真空铝钎焊炉的结构及其特点，总结了真空铝钎焊炉设计研究及调试过程中的一些经验体会。     

超细金属粉末的制备方法

介绍了机械法、物理法、物理-化学法等超细金属粉末的制备方法和研究进展及生产应用情况.虽然超细金属粉末的制备方法有很多种,但每种方法都有一定的局限性,存在许多需要解决和完善的问题.机械法是制备金属粉末的基本方法,但大多数机械法在制取粉末后存在分级困难的问题;旋转电极法和气体雾化法是目前制备高性能金属及合金粉末的主要方法,但生产效率低,超细粉末的收得率不高,能耗相对较大;气流磨粉碎法、氢化脱氢法适合大批量工业化生产,但对原料金属或合金的选择性较强.