全文获取类型
收费全文 | 2254篇 |
免费 | 152篇 |
国内免费 | 32篇 |
专业分类
电工技术 | 29篇 |
综合类 | 100篇 |
化学工业 | 1537篇 |
金属工艺 | 24篇 |
机械仪表 | 13篇 |
建筑科学 | 36篇 |
矿业工程 | 28篇 |
能源动力 | 17篇 |
轻工业 | 141篇 |
水利工程 | 3篇 |
石油天然气 | 96篇 |
武器工业 | 10篇 |
无线电 | 64篇 |
一般工业技术 | 285篇 |
冶金工业 | 24篇 |
原子能技术 | 21篇 |
自动化技术 | 10篇 |
出版年
2024年 | 8篇 |
2023年 | 28篇 |
2022年 | 33篇 |
2021年 | 41篇 |
2020年 | 57篇 |
2019年 | 42篇 |
2018年 | 42篇 |
2017年 | 54篇 |
2016年 | 79篇 |
2015年 | 77篇 |
2014年 | 107篇 |
2013年 | 131篇 |
2012年 | 166篇 |
2011年 | 139篇 |
2010年 | 115篇 |
2009年 | 142篇 |
2008年 | 111篇 |
2007年 | 142篇 |
2006年 | 128篇 |
2005年 | 132篇 |
2004年 | 94篇 |
2003年 | 112篇 |
2002年 | 76篇 |
2001年 | 64篇 |
2000年 | 60篇 |
1999年 | 48篇 |
1998年 | 41篇 |
1997年 | 32篇 |
1996年 | 13篇 |
1995年 | 36篇 |
1994年 | 16篇 |
1993年 | 13篇 |
1992年 | 18篇 |
1991年 | 8篇 |
1990年 | 3篇 |
1989年 | 6篇 |
1988年 | 4篇 |
1985年 | 4篇 |
1984年 | 9篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1951年 | 1篇 |
排序方式: 共有2438条查询结果,搜索用时 15 毫秒
11.
12.
The equations for predicting the number-average molecular weight are derived on the basis of the three stage polymerization model (TSPM) in this paper. By applying the equations, a plotting approach is proposed to determine the apparent initiator efficiency defined as f[(αtd+1)/2] and the constant of chain transfer to monomer, where f is the initiator efficiency and αtd denotes the fraction of the termination rate constants by disproportionation. Using the approach to plot the experimental data in the literature, it is found that the chain transfer to monomer can be neglected for both methylmethacrylate (MMA) and styrene (St) polymerizations, but it can exert a significant effect on ethylmethacrylate (EMA) polymerization. In addition, the apparent initiator efficiency is found to be independent of reaction temperature and initiator concentration at each stage. The values of f[(αtd+1)/2] at gel effect stage are slightly reduced as compared with that at low conversion stage for MMA and EMA polymerizations. However, it decreases significantly at gel effect stage for St polymerization. Using the equations derived and the apparent initiator efficiencies obtained from TSPM plots, the number-average molecular weights at different conversions can be predicted. Comparisons show that the agreement between predictions and experimental data is satisfactory. 相似文献
13.
W. Ming F. Melis R. D. van de Grampel L. van Ravenstein M. Tian R. van der Linde 《Progress in Organic Coatings》2003,48(2-4):316-321
Self-stratification strategy can be used to prepare films in which both bulk and surface properties can be optimized. By using this approach, only a very small quantity of fluorinated species is needed to generate a surface with low surface energy. When cross-linking is involved during film formation, we are dealing with a competition behavior between the diffusion of fluorinated species and the formation of cross-linked network. In this study low surface energy polymeric films were prepared on the basis of partially fluorinated polyisocyanates, in combination with hydroxyl-end-capped three-armed solventless liquid oligoesters and modified hyperbranched polyesters. At a fluorine concentration of only 0.5 wt.%, contact angles of water and hexadecane can reach 120° and 80°, respectively. A surface energy as low as 10–15 mN/m can be obtained upon the addition of less than 1 wt.% of fluorine in the films. It was shown, from real time ATR-FTIR and contact angle measurements, that the curing temperatures demonstrated significant effects on the cross-linking rate as well as on the wettability of the films. 相似文献
14.
Novel diols containing imide groups were prepared via condensation of aromatic dianhydrides with 5‐amino‐1‐naphthol. The diimide–dinaphthols prepared were characterized by conventional methods and used to synthesize new poly(urethane–imide)s (PUIs). All the polymers were characterized and their physical properties, such as solubility, solution viscosity, thermal stability, and thermal behaviour were studied. The polymers obtained showed more thermal stability than typical polyurethanes because of the presence of the imide groups. Copyright © 2003 Society of Chemical Industry 相似文献
15.
16.
17.
18.
Heather J. Avens 《Polymer》2008,49(22):4762-4768
Surface modification by surface-mediated polymerization necessitates control of the grafted polymer film thicknesses to achieve the desired property changes. Here, a microarray format is used to assess a range of reaction conditions and formulations rapidly in regards to the film thicknesses achieved and the polymerization behavior. Monomer formulations initiated by eosin conjugates with varying concentrations of poly(ethylene glycol) diacrylate (PEGDA), N-methyldiethanolamine (MDEA), and 1-vinyl-2-pyrrolidone (VP) were evaluated. Acrylamide with MDEA or ascorbic acid as a coinitiator was also investigated. The best formulation was found to be 40 wt% acrylamide with MDEA which yielded four to eightfold thicker films (maximum polymer thickness increased from 180 nm to 1420 nm) and generated visible films from fivefold lower eosin surface densities (2.8 versus 14 eosins/μm2) compared to a corresponding PEGDA formulation. Using a microarray format to assess multiple initiator surface densities enabled facile identification of a monomer formulation that yields the desired polymer properties and polymerization behavior across the requisite range of initiator surface densities. 相似文献
19.
采用苯酚、邻苯二酚、愈创木酚和紫丁香酚为木质素单体模化物,利用两段裂解反应器-在线气相色谱仪(GCs)进行热解实验和产物分析,采用多色谱柱对无机气体(IGs)、C1~C5烃(C1~C5 LHs)、非芳基含氧化合物、酚和芳烃进行定量分析,以确定羟基和甲氧基对木质素热解过程中开环反应及产物分布的影响. 结果显示:羟基和甲氧基可以提高模化物的转化率,且羟基和甲氧基的存在影响芳基开环反应、芳基取代反应和重排反应间的竞争关系,使热解产物分布存在明显差异. 4种模化物热解产物主要是芳环的开环反应产物,包括IGs(质量分数为27.29%~33.56%)和C1~C5烃(20.46%~39.51%). 一氧化碳产率(23.82%~29.18%)随羟基数增加而升高,随甲氧基数增加而降低;二氧化碳产率(0.19%~9.61%)随甲氧基数增加而升高. 羟基和甲氧基的存在降低了C1~C5烃的质量选择性,促进了烷基苯、大分子化合物和焦炭的形成. 相似文献
20.
M.J. Tsafack 《Surface & coatings technology》2006,201(6):2599-2610
The permanent fire proofing of textiles of natural origin such as cotton is still challenging because only a surface treatment can be applied. Moreover, to be resistant to washing or harsh weather conditions the flame retardant must be fixed strongly to the surface, most efficiently achieved via covalent bonds. For that purpose, the simultaneous grafting and polymerization of fire retardant monomers on cotton fabric induced by argon plasma have been investigated with four acrylate monomers containing phosphorus, diethyl(acryloyloxyethyl)phosphate (DEAEP), diethyl-2-(methacryloyloxyethyl)phosphate (DEMEP), diethyl(acryloyloxymethyl)phosphonate (DEAMP) and dimethyl(acryloyloxymethyl)phosphonate (DMAMP), which are known to be effective for this application. We also report the synthesis and the plasma-induced graft-polymerization (PIGP) of two new phosphoramidate monomers, diethyl(acryloyloxyethyl)phosphoramidate (DEAEPN) and acryloyloxy-1,3-bis(diethylphosphoramidate)propan (BisDEAEPN) on cotton fabrics. Their flame retardant effect was compared with the previously used acrylate phosphate and phosphonate monomers. DEAEPN and BisDEAEPN exhibit the highest LOI values (28.5 and 29.5 respectively). The good flame retardant properties of these phosphoramidate monomers are attributed to the presence of nitrogen which causes a synergistic enhancement in the efficiency of phosphorus-based flame retardants. The grafting and the polymerization processes taking place on the surface of the cotton textile were followed by weighing measurements, IR (ATR) spectroscopy and SEM. The fire retardant character of the treated fabrics was investigated by thermogravimetric analyses and LOI measurements. The durability of the treatment was investigated by using the accelerated method of laundering proposed by McSherry et al. 相似文献