全文获取类型
收费全文 | 29948篇 |
免费 | 2815篇 |
国内免费 | 861篇 |
专业分类
电工技术 | 368篇 |
综合类 | 1708篇 |
化学工业 | 15448篇 |
金属工艺 | 656篇 |
机械仪表 | 507篇 |
建筑科学 | 901篇 |
矿业工程 | 471篇 |
能源动力 | 439篇 |
轻工业 | 3994篇 |
水利工程 | 306篇 |
石油天然气 | 1794篇 |
武器工业 | 127篇 |
无线电 | 1058篇 |
一般工业技术 | 4136篇 |
冶金工业 | 646篇 |
原子能技术 | 247篇 |
自动化技术 | 818篇 |
出版年
2024年 | 133篇 |
2023年 | 336篇 |
2022年 | 524篇 |
2021年 | 661篇 |
2020年 | 744篇 |
2019年 | 853篇 |
2018年 | 777篇 |
2017年 | 954篇 |
2016年 | 939篇 |
2015年 | 1011篇 |
2014年 | 1453篇 |
2013年 | 1670篇 |
2012年 | 1907篇 |
2011年 | 2006篇 |
2010年 | 1574篇 |
2009年 | 1626篇 |
2008年 | 1480篇 |
2007年 | 1868篇 |
2006年 | 1955篇 |
2005年 | 1601篇 |
2004年 | 1374篇 |
2003年 | 1265篇 |
2002年 | 1086篇 |
2001年 | 982篇 |
2000年 | 825篇 |
1999年 | 782篇 |
1998年 | 585篇 |
1997年 | 505篇 |
1996年 | 371篇 |
1995年 | 320篇 |
1994年 | 309篇 |
1993年 | 262篇 |
1992年 | 210篇 |
1991年 | 145篇 |
1990年 | 98篇 |
1989年 | 101篇 |
1988年 | 63篇 |
1987年 | 33篇 |
1986年 | 24篇 |
1985年 | 44篇 |
1984年 | 43篇 |
1983年 | 35篇 |
1982年 | 39篇 |
1981年 | 3篇 |
1980年 | 9篇 |
1966年 | 5篇 |
1961年 | 4篇 |
1959年 | 3篇 |
1956年 | 2篇 |
1951年 | 11篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
121.
122.
LLDPE及其催化剂技术进展 总被引:3,自引:0,他引:3
综述了线性密度聚乙烯(LLDPE)研究的最进展情况,特别对乙烯原位聚合工艺和后过渡金属镍、钯催化剂进行了详细的叙述,对我国LLDPE的生产提出了自己的看法。 相似文献
123.
Studies on Catalytic Side-Chain Oxidation of Nitroaromatics to Aldehydes with Oxygen 总被引:2,自引:0,他引:2
The side-chain oxidation of 2-nitrotoluene in liquid phase in the presence of catalytic amount of manganese sulfate and stoichiometric amount of potassium hydroxide with oxygen was studied. In the most favorable conditions, over 80% of conversion of 2-nitrotoluene and 50% of selectivity to 2-nitrobenzaldehyde was achieved. Effects of the reaction parameters on the conversion of the reactant and the selectivity of the product were examined. These results, together with EPR spectroscopic study, show that a benzyl anion was formed in the early stage of the reaction, which was then converted to the final product via a free radical mechanism. 相似文献
124.
用 CaF_2单晶和 ZrO_2(+MgO)为固体电解质分别构成原电池:■和 Pt,B_((s)),NdBO_(3(s)),Nd(BO_2)_(3(s))|ZrO_2|Cr_2O_(3(s)),Cr_((s)),Pt联合测了 NdBO_3和 Nd(BO_2)_3的标准生成自由能:ΔG~0_(NdBO_3)=-1757+3.8×10~(-1)TΔG~0_(Nd)(BO_2)_3=-3435+8.8×10~(-1)T由此求出由氧化物生成 NdBO_3及 Nd((BO_2)_3)的反应的标准生成自由能变化:1/2Nd_2O_(3(s))+1/2B_2O_(3■)=NdBO_(3(s))ΔG~0_(NdBO_3)=-242+1.4×10~(-1)T和 1/2Nd_2O_(3(s))+3/2B_2O_(3(s))=Nd(BO_2)_(3■)ΔG~0′_(NdBO_2)3=-693+4.6×10~(-1)T 相似文献
125.
Simultaneous polymerization and doping of pyrrole have been carried out in the presence of a halogenic electron acceptor, bromine (Br2) or iodine (I2), in aqueous dispersion or in a two-phase solvent system. The morphology of the polypyrrole (PPY) so produced is granular and porous. The electrical conductivity of the PPY-I2 charge transfer (CT) complex is of the order of 101 ohm−1 cm−1 while that of the PPY-Br2 complex is about one order of magnitude less. Both complexes are stable in the atmosphere. The physicochemical properties of the PPY-I2 and PPY-Br2 CT complexes prepared under various experimental conditions are examined in detail. 相似文献
126.
新型阳离子聚丙烯酰胺微粒的研究--含PEO支链阳离子聚丙烯酰胺微粒的合成、助留性能及作用机理 总被引:6,自引:0,他引:6
本文采用反相微乳液聚合的方法合成了丙烯酰胺(AM)/丙烯酰氧基乙基三甲基氯化铵(AD-AMQUAT)/聚氧乙烯大单体(PEO-A)/N,N'-亚甲基双丙烯酰胺(Bis)的四元共聚物微粒.研究了该微粒助留剂的结构与性能.这种微粒和纸纤维能够通过离子键和氢键作用显著地增强助留效果. 相似文献
127.
Free radical emulsion polymerization of methyl methacrylate (MMA) and 2‐ethylhexyl acrylate (EHA) results in the synthesis of pressure‐sensitive adhesives (PSAs) with good tack properties. Management of both the copolymer composition and the polymerization process allows one to control the behavior of the PSA. Semicontinuous (SC) processes create polymer particles whose instantaneous composition is close to that of the feed particle The SC Mixture process (continuous feeding with comonomer blends) affords nearly homogeneous latex particles and PSA films. The SC Gradient process (separate feedings at inversely varying rates) affords heterogeneous particles and films. The Batch process leads to somewhat heterogeneous films, but the hard (MMA‐rich) microdomains are made compatible with their soft (EHA‐rich) matrix because of the assumed formation of tapered‐type copolymers. Tack measurements indicate the importance of the particle and film structures. Too much hardness or softness leads to unacceptable lacks of adhesion and cohesion, respectively. Homogeneous structures prove adequate, but their tack properties collapse with rising temperature. Heterogeneous structures, with extensive phase segregation, prove unsatisfactory because they lack adhesion and cohesion. Finally, the association of well‐balanced composition and compatible heterogeneity is the criterion for suitable PSA behavior. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2749–2756, 2003 相似文献
128.
M. Kobayashi M. Mukai H. Takahashi N. Ohno T. Kawakami T. Ishikawa 《International journal for numerical methods in engineering》2003,58(10):1523-1543
This paper describes the implicit integration and consistent tangent modulus of an inelastic constitutive model with transient and steady strain rates, both of which are time‐ and temperature‐dependent; the transient rate is influenced by the evolution of back stress decomposed into parts, while the steady rate depends only on applied stress and temperature. Such a non‐unified model is useful for high‐temperature structural analysis and is practical owing to the ease in determining material constants. The implicit integration is shown to result in two scalar‐valued coupled equations, and the consistent tangent modulus is derived in a quite versatile form by introducing a set of fourth‐rank constitutive parameters into the discretized evolution rule of back stress. The constitutive model is, then, implemented in a finite element program and applied to a lead‐free solder joint analysis. It is demonstrated that the implicit integration is very accurate if the multilinear kinematic hardening model of Ohno and Wang is employed, and that the consistent tangent modulus certainly affords quadratic convergence to the Newton–Raphson iteration in solving nodal force equilibrium equations. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
129.
乳化液浓度自动检测配比系统 总被引:4,自引:0,他引:4
本文论述了乳化液浓度自动检测配比系统。文章给出了阻容型浓度、液位传感器的原理、结构和测试电路,以及实现乳化液浓度自动检测与自动配比的系统硬件和软件。系统样机通过了型式试验、防爆和工业性试验。研究结构表明,本系统性能优良,达到了煤矿监控产品技术标准,对提高煤机械自动化程度具有重要意义,推广应用前景广阔。 相似文献
130.
丙烯酸酯与甲基丙烯酸酯的共聚及性能研究 总被引:22,自引:0,他引:22
采用悬浮聚合法,以丙烯酸-2-乙基-己酯与甲基丙烯酸十二酯为单体,合成了共聚型高吸油性树脂。研究了共聚单体的配比、交联剂用量、引发剂用量诸因素对高吸油性树脂的性能影响。制得的树脂可以吸其自身质量的11.8倍的煤油、14.7倍的苯、6.5倍的泵油。 相似文献