催化燃烧炉的节能性分析

传统的火焰燃气炉往往会产生不同数量的氮氧化物(NO和NO2)、一氧化碳等不完全燃烧产物,造成了环境污染和能源浪费.催化燃烧作为一种新的燃烧方式,打破了传统火焰燃烧的可燃界限,实现了贫甲烷/空气混合物在可燃界限以下的燃烧,燃烧效率高,提高了能源利用率.将催化燃烧应用于燃气炉,可以解决燃气炉由于火焰燃烧带来的燃烧效率低等缺点,达到节约能源的目的.以催化燃烧和燃气炉为依据,在催化燃烧炉Ⅰ型的基础上研制出催化燃烧炉Ⅱ型,分析了催化燃烧炉的热损失以及热效率,并与传统火焰燃烧炉做了比较.结果表明,催化燃烧炉Ⅱ型的热损失并不大,热效率较高,且其污染物排放量极低.     

济钢350m^3高炉高富氧生产技术

分析了济钢350m^3高炉高富氧对产量,理论燃烧温度,炉况顺行状况,焦比和生产效益的影响,高富氧可提高产量,但升高焦比和高炉理论燃烧温度,一定程度上影响高炉顺行,存在富氧效益最大化的适宜富氧率.高炉生产应低富氧高喷煤,根据钢目前的情况,富氧率经2%-3%为宜.     

偶联剂处理硅灰石填充不饱和聚酯树脂的研究

对针状硅灰石 (L∶D≥ 10∶32 5目 )提纯后 ,采用偶联剂进行表面处理 ,将硅灰石按不同比例填充于不饱和聚酯树脂体系中 ,研究了材料的性能。结果表明 ,改性后的硅灰石可显著改善不饱和聚酯的性能。     

New developments in speciality polymers: polymeric stabilizers

Many new speciality polymers have been developed in the last few years. In this paper polymeric stabilizers (antioxidants, flame retardants and ultraviolet stabilizers) will be discussed. Polymeric antioxidants of the hindered-phenol type, copolymers of 2,6-ditertiarybutyl-4-vinyl(or isopropenyl)phenol with styrene, methyl methacrylate, or more importantly butadiene or isoprene have been prepared; hydrogenation of the latter copolymers gave copolymers of the two polymerizable phenolic antioxidants with ethylene or ethylene/propylene. The polymeric antioxidants have been blended with diene polymers and selected polyolefins and have improved the long-term oxidative stability of these polymers. Polymeric flame retardants have been prepared by copolymerizing styrene and/or acrylonitrile with acrylates and methacrylates of aliphatic bromine-containing alcohols or bromine-containing phenols. Polymers with polymer-bound flame retardants have a higher limiting oxygen index compared with the original polymer. A new class of polymerizable ultraviolet stabilizers has also been developed; these stabilizers are styryl, α-methylstyryl, acryloyl and methacryloyl derivatives of 2(2-hydroxyphenyl)2H-benzotriazoles. These monomers have been copolymerized with styrene, acrylates and methacrylates. 2(2-Hydroxyphenyl)2H-benzotriazoles substituted in the 4 position of the benzotriazole ring with hydroxyl, acetoxy or carboxyl groups suitable for incorporation into polyesters, polycarbonates, polyamides and epoxy resins have also been synthesized. All 2(2-hydroxyphenyl)2H-benzotriazole ultraviolet absorbers and the polymers into which they are incorporated have high light absorbency with γ_max between 330 and 350 nm and extinction coefficients in some cases as high as 4.5 × 10⁴ 1 mol^?1 cm^?1.     

Formation and investigation of epoxy intumescent compositions modified by active additives

Results are reported of research on intumescent composites based on epoxy resin cross‐linked with polyethylene polyamine and containing ammonium polyphosphate and such modifying additives as calcium borate, manganese dioxide, nickel, and chromium, containing tubulenes as gas‐formers and carbonization stimulators. The changes in composition and physicochemical properties of modified compositions under conditions of heat and fire were investigated by X‐ray photo‐electron spectroscopy, atomic force microscopy, and local force spectroscopy. Ammonium polyphosphate mainly stimulates carbonization processes on the inner surface of a bubble being formed during foam coke formation. The introduction of metal‐containing tubulenes leads to the formation of fire‐retardant and low flammability‐compositions with high coke and carbon structures content. The use of calcium borate in the compositions considerably increases the strength of foam coke being formed. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 1477–1483, 2002     

毛/涤纱分散/酸性(媒染)染料一浴法筒子染色工艺

毛/涤纱分散/酸性(媒染)染料一浴法筒子染色工艺,在100℃条件下能满足毛、涤两种纤维同时上染,染色产品具有着色深浓鲜艳,色泽一致,各项牢度符合要求,对纤维无损伤等优点,从而缩短生产时间,降低成本,提高经济效益。     

负离子功能针织物在直接蒸发冷却式空调中的应用

在分析负离子净化空气的原理及环境状况与空气中负离子浓度的关系基础上,应用负离子功能粘胶长丝和涤纶短纤混纺纱针织物作为空调滤材,利用空调出风(冷风)使针织物滤材试样飘动,相互拍击摩擦,使空调出风中的氧气分子和水分发生有效电离,从而产生大量空气负离子。实验结果表明,负离子功能粘胶长丝和涤纶短纤混纺纱针织物都有释放空气负离子的功能;而且在同规格纱线的平针组织、双罗纹组织、蜂巢组织和畦编组织针织物中,畦编组织针织物释放的负离子量最大;空气相对湿度对功能材料释放负离子数量有明显影响,当相对湿度在65%~70%时释放的负离子量趋于最大。     

端基封闭法合成双环戊二烯改性不饱和聚酯

研究端基封闭法合成双环戊二烯（ＤＣＰＤ）改性不饱和聚能工艺条件对产品性能的影响。研究结果表明，合成反应的最佳工艺条件为总酸酐：丙二醇：ＤＣＰＤ＝１：１．１：０．１─０．１６；封端反应温度１３０─１４０℃催化剂量为总重量的０．０２％─０．０３％；聚酯酸值５０ｍｇｋＯＨ·ｇ￣（－１）时滴加ＤＣＰＤ，滴加时间控制在１─２小时；加成反应时间为２小时左右。     

Flame retardant and the degradation mechanism of high impact polystyrene/Fe-montmorillonite nanocomposites

High impact polystyrene/Fe-montmorillonite (HIPS/Fe-MMT) nanocomposites were successfully prepared by melting intercalation. The nanostructures of HIPS/Fe-MMT were testified by X-ray diffraction (XRD) and transmission electron microscope (TEM). Corresponding to pure HIPS, the thermal stability of HIPS/Fe-MMT nanocomposites was notably improved. The peaks of heat release rate (PHRR) and the mass loss rate (MLR) were significantly reduced after the formation of the HIPS/Fe-MMT nanocomposites from cone calorimetry. And nanocomposites PHRR was further lower with the increase of Fe-MMT content in the range of 1 to 5 wt%. The degradation mechanism of HIPS and HIPS/Fe-MMT nanocomposites was conducted by pyrolysis gas chromatography mass spectrometry (Py-GC-MS). And the reason of the enhancement of thermal stability maybe is that structural iron is the operative site for radical trapping in the Fe-MMT and the nanostructure enhances the interaction of the chains of the HIPS.     

新型油脂--蔗糖豆油酸多酯的合成研究

用蔗糖和豆油酸甲酯合成了蔗糖豆油酸多酯，通过单因素及正交实验，得出合成蔗糖豆油酸多酯最佳合成条件为：豆油酸甲酯与蔗糖摩尔比为10：1。反应温度130℃，反应时间6h，此条件下反应产率达到92．9％。