Viscous behaviour of glass-forming liquids: a thermodynamic approach

The temperature dependence of the viscosity of the undercooled melts exhibits an important role in the study of nucleation, crystal growth and the glass-forming ability of materials. Several attempts have been made to study the viscous behaviour of the glass-forming melts and these investigations are mainly based on free volume theory as well as on the configurational entropy model. In the present investigation, an attempt has been made to correlate the thermodynamic parameters with the viscosity of the glass-forming melts and to study the temperature dependence of the viscosity of undercooled liquids on the basis of the free volume theory as well as on the basis of the configurational entropy model of Adam and Gibbs. The entire study is confined on the expression for thermodynamic parameters reported by the authors recently. The expression obtained has been successfully applied to study the temperature dependence of the viscosity of the metallic, molecular and oxide glass-forming liquids.     

自由电子激光光导效应数值研究

本文对喇曼型自由电子激光光导效应进行了理论研究和数值模拟。我们编写了轴对称的二维计算机程序(FELOG),用来研究无波导和有波导情况下的光导效应。对光场分布、光场半径、填充因子及等效折射率等进行了模拟。根据实验参数进行的模拟结果与实验结果进行比较,它们符合很好。并对影响光导效应的因素进行了分析。     

镀锌层上有机物无铬钝化涂层的耐蚀性

选择了一种无毒的水溶性丙烯酸树脂（AC）加入至钼酸盐、磷酸盐中（M）得到一种钝化液（ACM），对镀锌层进行钝化处理以代替有毒的铬酸盐钝化。通过盐雾试验、扫描电镜、电化学测试等手段，研究了该纯化膜的耐蚀性及耐蚀机理。结果表明，热浸镀锌层采用该无毒钝化液进行钝化，可以推迟镀锌层出现白锈的时间，其抗蚀性已接近铬酸盐钝化水平；ACM钝化膜耐蚀性的提高是由于钝化膜中的钼酸盐与丙烯酸树脂产生交联作用，抑制钝化膜裂纹的扩展，同时由于膜层中钼酸盐的缓蚀作用，提高了镀锌层的抗蚀性。     

催化氧化法合成脂肪醇醚羧酸盐的研究进展

详细介绍了氮氧自由基催化氧化法和贵金属催化氧化法合成脂肪醇醚羧酸盐。氮氧自由基催化时,反应温度20～60℃,反应时间3～6 h,得到酸型产品。贵金属催化剂中,钯的催化活性比铂高。贵金属催化时,加入铅、铋等助催化剂,并以活性炭为载体,碱性条件下于50～90℃反应2～6 h,得到盐型产品。在适当的条件下,这两种方法均可使醇醚转化率达95％,选择性达90％以上。     

碳含量对易切削非调质塑模钢组织及性能的影响

研究了碳含量与易切削非调质塑料模具钢性能间的关系。结果表明，随着碳含量的上升，钢的硬度随之而升高，韧性则先升后降，钢的切削性能渐趋恶化。     

基于Vega粒子系统的自由大气分子运动虚拟仿真

在军事训练中,三维仿真的战场环境发挥了极为重要的作用。本文将对战场环境中的自由大气进行虚拟仿真。首先分析自由大气中运动分子的性质,详细介绍在模拟不规则自然现象中运用最多的粒子系统技术,最后在Vega中运用粒子系统对大气分子的运动进行模拟仿真。仿真结果能基本模拟出大气分子的运动特性,且可以通过接口编程访问粒子的属性,从而能在无人机等航迹规划的危险天气现象的规避中加以运用。     

构建面向销售服务的运营商管理支撑系统

在电信运营行业竞争日益加剧的大环境下,市场对传统运营商运营模式的转变提出了更加具体的要求。面向销售服务的运营商管理支撑系统为市场经营"围绕客户、细分需求、有效沟通"提供了信息化解决方案。文章结合某电信运营商的具体案例,分析了现有的支撑系统,提出了销售服务管理支撑系统进一步建设的必要性、目的性、设计思路、规范原则、总体架构和技术体系,描述了系统的相关功能,归纳了其主要特点,并思考了系统实施过程中应注意的一些问题。     

Blind estimation of the PN sequence in lower SNR DS-SS signals with residual carrier

This paper presents a method of singular value decomposition (SVD) plus digital phase lock loop (DPLL) to solve the difficult problem of blind pseudo-noise (PN) sequence estimation in low signal to noise ratios (SNR) direct sequence spread spectrum (DS-SS, DS) signals with residual carrier. Of course, the method needs to know the parameters of DS signal, such as the period and code rate of PN sequence. Firstly, the received signal is sampled and divided into non-overlapping signal vectors according to a temporal window, whose duration is two periods of PN sequence. Then, an autocorrelation matrix is computed and accumulated by the signal vectors one by one. The PN sequence with residual carrier can be estimated by the principal eigenvector of this autocorrelation matrix. Furthermore, a DPLL is used to deal with the estimated PN sequence with residual carrier, it estimates and tracks the residual carrier, removes the residual carrier in the end. Theory analysis and computer simulation results show that this method can effectively realize the PN sequence estimation from the input DS signals with residual carrier in lower SNR.     

Study of viscosity of mono-, di-, and trialkylamines

Viscosities of several mono-, di-, and trialkylamines have been measured in the temperature range 298 to 333 K. It is observed that viscosities are highly dependent on shape, size, and association through H-bond or through dipole. Following the transition state theory, energy, Gibbs free energy, and entropy of activation of viscous flow have been calculated. The values of expansion energy for these liquids have also been calculated using free volume theory, and subsequently amines have been classified as volume-restrained or energy-restrained liquids. The group contribution method of Van Velzen, Cardozo, and Langenkamp for estimating viscosity has been examined with the present and literature data, and the new group contribution increments N _i and B _i for amines have been evaluated.     

无相位反馈的分布式发射波束成形技术研究

分布式发射波束成形技术是实现协作通信的一种有效方式,而分布式发射波束成形面临的主要技术挑战有发射信息共享、载波同步、发射时间同步等。本文针对这些技术挑战利用时分双工系统前后向信道的一致性,提出了一种不需要在节点之间反馈相位控制信息的分布式发射波束成形技术。在此基础上,发射节点和目标节点之间数据传输采用OFDM技术,提出了对每个子载波信号分别进行发射波束成形的实现方法。