Catalytic conversion of methane to benzene over Mo/ZSM-5

Dehydroaromatization of methane to benzene occurs over a 2 wt% Mo/ZSM-5 catalyst at 700C under non-oxidizing conditions. Following an initial induction period, during which CH₄ reactant reduces the original Mo⁶⁺ ions in the zeolite to Mo₂C and deposition of coke occurs, a benzene selectivity of 70% at a CH₄ conversion of 8–10% could be sustained for more than 16 h. X-ray photoelectron spectroscopy and X-ray powder diffraction measurements indicate that the reduced Mo is highly dispersed in the channels of the zeolite. Initial activation of CH₄ reactant occurs on Mo₂C sites, leading to the formation of C₂H₄ as the primary product. The latter then undergoes subsequent oligomerization reactions on acidic sites of the zeolite to form aromatic products.     

用工业废碱水处理反渗透法高含盐排放浓水

反渗透处理装置排放的浓水含盐量很高，如果不经处理直接排放势必对周围环境造成污染和水的浪费，氧化铝生产工艺废水中含有大量的碳酸钠、苛性碱等碱类物质，pH值达到13左右，回水量约2000m^3／h，用这些废水和反渗透浓水混合进行软化处理，降低浓水中的钙镁离子含量，并对难去除的硫酸盐进行稀释降低浓度，回用到蒸发循环水系统作为补充用水、氧化铝生产部分工艺用水、设备冷却用水，达到浓水回收再利用的目的。该方案实施后效果十分显著，回收反渗透浓水约60m^3／h，减少污水系统补充新水，降低生产用水费用约每年176万元。     

烟气脱硫技术在浮法玻璃线上的应用

简介了烟气脱硫技术在浮法玻璃线上的应用情况,以工程实例详细介绍该技术在某浮法玻璃线上的设计、实施、应用情况以及重点、难点问题的处理,为该技术在浮法玻璃线的应用提供借鉴和参考.     

An analysis of transport phenomena for multi-solid particle systems at higher reynolds numbers by a standard karman—pohlhausen method—I Momentum transfer

Using the concentric spheres free surface model and a standard 4th polynomial Karman—Pohlansen method, the dimensionless tangential stress distribution, and the dimensionless pressure distribution around a solid sphere in a swarm, and the viscous, form and total drag coefficient for multi-solid particle systems were computed numerically at higher Reynolds numbers. The void function obtained from the drag coefficient for multiparticle system was comparative to the experimental data. The friction factor for multi-particle systems so computed agreed with the experimental data of packed and distended beds.     

Switch on to games: Can digital games aid post-work recovery?

Recovery is a necessary factor in avoiding work-related strain and in feeling prepared for the next day of work. In order for recovery to be successful, an individual must experience psychological detachment from work, relaxation, mastery experiences and a sense of control, all of which have been argued to be assisted by digital game use. However, it is unclear whether these associations will be greater for certain digital game genres, or whether this would extend to other recovery-related outcomes, for instance work home interference (WHI), where the stress from work interferes with home-life. These factors may be vital in determining whether interventions aimed at improving recovery using digital games would be effective, and what form these should take. The present research surveyed 491 participants and found that the total number of hours spent playing digital games per week was positively correlated with overall recovery. Correlations varied with genre, highlighting the importance of game characteristics in this relationship: first person shooters and action games were most highly correlated with recovery. Moreover, digital game use was not related to a reduction in work–home interference. When restricting the analysis to gamers who report to have developed online relationships, online social support mediated the relationship between digital game use and recovery. Results are discussed in terms of how digital games may be utilised to improve recovery and reduce work-related stress.     

黄荆提取物对几种害虫的杀虫活性

研究了黄荆种子二氯甲烷提取物对5种害虫的杀虫活性以及对天敌异色瓢虫的安全性。结果表明：黄荆提取物对菜青虫、小菜蛾、麦长管蚜和桃蚜都有较高的杀虫活性，尤其是对菜青虫的活性最高，稀释100倍，处理4龄幼虫死亡率可达93．3％。但对大猿叶甲的杀虫活性则很低。黄荆提取物对异色瓢虫幼虫有一定的杀虫活性，但对其成虫无任何影响。本研究结果为开发利用这一新的杀虫植物资源提供了依据。     

现有合成氨厂建设8万吨/年硫酸钾及4万吨/年纯碱装置的可行性

本文试图论述现有合成氨厂改变产品结构,采取以生产化肥为主,联产化工产品。通过对钾芒硝法工艺及联碱工艺技术路线的选择,技术经济分析,以期提高化肥厂的经济效益。     

制革工业污泥中Cr~(3+)的回收试验

对制革工业污泥中Cr回收与再利用进行了试验。试验表明:Cr的总回收率的高低主要决定于Cr3+的氧化是否彻底,在n(H2O2):n(Cr3+)为7.5,pH=10,温度为60℃以及反应时间为30min的条件下,污泥中Cr3+氧化率接近90%,总回收率可以达到80%以上。     

变压吸附法处理硝酸尾气的研究

概述了硝酸尾气的处理方法，详述了变压吸附法处理硝酸尾气的原理，提出了处理尾气的工艺过程和工艺指标。     

轨迹空间中基于特征符号搜索算法的非刚体三维运动重建研究

现有研究一般是在正交约束条件下采用最小二乘法来求解三维运动轨迹基重建问题,然而这些算法的性能容易受噪声影响,产生不适定性。为此,通过利用离散线性的方法为三维运动搜索最优轨迹基系数和三维结构,建立了一种基于特征符号搜索算法的三维运动轨迹基重建方法。利用该方法,对一系列单目图像序列进行了重建实验研究,结果表明所提出的方法是可行的,并提高了重建算法的准确性。