Influence of adsorption on the measurement of diffusion coefficients by Taylor dispersion

The effect of adsorption on the measurement of diffusion coefficients by the Taylor dispersion technique is investigated by modifying the governing equation to account for reversible, nonequilibrium adsorption. The resulting two-dimensional equations are solved by an explicit finite-difference technique. Experimental data for the acridine carbon dioxide system indicated that acridine adsorbs on the walls on the tubing and these data were investigated with this model. The influence of carious parameters including the number of sites and the rates of adsorption desorption was investigated by conducting a parametric sensitivity analysis on the model. It was found that adsorption of the solute on the wall of the tubing could produce an error as high as 35% on the measured diffusion coefficient compared to the actual diffusion coellicient. Examination of the influence of each of the parameters will enable Inure investigators to reduce the effect of adsorption in the measurement of diffusion coefficients by Taylor dispersion.     

管外上升R－113流体的沸腾换热试验

详细介绍了Ｒ－１１３流体管外上升流动的沸腾换热试验，包括试验台架、流量计和温度测量的修正，以及试验数据。拟合的换热关系式为ｑ＝５２８（Ｔｗ─Ｔｓ）１．３３。     

用基团贡献法预测纯物质蒸气压

对应状态原理与基团贡献法结合，提出一个新的蒸气压估算方程（ＲＬＹＭ）。通过对烷烃、烯烃、炔烃、环烷烃、环烯烃、醇、环醇、酮、醚、芳烃、酚、萘在内的１７４种有机物质蒸气压实验数据的关联，获得了３０种基团的贡献参数值。新模型的预测精度优于现有的对应状态法，并且对高碳分子仍有较好的估算精度。总的关联误差小于１．１７％。     

Pressure Behavior for Spherical Flow in a Reservoir of Non-Newtonian Power-Law Fluids

The pressure variations during polymer flooding of oil reservoirs for oil recovery projects can be used to analyze the flow in the reservoir which is especially useful for the partially perforated reservoirs. This paper presents a relationship between the viscosity and the shear rate which is similar to forms developed for radial flow (Odeh, A. S., Yang, H. T. ([1979]). SPEJ. AIME (Jun.) 155). The power-law viscosity model is used to give the variation of the fluid viscosity with the spherical radius for a mathematical model of unsteady spherical flow for non-Newtonian fluids with wellbore storage and skin. An analytical solution for the wellbore pressure responses derived in Laplace space is used to analyze the behavior characteristics at early and later times to interpret the well-test parameters. The pressure variations are similar to those for a Newtonian fluid at the early times, but at later times, the variation of the viscosity with the power-law exponent is important, so the pressure response differs from that for a Newtonian fluid. The solution has significance for interpreting well test parameters for non-Newtonian spherical flow.     

撞击流管式反应制备超细氧化锆粉体

我国氧化锆粉体产业目前基本上“精进粗出”，迫切需要开发氧化锆粉体备新工艺，特别是具有高附加值的纳米氧化锆粉体制备技术，液相反应沉淀法具有成本低，易于工业化等优点而成为研究的热点。本文采用撞击流管式反应新工艺，撞击流接触反应强化了过程的微观混合。实现了均匀成核，使得成核过程易于控制，而管式反应器的独特设计克服了返混，因而使得反应沉淀过程易于控制，粒子分布窄。用该工艺结合醇热处理表面改性制备的超细氧化锆粉体。平均粒径约为14nm，粒度分布窄并无硬团聚发生。该方法过程简单，易于工业化大生产。     

转子叶片在非均匀来流条件下的流体激振特性

该文通过研究得出非均匀来流对转子叶片流体激振的三个重要特征 :非均匀来流相对于转子叶片的非定常流中主频分量是产生叶片动应力的决定因素 ;非均匀来流的非均匀度 (相当于非定常流的波幅 )大小和叶片流体激振的动应力大小成正比 ;转子叶片流体的定常压力水平与叶片动应力的水平密切相关。图 4表 2     

Extraction of Singular Points from Dense Motion Fields: An Analytic Approach

In this paper we propose a new method to extract the vortices, sources, and sinks from the dense motion field preliminary estimated between two images of a fluid video. This problem is essential in meteorology for instance to identify and track depressions or convective clouds in satellite images. The knowledge of such points allows in addition a compact representation of the flow which is very useful in both experimental and theoretical fluid mechanics. The method we propose here is based on an analytic representation of the flow. This approach has the advantage of being robust, simple, fast and requires few parameters.     

大庆油田水平井分流压裂技术

水平井分流压裂的技术原理是将水平井的水平段分成若干个单元，在每个单元的最佳部位进行射孔，每段的射孔数由孔径、单元数、设计施工排量等参数决定，射孔方案为压裂方案的有机组成部分。大庆油田已有5口水平井实施分流压裂，根据油层厚度分为两类：裂缝限制在油层内和裂缝穿透隔层贯穿多个薄油层。通过肇57-平35井和肇57-平33井进行的分流压裂贯穿多个油层现场试验，介绍了大庆油田水平井分流压裂的设计方法、压裂液体系、现场施工控制方法和效果分析方法。微地震裂缝监测结果表明，在最大施工排量7．5m^3／mim条件下，一次施工形成3～4条裂缝，加砂量最大达到75m^3（陶粒），平均砂比达到35％以上。水平井采用分流压裂技术施工后，初期产能可达到相邻直井压裂后产能的2．0倍以上。如何检测裂缝是否穿透了隔层并贯穿多个油层，是指导水平井分流压裂技术的选井选层，提高压裂效果的关键技术。图8表2参2。     

GC/MS characterization of mate tea leaves extracts obtained from high-pressure CO2 extraction

This work presents a study concerning the chemical characteristics and analytical separation process of the essential oil obtained from high-pressure carbon dioxide extraction of Ilex paraguariensis. The experiments were performed in a laboratory-scale unit in the temperature range of 20–40 °C, from 100 to 250 bar. A blend of the I. paraguariensis extracts was percolated through a preparative chromatographic column, containing silica gel, and successively eluted with 150 mL of each of the following solvents: hexane, toluene, dichloromethane, ethyl acetate, acetone and methanol. The raw extract and its fractions were analyzed by gas chromatography coupled to mass spectrometry detection (GC/MS). The fractionation procedure showed to be a good clean up technique due to the isolation of different classes of compounds in each fraction. Chromatographic analyses allowed the identification of caffeine, fatty acids and esters, phytol, squalene, Vitamin E, stigmasterol derivatives and saturated hydrocarbons.     

硅化腐植酸钠GFN-1的研制

针对目前生产腐植酸硅化产品原料受限的缺点,在大量试验的基础上,确定了一条以腐植酸和硅化剂为主要原料的生产工艺,合成了一种与有机硅腐植酸钾(OSAM-K)性能相当的硅化腐植酸钠产品GFN-1,对其常规性能指标和在清水及无固相聚合物钻井液体系中、在膨润土浆和低固相钻井液体系中应用指标,耐温性能进行了对比实验。实验结果表明,GFN-1作为钻井液添加剂,具有良好的降滤失、降黏、耐温及热稳定性,并兼有优良的控制页岩分散能力,其大多数应用性能相当于或略优于OSAM-K,作为替代品完全能够满足油田现场应用的需要。GFN-1的硅化原料性质稳定、来源广泛,生产工艺简单易行,产品质量稳定,具有较好的推广价值。