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81.
氧化钨物理特征的测量 总被引:2,自引:0,他引:2
对铵钨青铜(ATB)、氢钨青铜(HTB),紫色氧化钨(TVO)和蓝色氧化钨(TBO)四种氧化钨粉的氮气吸附/脱附等温线数据的分析。可以得出其表面积,微孔体积,微孔分布,中孔体积,平均孔径和分数维数。吸附/脱附等温线数据的分析表明,TVO粉末具有最大的中孔体积,最小的微孔体积,最窄的孔径分布,最小的分数维数和最大的平均孔径,其有利于氢还原制取超细钨粉,而不利于掺杂工艺,HTB粉末具有最大的微孔体积,最宽的孔径分布,最高的分数维数和最小的平均孔径,对于掺杂工艺来说是有利的,ATB和ABO的上述参数界于TVO和HTB之间。结果表明,利用吸附/脱附等温线来研究氧化物的物理特征是一个很好的方法;在氧化钨用于氢还原工艺和掺杂工艺之前必须研究其物理特征。 相似文献
82.
介绍了以菱锌矿为原料生产轻质氧化锌的方法,论述了反应酸浓度,煅烧温度,溶液PH值对实验的影响,并对生产工艺条件进行了研究。其工艺流程是将粉碎后的菱锌矿进行循环酸浸,净化后再直接和碳化母液反应,经沉降后再煅烧分解为轻质氧化锌,产品质量符合国家标准,视比容大,活性强,成本低,经济效益显著。 相似文献
83.
Copolyesters containing poly(ethylene terephthalate) and poly(hexamethylene terephthalate) (PHT) were prepared by a melt condensation reaction. The copolymers were characterised by infrared spectroscopy and intrinsic viscosity measurements. The density of the copolyesters decreased with increasing percentage of PHT segments in the backbone. Glass transition temperatures (Tg). melting points (Tm) and crystallisation temperatures (Tc) were determined by differential scanning calorimetry. An increase in the percentage of PHT resulted in decrease in Tg, Tm and Tc. The as-prepared copolyesters were crystalline in nature and no exotherm indicative of cold crystallisation was observed. The relative thermal stability of the polymers was evaluated by dynamic thermogravimetry in a nitrogen atmosphere. An increase in percentage of PHT resulted in a decrease in initial decomposition temperature. The rate of crystallisation of the copolymers was studied by small angle light scattering. An increase in percentage of PHT resulted in an increase in the rate of crystallisation. 相似文献
84.
The mechanical fracture strength and toughness of short-fibre composites, injection moulded from compounds of poly(ethylene terephthalate) (PET) containing 10 and 30% (by weight) (w/o) glass, have been investigated and the dependence upon matrix hydrolytic stability determined. Mouldings have been characterised by several physical techniques to evaluate molecular weight, degradation rates, crystallinity and morphology, whilst time-dependent gravimetric data were derived to quantify sorption kinetics and allow comparisons with theoretical reaction rates to be made. During melt processing, PET is hydrolysed extremely rapidly by traces of moisture (<0.02w/o). yet the inherent strength of moulded composites declines significantly only below an apparently critical molecular weight. However, on long-term humid ageing in hot water, impact behaviour especially is rendered more complex by simultaneous crystallisation, molecular reorder and losses of interfacial bond strength. 相似文献
85.
The Synthesis of Sulfated Titanium Oxide Nanotubes 总被引:1,自引:0,他引:1
Chiu-Hsun Lin Shu-Hua Chien Jiunn-Hsing Chao Chyi-Yang Sheu Yu-Cheng Cheng Ya-Jean Huang Chih-Hsiang Tsai 《Catalysis Letters》2002,80(3-4):153-159
TiO2 nanotubes can be prepared in gram quantities by treating anatase TiO2 powder with concentrated NaOH solution. These TiO2 nanotubes acquired strong acidity after being impregnated with sulfuric acid solution and calcined at 300 °C. The anatase TiO2 powder used to prepare the nanotube did not catalyze the esterification between cyclohexanol and acetic acid, while sulfated TiO2 nanotubes were very reactive toward the esterification reaction. 相似文献
86.
In the oxidation of TiAl alloys, the role of scale-growth stresses formed during oxidation has, thus far, been unknown. In the present paper the oxide-growth stresses were investigated by the deflection-test method in monofacial oxidation (DTMO) accompanied by acoustic-emission measurements. On unmodified surfaces the growth stresses are compressive and reach levels of around –100 MPa. At the same time, significant acoustic emission occurs indicating that even under isothermal conditions, stresses are relieved by a scale-cracking mechanism. For oxide scales on TiAl surfaces, which had been ion implanted with chlorine before oxidation, a very thin protective alumina layer is formed which, however, develops growth stresses in the range of several GPa, accompanied by intensive acoustic emission. In all stress–time curves, a dynamic situation is observed. This consists of phases of stress relief by scale microcracking and phases of stresses increase due to crack healing and further oxide growth. As a result, the level of stress as a function of oxidation time, is characterized by an oscillating course. 相似文献
87.
88.
Magnus Rnning Florian Huber Hilde Meland Hilde Venvik De Chen Anders Holmen 《Catalysis Today》2005,100(3-4):249-254
In order to investigate the effect of cerium oxide on Cu–Zn-based mixed-oxide catalysts four catalyst samples were characterized by means of XRD, in situ XANES and thermogravimetric analysis. The activity of the catalyst samples was tested for the forward water–gas shift reaction. Cerium oxide was found to increase the crystallinity of the ZnO phase indicating a segregation of the Cu and ZnO phases. The TOF of the water–gas shift reaction based on chemisorption data was found to be independent of composition and preparation conditions of the four catalyst samples. In contrast, the catalyst stability depends on composition and preparation conditions. Cerium oxide impregnated before calcination of the hydrotalcite-based Cu–Zn precursors leads to a more stable water–gas shift catalyst. 相似文献
89.
90.
以十二烷基磺酸钠为模板剂、乙二胺为碱性介质,将水热法合成的氧化铁/十二烷基磺酸钠复合中孔材料在550℃、空气气氛中煅烧10h,除去模板剂,得到介孔氧化铁。通过X射线衍射、氮气吸附-脱附方法对介孔氧化铁的晶体结构和表面物性进行表征。表征结果显示,煅烧后的介孔氧化铁具有典型的六方介孔的结构特征,平均孔径为5.4nm。将介孔氧化铁用于催化正辛醇乙氧基化反应,研究结果表明,升高反应温度和初始压力、增加催化剂用量,可加快环氧乙烷的反应速率,同时产物的相对分子质量分布较窄。当平均聚合度为6.5时,正辛醇聚氧乙烯醚相对分子质量分布的选择性系数达到21.1。 相似文献