首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   292729篇
  免费   37016篇
  国内免费   30018篇
电工技术   28065篇
技术理论   16篇
综合类   21497篇
化学工业   60218篇
金属工艺   18114篇
机械仪表   17104篇
建筑科学   16683篇
矿业工程   6473篇
能源动力   9198篇
轻工业   21761篇
水利工程   4701篇
石油天然气   10901篇
武器工业   3056篇
无线电   39595篇
一般工业技术   32660篇
冶金工业   11211篇
原子能技术   4538篇
自动化技术   53972篇
  2024年   1191篇
  2023年   4612篇
  2022年   8328篇
  2021年   10498篇
  2020年   10267篇
  2019年   9203篇
  2018年   8498篇
  2017年   11191篇
  2016年   12150篇
  2015年   13642篇
  2014年   15659篇
  2013年   18518篇
  2012年   21893篇
  2011年   23734篇
  2010年   17151篇
  2009年   17413篇
  2008年   18072篇
  2007年   21014篇
  2006年   19903篇
  2005年   16993篇
  2004年   14423篇
  2003年   12068篇
  2002年   9658篇
  2001年   7860篇
  2000年   6633篇
  1999年   5506篇
  1998年   4464篇
  1997年   3628篇
  1996年   2914篇
  1995年   2435篇
  1994年   2117篇
  1993年   1551篇
  1992年   1335篇
  1991年   1028篇
  1990年   872篇
  1989年   696篇
  1988年   473篇
  1987年   298篇
  1986年   262篇
  1985年   312篇
  1984年   273篇
  1983年   177篇
  1982年   241篇
  1981年   137篇
  1980年   154篇
  1979年   34篇
  1978年   28篇
  1977年   33篇
  1975年   23篇
  1959年   32篇
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
121.
金鑫城  孙浩睿 《发电技术》2020,41(2):137-205
泛在电力物联网是物联网在电力领域的具体体现,建设泛在电力物联网是推进"三型两网"建设的关键环节,也是实现能源转型的必要手段。阐述了泛在电力物联网的定义,从供电公司角度出发,根据北京经济技术开发区实际情况,讨论了依托地区特点的泛在电力物联网实施策略和实际应用场景,分析了可能遇到的问题。得出结论:随着泛在电力物联网的深入建设,供电公司能够为电力客户提供多元化服务,提高客户满意度;地市供电公司能够依托泛在电力物联网开展更多电力相关业务;泛在电力物联网的安全性、实用性、有效性是发展面临的首要问题。  相似文献   
122.
摘要:为了研究300M超高强钢在中性盐雾环境中的腐蚀行为及腐蚀机制,采用失重法,宏观、微观腐蚀形貌分析,三维表面轮廓分析及电化学分析的研究方法,来表征腐蚀实验现象并进行分析。结果表明:300M超高强钢在中性盐雾环境中的腐蚀产物为FeOOH、Fe2O3、Fe(OH)3和Fe3O4;腐蚀速率随着腐蚀时间逐渐降低,腐蚀后期(72h)腐蚀速率降低50%;腐蚀初期以点蚀为主,点蚀坑通过横向扩展,逐渐发展为后期的均匀腐蚀,腐蚀表面形貌呈沟壑状;外腐蚀层对基体的保护能力很弱,Cr元素在锈层靠近基体的一侧偏聚使内腐蚀层具有一定的抗腐蚀性。  相似文献   
123.
Orthorhombic molybdenum trioxide (MoO3) is one of the most promising anode materials for sodium‐ion batteries because of its rich chemistry associated with multiple valence states and intriguing layered structure. However, MoO3 still suffers from the low rate capability and poor cycle induced by pulverization during de/sodiation. An ingenious two‐step synthesis strategy to fine tune the layer structure of MoO3 targeting stable and fast sodium ionic diffusion channels is reported here. By integrating partially reduction and organic molecule intercalation methodologies, the interlayer spacing of MoO3 is remarkably enlarged to 10.40 Å and the layer structural integration are reinforced by dimercapto groups of bismuththiol molecules. Comprehensive characterizations and density functional theory calculations prove that the intercalated bismuththiol (DMcT) molecules substantially enhanced electronic conductivity and effectively shield the electrostatic interaction between Na+ and the MoO3 host by conjugated double bond, resulting in improved Na+ insertion/extraction kinetics. Benefiting from these features, the newly devised layered MoO3 electrode achieves excellent long‐term cycling stability and outstanding rate performance. These achievements are of vital significance for the preparation of sodium‐ion battery anode materials with high‐rate capability and long cycling life using intercalation chemistry.  相似文献   
124.
The lack of consensus on the meaning of energy security and how it should be measured hinders the evaluation of alternatives for improving the Cape Verdean energy sector. The objective of the paper is to develop an energy security index adjusted to the country's context. The methods used are the multi-criteria analysis and the Delphi survey. Different alternatives to improve energy security are assessed: electrically interconnect Cape Verde's islands, increase the share of renewable energy, and a combination of the previous alternatives. The results of our analysis indicate that increasing renewable energy is the optimal alternative for Cape Verde.  相似文献   
125.
The grouping of pixels based on some similarity criteria is called image segmentation. In this paper the problem of color image segmentation is considered as a clustering problem and a fixed length genetic algorithm (GA) is used to handle it. The effectiveness of GA depends on the objective function (fitness function) and the initialization of the population. A new objective function is proposed to evaluate the quality of the segmentation and the fitness of a chromosome. In fixed length genetic algorithm the chromosomes have same length, which is normally set by the user. Here, a self organizing map (SOM) is used to determine the number of segments in order to set the length of a chromosome automatically. An opposition based strategy is adopted for the initialization of the population in order to diversify the search process. In some cases the proposed method makes the small regions of an image as separate segments, which leads to noisy segmentation. A simple ad hoc mechanism is devised to refine the noisy segmentation. The qualitative and quantitative results show that the proposed method performs better than the state-of-the-art methods.  相似文献   
126.
127.
High‐performance adhesives require mechanical properties tuned to demands of the surroundings. A mismatch in stiffness between substrate and adhesive leads to stress concentrations and fracture when the bonding is subjected to mechanical load. Balancing material strength versus ductility, as well as considering the relationship between adhesive modulus and substrate modulus, creates stronger joints. However, a detailed understanding of how these properties interplay is lacking. Here, a biomimetic terpolymer is altered systematically to identify regions of optimal bonding. Mechanical properties of these terpolymers are tailored by controlling the amount of a methyl methacrylate stiff monomer versus a similar monomer containing flexible poly(ethylene glycol) chains. Dopamine methacrylamide, the cross‐linking monomer, is a catechol moiety analogous to 3,4‐dihydroxyphenylalanine, a key component in the adhesive proteins of marine mussels. Bulk adhesion of this family of terpolymers is tested on metal and plastic substrates. Incorporating higher amounts of poly(ethylene glycol) into the terpolymer introduces flexibility and ductility. By taking a systematic approach to polymer design, the region in which material strength and ductility are balanced in relation to the substrate modulus is found, thereby yielding the most robust joints.  相似文献   
128.
This study presents a design criterion developed for fatigue strengthening of a 120-year-old metallic railway bridge in Switzerland and presents a pre-stressed un-bonded reinforcement (PUR) system developed to apply the strengthening. The PUR system uses carbon fiber reinforced polymer (CFRP) plates; however, unlike conventional pre-stressed CFRP reinforcement methods, preparation of the existing metallic bridge surface is not required. This decreases the time required for on-site strengthening procedures. The principle of the constant life diagram (CLD) and two fatigue failure criteria (Johnson and Goodman) are described. Analytical formulations are developed based on the CLD method to determine the minimum CFRP pre-stress level required to prevent fatigue crack initiation. The PUR system uses an applied pre-stress force to reduce the mean stress level (and stress ratio) to shift an existing fatigue-susceptible metallic detail from the ‘at risk’ finite life regime to the ‘safe’ infinite life regime. The applied CLD method is particularly valuable when the stress history of the detail is not known and it is difficult to assess the remaining fatigue life. Moreover, it is shown that the currently adopted approach in many structural codes which emphasizes stress range as the dominant parameter influencing fatigue life are non-conservative for tension–tension stress patterns (i.e., stress ratios of 0 < R < 1). Analyses show that the modified Johnson formula accurately reflects the combined effect of stress range, mean stress level, and material properties, and offers a relatively easy design procedure. Details of a retrofit field application on members of a riveted wrought iron railway bridge are given. A wireless sensor network (WSN) system is used for long-term monitoring of the on-site CFRP stress levels and temperature of the retrofitted details. WSN measurements indicate that increases in ambient temperature result in increased CFRP pre-stress levels.  相似文献   
129.
A series of novel aliphatic poly(β‐thioether ester)s with various methylene group contents were prepared by direct lipase‐catalyzed polycondensation of the monomer with an acid‐labile β‐thiopropionate group. The polycondensation reaction using immobilized lipase B from Candida antarctica was carried out in diphenyl ether at 90 °C. Poly(β‐thioether ester)s with high molecular weights of 20 500–57 000 Da and narrow polydispersities in the range 1.40–1.48 were obtained. Thermogravimetric analysis, differential scanning calorimetry and wide‐angle X‐ray diffraction were used to investigate the thermal properties and crystal structures of these polyesters. All the poly(β‐thioether ester)s were semicrystalline polymers and thermally stable up to at least 200 °C. In vitro degradation studies showed that they can rapidly degrade under acidic conditions by the hydrolysis of the β‐thiopropionate groups, suggesting their potential as acid‐degradable polymeric materials. © 2019 Society of Chemical Industry  相似文献   
130.
Polyethersulphone (PES) is an aromatic thermoplastic, at low environmental impact, evaluated in this work as a promising candidate for new polymer electrolytes in the PEMFCs technology. A sulfonation procedure has been tuned in order to graft sulfonic acid groups on the polymer chains (sPES) and to make it hydrophilic. Homogeneous membranes with different polymer's sulfonation degrees (SD%) have demonstrated excellent mechanical properties and very low permeability toward methanol (important in the DMFCs), even if low proton conductivity. Nanocomposite sPES membranes were prepared by dispersion of highly hydrophilic lamellar particles such as layered double hydroxide (LDH) in the polymer. Deep investigations performed by a combination of PFG-NMR, EIS, XRD, DMA, and scanning electron microscopy have evidenced the exfoliation of the lamellae in polymer matrix. However, a certain anisotropy was evidenced both in the morphology and molecular diffusion, favored in the longitudinal direction (parallel to surface), while completely inhibited in the cross-section. This finding is most likely induced by the polymer structure, therefore particular attention must be paid to the choice of the filler and preparation of the composites. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019 , 136, 47884.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号