UWinBatch配方管理软件在精细化工行业的应用研究

本文首先从核心理念、实现机理上对批量过程控制标准ISA S88进行了全面地解读分析,成功地将S88标准转换成了一个具体的产品--UWinBatch,然后以果汁生产线为例,对UWinBatch的开发过程、丰富的功能模块进行了介绍,最后在某公司的农药生产线项目应用中,以实际效果证明了UWinBatch是一款高度符合S88标准,能给用户带来极大收益的优秀产品。     

Phenolic compounds from vacuum pyrolysis of wood wastes

Various softwood and hardwood bark residues, primary sludges and softwood sawdust residues were processed by vacuum pyrolysis in a laboratory scale batch reactor. The pyrolysis oil, water, charcoal, and gas were recovered and analyzed. The pyrolysis oils were analyzed in details for their content in phenolic compounds after derivatization to their acetyl derivatives. The influence of temperature, heating rate, feedstock bed thickness, particle size and feedstock water pretreatment on the yield of phenols was investigated. The highest yield of phenols was obtained when hardwood bark was soaked in water for 48 hours and pyrolyzed at a temperature of 450°C and a heating rate of 10°C/min. Pyrolysis performance was evaluated in terms of total phenolic yield and composition.     

国内外天然气化工产品发展方案探讨

阐述了国内外天然气化工产品的生产现状和发展趋势，从传统天然气化工产品中规划出乙酸乙烯、聚氯乙烯、甲醇等3个产品链方案，并分别对其产品方案及规模、产品市场、投资估算、主要技术经济指标等进行了分析，提出了当前我国发展天然气化工存在的问题和建议。     

控制饮用水加氯消毒副产物的研究

试验证明高锰酸钾复合药剂与粒状活性炭联用处理技术是一种高效、经济的除污染技术．能够有效地去除水中有机物，尤其是水中的卤代有机物及其前驱物质．这样就充分保证了饮用水的安全性。     

Electroless Plating of Copper on Fluorinated Polyimide Films Modified by Plasma Graft Copolymerization and UV‐induced Graft Copolymerization with 4‐Vinylpyridine

Surface modification of two types of fluorinated polyimide (FPI) films, either by plasma polymerization and deposition of 4‐vinylpyridine (4VP) or by UV‐induced graft copolymerization with 4VP under atmospheric conditions, was carried out for adhesion enhancement with the electrolessly deposited copper. X‐ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FTIR) results revealed that the pyridine groups in the plasma polymerized 4VP (pp‐4VP) layer could be preserved to a large extent under proper glow discharge conditions. The grafted 4VP layer with well‐preserved pyridine groups was used not only as the chemisorption sites for the palladium complexes (without the need for prior sensitization by SnCl₂) during the electroless plating of copper, but also as an adhesion promotion layer for the electrolessly deposited copper. The T‐peel adhesion strength of the electrolessly deposited copper with both the 4VP plasma‐polymerized FPI (pp‐4VP‐FPI) film and the 4VP graft‐copolymerized FPI (4VP‐g‐FPI) film was much higher than that of the electrolessly deposited copper with the pristine or the Ar plasma‐treated FPI films. The high adhesion strength between the electrolessly deposited copper and the surface‐modified FPI film was attributed to the fact that the plasma‐polymerized and the UV graft‐copolymerized 4VP chains were covalently tethered on the FPI surfaces, as well as the fact that these grafted 4VP polymer chains were spatially and reactively distributed into the copper matrix.

     

Movement characteristics of Karst water in a deep mining area

In order to study the movement characteristics of groundwater in a deep mining area and solve the dispute of the distri-bution rule of hydro-chemical zoning which is contradicted by lixiviation water zoning in a horizontal direction, we directed our attention to the source of deep groundwater, its seepage and hydro-chemical characteristics in a typical mining area. We used a neotectonic water-control theory, chemical and isotope methods, as well as a method for analyzing dynamic groundwater conditions. The results indicate that 1) Karst water in the deep and medium parts of this mining area is recharged by vertical leakage through neotectonic fractures rather than seepage along strata from subcrop parts or surrounding flows; 2) from surface to deep leakage paths, the variation in the types of chemical groundwater agrees with the normal lixiviation water distribution rule and the age of mixed groundwater increases; 3) the water-rich zones along neotectonic fractures correspond with water-diluted zones in a hori-zontal direction; 4) the leakage coefficient and water capacity of aquifers increases during the flow process of Kant water along the antidip direction (from west to east) and 5) Karst water in shallow mining areas forms a strong runoff belt along strikes and quickly dilutes the water from deep and medium mining areas. Overall, chemical and dynamic water characteristics actually agree with in terms of the entire consideration for differences in vertical leakage and abnormalities in the zone of water chemical distribution, along a horizontal runoff direction.     

危险化学品突发泄漏事故应急决策系统研究

针对危险化学品突发泄漏事故需要应急反应,通过建立危险化学品及其特性数据库,利用GIS技术,实现地图数据的动态装载,实现一个面向危险化学品突发泄漏事故的应急决策系统.该系统可以向危险化学品相关行业人员提供相关化学品的理化性质,生产、运输所需的工具、操作方法和步骤,实现数据的双向更新,做到对危险化学品的实时监控,并在发生突发泄漏事故时软件能够及时自动生成紧急处置预案,包括处置方法、手段和标准.在突发泄漏事故发生时为领导决策层提供科学依据,实现快速反应,防止重大事故的发生.     

Introduction of fluorin into PBO polymer chains: Toward higher thermal stability and lower dielectric constant

A series of novel fluorinated benzoxazole polymers (6FPBO's) with high thermal stability and low dielectric constant were synthesized by copolymerization of 1,3-diamino-4, 6-dihydroxybenzene dihy-drochloride (DAR), 1,4-benzenedicarboxylic acid (PTA) and various amount of 4'4- (hexafluoroisopro-pylidene) bis (benzoic acid) (BIS-B-AF) in the medium of polyphosphoric acid (PPA). 6FPBO fibers were then obtained via dry-jet wet-spinning technique and characterized by means of Fourier transform infrared (FTIR) spectra, thermogravimetric analysis (TGA), single fiber tensile testing machine and scanning electron microscopy (SEM). FTIR spectrum of 6FPBO fibers indicated that the fluorine groups had been incorporated into PBO molecular chains successfully. TGA curves revealed that 6FPBO fibers possessed high thermal stability just as pure PBO fibers. Moreover, dielectric constant spectrum of 6FPBO exhibited that the polymers had low dielectric constant, especially in the range of high- frequency.     

加快乙烯三聚制1-己烯生产技术成果的工业化

国内自行开发的乙烯三聚帛1－己烯技术已中试成功，主产1－己烯，还可联产1－丬烯，1－癸烯等高碳α-烯烃，都是很有价值的有机化工原料，应用市场前景广阔，尤其是可解除我国聚乙烯共聚单体以及高级润滑油发展的瓶颈。     

三嗪基含氟扩链剂改性水性聚氨酯的合成

利用三聚氰氯（CC）、八氟戊醇（OFP）和乙醇胺（MEA）间的反应先合成了三嗪基含氟扩链剂CC-F，在此基础上制备出系列三嗪基含氟扩链剂改性水性聚氨酯CC-FPUF。利用FTIR和1HNMR对其结构进行表征，并用DLS、XRD、XPS、SEM、WCA和电子万能试验机探究了CC-FPUF制备中所用CC-F的含量(以CC-F、IPDI、CMA-1044、DMPA、S104、TMP和TEA的总质量为基准，下同）对CC-FPUF的乳液粒径、聚合物形态、胶膜形貌、表面元素组成、疏水性能和力学性能的影响。结果表明，随着CC-F含量的增加，CC-FPUF的乳液粒径、胶膜疏水性能和胶膜拉伸强度均有所增加。当CC-F的含量达到8%（CC-FPUF-8）时，胶膜的水接触角最高达到125.8°，相比不含氟的水性聚氨酯（PU）和CC-FPUF-0（CC-F的含量为0）分别增加了60.9°和34.1°；此时胶膜的拉伸强度最大，相比CC-FPUF-0增加了24.47 MPa。胶膜CC-FPUF-8表现出优异的疏水性能和良好的力学性能。