凉水塔技术研究与探讨

通过对我厂引进的大型进口设备———Marley—600型冷却塔进行技术改造情况的介绍,具体分析了进口材料与国产材料的本质区别,并具体介绍了我厂的使用情况。此次技术改造在大化肥行业是首次进行,并取得了成功。论证了进口设备走国产化道路的必然性及可行性,从而为我国的其他大型Marley—600型冷却塔设备走国产化道路作了较好的铺垫。     

循环冷却水处理新化学药剂的发展

随着水资源的日益紧张和排放标准的日益严格,要求循环冷却水处理药剂能适应高硬度、高碱度、高氯离子、高有机污染的需要,本文介绍的国外的新型药剂－－聚氨基聚醚基甲叉膦酸、膦酰基羧酸、聚天冬氨酸、过氧乙酸、４,５－二氯－２－正丁基－４－异噻啉丁酮等具有优良的阻垢和杀菌作用,并且对环境友好。     

石化企业循环水系统的节水运行与管理

围绕工业循环冷却水系统的工艺原理及水质特点，全面分析阐述了石化循环水系统开展节水运行管理的途径方法及其注意事项，天津石化公司乙烯厂在此方面取得了良好的效果。     

低位真空冷却装置在磷酸系统中的应用

葛丰化工厂磷酸萃取槽反应热不能有效移出,限制了生产能力的提高,通过采用低位真空冷却装置移走反应热,并同时改造水循环系统。改造后,投矿浆量达16t/h〔矿浆w(H2O)35%〕,生产能力从技改前2.67tP2O5/h提高到4.56tP2O5/h,萃取温度稳定控制在83～85℃。由于结晶状况改善,萃取率、洗涤率分别提高达96.33%、99.04%,能耗从181.3kW·h/tP2O5降低到149.8kW·h/tP2O5,含氟废气排放量从30000m3/h减少到小于6000m3/h。     

双工质塑料冷混机设计研讨

介绍了可提高塑料混合时冷却效率的双工质塑料冷混机，并简要叙述了立式，卧式和立式搅龙双工质冷混机却装置冷却物料的工序。     

循环水冷却塔的改造

分析了循环水冷却塔存在的问题,重点论述了冷却塔的改造及其经济效益。     

A study on crystallization kinetics of pentaerythritol in a batch cooling crystallizer

The crystallization kinetics of pentaerythritol (PeE) in aqueous solution in the presence of impurity or not in a batch cooling crystallizer was explored. Also, the solubility and the nucleation and crystal growth kinetics of PeE in aqueous solution were investigated. A second-order dependence of PeE growth rate on supersaturation is observed in pure PeE-water system. The crystal growth rate of PeE-water system in the presence of impurity is proportional to the supersaturation to the 3.5 power. The nucleation and crystal growth behaviors for PeE-water system in a batch cooling crystallizer were grasped according to Mersmann's criteria. The nucleation in this crystallizer was found to act with heterogeneous nucleation. In this system, it suggests that the crystal growth is controlled by a complex mechanism behavior of surface integrated and diffusion limited. Simplified relation was derived for calculation of mean crystal size of product crystals from the batch cooling crystallizer. The obtained relation was verified by a set of experiments.     

通用循环水冷却器延时关闭控制联动电路设计

目前许多大型仪器的循环冷却水系统，都没有提供相应的自动化延时关闭装置，给工作带来不便。经过分析，将主机供电系统与循环冷却水供电系统进行关联，设计了联动电路，实现了正常关机，循环冷却水系统自动延时20min后关闭。既节约了工作时间，又提高了工作效率。     

Evaporative light scattering mass detection for high-performance liquid chromatographic analysis of sucrose polyester blends in cooking oils

A high-performance liquid chromatographic method is described to determine the sucrose polyester (SPE) content in seven blends of cooking oils. Four gel-permeation chromatography (GPC) columns were used in series with an evaporative light scattering mass detector to separate the SPE from the acylglycerols in the final chromatogram. The SPE fraction was collected off the GPC column and injected onto a reverse-phase C-18 column for quantitation with sucrose octaacetate as an internal standard and a gradient of nonaqueous solvents as mobile phase. The chromatograms were interference-free, with only two sharp peaks appearing. The standards were linear from 500 to 5000 μg/mL with a correlation coefficient of r=0.999. The mean percent recovery (n=9) and standard deviation were 102±6.7. The detector could detect amounts as low as 5 μg SPE.     

抗震冷却塔金属淋水填料研究

冷却塔的冷却效果主要由淋水填料的冷却数和冷却塔的有效高度决定,淋水填料的换热性能决定了冷却塔的主要换热效果。为提高抗震冷却塔的抗震效果,淋水填料采用金属填料。通过在某工程中抗震冷却塔金属填料与普通塑料填料应用的对比分析,研究金属填料的特点及适用性,为抗震冷却塔的设计提供依据。