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71.
《International Journal of Hydrogen Energy》2022,47(70):30234-30247
The dehydrogenation temperature of LiAlH4 was significantly reduced by the production of mixtures with ZrCl4. Stoichiometric 4:1, and 5 mol % mixtures of LiAlH4 and ZrCl4 were produced by ball milling at room temperature and ?196 °C, and tested for dehydrogenation at low temperature. Cryogenic ball-milling resulted in an effective way to produce reactive mixtures for hydrogen release; because of achieving small aggregates size (5–20 μm) in 10 min of cryomilling while preventing substantial decomposition during preparation. Dehydrogenation reaction in the mixtures LiAlH4/ZrCl4 started around 31–47 °C under different heating rates. Partial dehydrogenation was proved at 70 °C: 4.4 wt % for the 5 mol% ZrCl4–LiAlH4 mixture, and 3.4 wt % for the best 4:1 stoichiometric mixture. Complete dehydrogenation up to 250 °C released 6.4 wt% and 4.1 wt%, respectively. Dehydrogenation reactions are exothermic, and the LiAlH4/ZrCl4 mixtures are unstable and difficult to handle. The activation energy of the exothermic reactions was estimated as 113.5 ± 9.8 kJ/mol and 40.6 ± 6.6 kJ/mol for 4LiAlH4+ZrCl4 and 5%mol ZrCl4+LiAlH4 samples milled in cryogenic conditions, respectively. The dehydrogenation pathway was changed in the LiAlH4/ZrCl4 mixtures as compared to pure LiAlH4. Dehydrogenation reaction is proposed to form Al, LiCl, Zr, and H2 as main products. Modification of the dehydrogenation reaction of LiAlH4 was achieved at the cost of reducing the total hydrogen release capacity. 相似文献
72.
To evaluate the performance of the ejector-expansion refrigeration cycle (EERC) using zeotropic mixtures, a numerical study is conducted. A constant-pressure two-phase ejector model for zeotropic mixtures is established. The effects of both the fluid composition and the working conditions are investigated. Mixture R134a/R143a is selected as the working and the simulation results reveal that, the cycle COP increases first and then decreases as MFt (the mass fraction of R134a) increases in the researched condition. The COP gets a maximum value of 4.18 with MFt of 0.9 and yields a minimum value of 3.66 with MFt of 0.5. With mixture 0.9/0.1, the COP improvement reaches a maximum value of 10.47%. This improvement rises at high condensing temperature or low evaporating temperature. The exergy analysis shows that the compressor and ejector contribute the most exergy destruction, and the cycle exergy efficiency achieves a maximum value with MFt of 0.7. 相似文献
73.
Pei-Chann Chang Jyun-Jie Lin Jui-Chien Hsieh Julia Weng 《Applied Soft Computing》2012,12(10):3165-3175
This study presented a new diagnosis system for myocardial infarction classification by converting multi-lead ECG data into a density model for increasing accuracy and flexibility of diseases detection. In contrast to the traditional approaches, a hybrid system with HMMs and GMMs was employed for data classification. A hybrid approach using multi-leads, i.e., lead-V1, V2, V3 and V4 for myocardial infarction were developed and HMMs were used not only to find the ECG segmentations but also to calculate the log-likelihood value which was treated as statistical feature data of each heartbeat's ECG complex. The 4-dimension feature vector extracted by HMMs was clustered by GMMs with different numbers of distribution (disease and normal data). SVMs classifier was also examined for comparison with our system in experimental result. There were total 1129 samples of heartbeats from clinical data, including 582 data with myocardial infarction and 547 normal data. The sensitivity of this diagnosis system achieved 85.71%, specificity achieved 79.82% and accuracy achieved 82.50% statistically. 相似文献
74.
CF_3I is a potential SF_6 alternative gas.In order to study the insulation properties and synergistic effects of CF_3I/N_2 and CF_3I/CO_2 gas mixtures,two-term approximate Boltzmann equations were used to obtain the ionization coefficient α,attachment coefficient η and the critical equivalent electrical field strength(E/N)_(cr).The results show that the(E/N)_(cr)of CF_3I gas at 300 K is 1.2 times that of SF_6 gas,and CF_3I/N_2 and CF_3I/CO_2 gas mixtures both have synergistic effect occurred.The synergistic effect coefficient of CF_3I/CO_2 gas mixture was higher than that of CF_3I/N_2 gas mixture.But the(E/N)_(cr)of CF_3I/N_2 is higher than that of CF_3I/CO_2 under the same conditions.When the content of CF_3I exceeds 20%,the (E/N)_(cr) of CF_3I/N_2 and CF_3I/CO_2 gas mixture increase linearly with the increasing of CF_3I gas content.The breakdown voltage of CF_3I/N_2 gas mixture is also higher than that of CF_3I/CO_2 gas mixture in slightly non-uniform electrical field under power frequency voltage,but the synergistic effect coefficients of the two gas mixtures are basically the same. 相似文献
75.
《Drug development and industrial pharmacy》2013,39(2):119-128
Ground mixtures of ketoprofen (KETO) with native crystalline β-cyclodextrin, amorphous statistically substituted methyl-β-cyclodextrin, and microcrystalline cellulose were investigated for both solid phase characterization (differential scanning calorimetry (DSC) powder X-ray diffractometry, and infrared (IR) spectrometry) and dissolution properties (dispersed amount and rotating disk methods) to evaluate the role of the carrier on the performance of the final product. The effects of different grinding conditions, partial sample dehydration, and 1 year storage at room temperature were also investigated. The results pointed out the importance of the carrier nature on the efficiency of the cogrinding process. Both cyclodextrins were much more effective than was microcrystalline cellulose, even though no true inclusion complex formation occurred by mechanochemical activation. The best results were obtained from ground mixtures with methyl-β-cyclodextrin, which showed the best amorphizing and solubilizing power toward the drug and permitted an increase of approximately 100 times its intrinsic dissolution rate constant, in comparison with the approximate 10 times increase obtained from ground mixtures with β-cyclodextrin. 相似文献
76.
《Measurement》2016
To predict fatigue life of Polyethylene Terephthalate (PET) modified asphalt mixture, various soft computing methods such as Genetic Programming (GP), Artificial Neural Network (ANN), and Fuzzy Logic-based methods have been employed. In this study, an application of Support Vector Machine Firefly Algorithm (SVM-FFA) is implemented to predict fatigue life of PET modified asphalt mixture. The inputs are PET percentages, stress levels and environmental temperatures. The performance of proposed method is validated against observed experiment data. The results of the prediction using SVM-FFA are then compared to those of applying ANN and GP approach and it is concluded that SVM-FFA leads to more accurate results when compared to observed experiment data. 相似文献
77.
宏观上假定气体放电过程中产生的正、负离子束和电子束为流体,采用二维流体动力学模型对SF6/N2混合气体正向流注电晕放电过程进行建模,利用通量校正传输法求解连续方程,通过求解耦合的泊松方程处理空间电荷畸变电场对放电的作用,仿真过程中假设带电粒子的输运参数是折算电场的函数,对比分析了平行板电极间隙、同轴电极间隙和棒-板电极间隙三种电极结构中正向流注电晕放电特性。结果表明:流注电晕的形成加强了流注头部与阳极间的场强,减弱了流注尾部与阴极的场强。只有流注头部所在位置的初始场强足够大时放电才能继续发展,否则放电转化为稳定的流注电晕放电。 相似文献
78.
This paper quantifies the influence of Al2O3 nanoparticles on the pool boiling performance of R134a/polyolester mixtures on a Turbo-BII-HP boiling surface. Nanolubricants with 10 nm diameter Al2O3 nanoparticles of various volume fractions (1.6%, 2.3%, and 5.1%) in the base polyolester lubricant were mixed with R134a at two different mass fractions (0.5% and 1%). The study showed that nanolubricants can improve R134a boiling on a reentrant cavity surface as long as the nanoparticles remain well dispersed in the lubricant and are at sufficiently large concentration. For example, three of the refrigerant/nanolubricant mixtures with the smallest nanoparticle mass fraction exhibited average enhancements over the entire heat flux range of approximately 10%. However, when the nanoparticle mass fraction was increased to a point that likely encouraged agglomeration, an average heat transfer degradation of approximately 14% resulted. An existing model was used to predict the boiling heat transfer. 相似文献
79.
80.
Micellar Properties for Propoxylated Surfactants in Water/Alcohol Solvent Mixtures and Their Antibacterial and Polyester Fabric Antistatic Performances
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Yongqiang Sun Chao Wang Wanxu Wang Xiuquan Yang Martino Di Serio Lifei Zhi 《Journal of surfactants and detergents》2016,19(3):543-552
Two propoxylated quaternary amine surfactants characterized by two and six average PO adduct numbers (PO-2 and PO-6 QA surfactants) were synthesized to investigate the micellar properties of propoxylated cationic surfactants in water/alcohol mixtures. The effect of PPO groups on micelle formation was explored using conductivity, UV–vis spectroscopy, dynamic light scattering techniques. Regular or reverse micellization occur with water or alcohol rich solvent mixtures, respectively. For intermediate composition no micellization occurs. Also the performances in antibacterial and antistatic fabrics were studied. PO-2 QA surfactant has excellent antibacterial activities against both the Gram-negative bacterium Escherichia coli and the Gram-positive bacterium Staphylococcus aureus while both surfactants have good antistatic activity over polyester fabric. 相似文献