添加尖晶石对氧化锌压敏电阻性能的影响

通过添加尖晶石（Ｚｎ７Ｓｂ２Ｏ（１２））改性研制出电位梯度为１００Ｖ／ｍｍ左右，压敏电压在８２～１５０Ｖ，通流容量可达１６００Ａ／ｃｍ２，漏电流＜２μＡ系列压敏电阻器，从而满足了国内电话交换机行业对８２Ｖ、１００Ｖ、１２０Ｖ、１５０Ｖ压敏电阻器的电性能要求。从工艺的角度解释了尖晶石对氧化锌瓷晶粒的作用原理，并分析了尖晶石的微观结构及粒度对瓷片电性能的影响。     

Lubricating behavior of iron rhenate and its relation to matching pairs

The iron rhenate was compounded by chemical method, which may be generated during wear process of Fe-Re alloys at elevated temperature. The friction coefficient of iron rhenate has been determined by a pin-on-disc device. The results show that iron rhenate plays role of lubricating at RT-600 °C. The lubricating behavior is related to the matching pairs. The hardness of the materials of matching pairs, compatibility of iron rhenate with materials of matching pairs and surface roughness of disc affect the lubricating behavior of iron rhenate mostly. The principle of matching pairs is proposed. Project supported by the National Natural Science Foundation of China Synopsis of the first author Xiong Dangsheng. associated professor, born in 1960. Current research fields include high-temperature self-lubricating alloys and tribological properties of material.     

铸轧5052合金冷隔缺陷产生的机理研究

阐述了5052合金铸轧坯料生产时冷隔缺陷产生的机理,结合超型FATA—HUNTERΦ1003×1850mm机多年的生产实践经验,提出了消除铸轧冷隔缺陷的措施。     

WO3 pillar-type and helical-type thin film structures to be used in microbatteries

In the present study WO₃ thin films were deposited by sputtering onto ITO glass, W/ITO and Si substrates by using the glancing angle deposition (GLAD) technique, with the objective of applying these materials in electrochemical intercalation devices. The thin films microstructure and electrochemical behavior were determined through scanning electron microscopy (SEM) and cycling at constant current with potential limitation. By mainly adjusting the substrate holder speed rotation, pillar-type and helical-type structures were obtained under high and low speed rotation levels, respectively. The electrochemical results showed that the best charge capacity performance was obtained for the WO₃/W/ITO films with pillar-type structures, which are more porous.     

乙烯直接氧化合成乙酸

用常规固定床反应器考察了Pd-SiW12/SiO2催化剂还原条件对乙烯直接氧化合成乙酸催化性能的影响。催化剂用H2在200－300℃还原后Pd 的分散度较高，其催化活性远高于肼在液相中还原的催化剂，在乙烯气相氧化合成乙酸反应的原料气中，适量1，2－二氯乙烷的存在有助于提高乙酸的选择性和时空产率，初步考察了Pd-Se-SiW12/SiO2催化剂连续206h运转的稳定性，结果表明，催化剂中Pd晶粒的长大和硅钨酸的流失是造成催化剂失活的主要原因。     

重油接触裂解制乙烯的HCC工艺研究

重油裂解制乙烯的HCC技术采用与FCC类似的“反应—再生”工艺技术,利用重油直接裂解制乙烯,兼产丙烯、丁烯和轻质芳烃,既可扩大乙烯的原料的来源,又可降低生产成本。HCC工艺的乙烯产率可达19%～27%,总烯烃产率大于50%。     

SO_4~(2-)(S_2O_8~(2-))/Fe_2O_3-SiO_2固体超强酸对乙酸/丁醇酯化反应的催化性能研究

研究了SO2 -4/Fe2 O3 SiO2 固体超强酸对乙酸 /丁醇酯化反应的催化作用 ,得到合适的工艺条件 :复合氧化物中n(Fe)∶n(Si) =1∶2 ,浸渍的H2 SO4浓度 1mol/L ,5 5 0℃预焙烧活化 3h ,催化剂用量 0 .8g ,酯化反应时间 4h ,乙酸的转化率达 96 .3%。在此条件下制得S2 O2 -8/Fe2 O3 SiO2 固体超强酸催化剂 ,并考察了其催化活性 ,实验结果显示该固体超强酸具有更高的催化活性 ,乙酸转化率高达 98.6 %。     

乙烯装置制冷系统的用能分析

通过对制冷压缩机功耗的模拟和对实际运行数据的分析,比较了乙烯装置中的复迭多级制冷系统和混合冷剂制冷系统的用能状况,分析了混合冷剂制冷的优点和不足。采用AspenPlus10.2软件模拟的结果表明,采用混合冷剂制冷技术的丙烯-混合冷剂复迭制冷系统比传统的丙烯-乙烯复迭制冷系统节省功耗4.3GJ/h,制冷压缩机损系数则从47.6%减小到43.3%,而系统效率由25.0%提高到26.6%。虽混合冷剂在换热过程中出现的气液两相流,会在一定程度上抵消其在热力学效率上的优势,但混合制冷技术用于乙烯装置仍可降低能耗、提高热力学效率。     

Vanadium species in new catalysts for the selective oxidation of methane to formaldehyde: Activation of the catalytic sites

New vanadium oxide supported on mesoporous silica catalysts for the oxidation of methane to formaldehyde were investigated by infrared and Raman spectroscopies to identify and characterize the molecular structure of the most active and selective catalytic sites. In situ and operando experiments have been conducted in order to understand the redox and hydroxylation/dehydroxylation processes of the vanadium species. (SiO)₂VO(OH) species were identified in these catalysts in reaction conditions and shown to undergo a deprotonation at 580 °C under vacuum, leading to a site giving a photoluminescence band at 550 nm attributed to reverse radiative decay from the excited triplet state:

(V⁴⁺–O⁻)^*  (V⁵⁺O²⁻). An activation mechanism of vanadium monomeric species with electrophilic oxygen species is proposed.