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41.
A systematic investigation of the magnetic and transport properties of Ti doped La0.67Ca0.33MnO3 was reported. The Ti substitution for Mn ions results in a reduction in ferromagnetism and conductivity. The metal-insulator transition temperature is close to Curie temperature which decreases from 274 to 82 K as x increases from 0 to 0.17. The most important effect of Ti doping is to introduce spin clusters in the samples due to the distortion of local lattice and the inhomogeneous magnetic structure induced primarily by the random distribution of Mn ions. A maximum magnetoresistance ratio as large as 90% in 1 T at 122 K was obtained for the sample with x =0. 055, which is four times larger than that obtained for LCMO sample at 272 K. There is a remarkable field-history dependent MR in the cooling process for the doped samples while such phenomenon disappears in the warming run. The resistivity follows well the variable range hopping behavior in paramagnetic state. Both the size effect and spin dependent hopping of carriers between the spin clusters should be considered in this system. 相似文献
42.
The effects of yttrium and cerium on microstructures and properties of Nb-Si system composites were investigated by scanning electron microscopy( SEM), energy dispersive spectrum(EDS), X-ray diffraction(XRD) and high temperature oxidation experiments.It is found that the coarse primary silicide phase became finer and more homogeneous with Y and Ce addition.The results of high temperature oxidation experiments show that the oxidation rates of NbSi system composites with an appropriate amount of Y and Ce decrease compared with those of alloys without Y or Ce addition, and oxidation products mainly distribute along the phase boundaries between the Nb solid solution and silicide. 相似文献
43.
44.
钻一口通过主采盐层的水平井与已完成的直井对接,形成连通井(形如“U”字),一口井注水溶解盐/芒硝矿,另一口井采出卤水,这是盐化工业对钻井提出的要求。针对水平对接盐井井身轨迹设计、着陆段、水平段的轨迹控制和连通技术,介绍了水平段侧钻时的钻井液技术。 相似文献
45.
Y. MURAKAMI K. TAKAHASHI R. KUSUMOTO 《Fatigue & Fracture of Engineering Materials & Structures》2003,26(6):523-531
ABSTRACT The fatigue crack growth behaviour of 0.47% carbon steel was studied under mode II and III loadings. Mode II fatigue crack growth tests were carried out using specially designed double cantilever (DC) type specimens in order to measure the mode II threshold stress intensity factor range, ΔKIIth. The relationship ΔKIIth > ΔKIth caused crack branching from mode II to I after a crack reached the mode II threshold. Torsion fatigue tests on circumferentially cracked specimens were carried out to study the mechanisms of both mode III crack growth and of the formation of the factory‐roof crack surface morphology. A change in microstructure occurred at a crack tip during crack growth in both mode II and mode III shear cracks. It is presumed that the crack growth mechanisms in mode II and in mode III are essentially the same. Detailed fractographic investigation showed that factory‐roofs were formed by crack branching into mode I. Crack branching started from small semi‐elliptical cracks nucleated by shear at the tip of the original circumferential crack. 相似文献
46.
47.
In this paper, we examine, both experimentally and theoretically, the kinetics of formation and microstructure of product
phases in thin film reactions, using the Nb/Al and Ti/Al systems as our prototypes. The results of calorimetry and microscopy
studies are interpreted using simple kinetic and morphology models. In particular, the kinetic models employed here focus
on the nucleation and growth components of the phase formation process and the morphology models provide a starting point
for the classification of product grain structures.
An erratum to this article is available at . 相似文献
48.
新型超微晶软磁合金FePCCuMoSi微观结构缺陷的正电子湮没研究 总被引:1,自引:0,他引:1
用正电子湮没方法研究了新型超微晶软磁合金的微观结构缺陷,样品选用的是在不同温度下退火的Fe81P12C3Cu1Mo0.5Si2.5合金,结果表明,合金的微观结构构陷大小,密度随退火温度有规律地变化,这种现象可能与非晶的晶化过程有关。 相似文献
49.
50.
WC对Cu/WC_P复合材料性能及组织的影响 总被引:8,自引:0,他引:8
通过WC含量对WC/Cu复合材料性能的影响,确定了冷压-烧结法制备Cu/WC材料的适宜WC含量为10vol%左右。并就WC对该材料组织和再结晶行为的影响进行了有益的探讨。 相似文献