钽平台-石墨炉原子吸收法测定高背景废水样品中的Cd、Pb

运用钽平台石墨管测定基体成分复杂的废水样品中的Cd、Pb元素,基本消除了基体残留影响和记忆效应,降低了背景吸收,提高了灵敏度。样品经超声波仪粉碎后直接进样,用校正曲线法测定,简化了操作步骤,减少了测定时间,延长了石墨管使用寿命。其测定值与石墨平台标准加入法测定值结果一致。样品回收率:Cd为96.9%～104%,Pb为98.2%～106%,Cd的相对标准偏差(RSD)为3.04%～4.24%,Pb的RSD为2.93%～6.53%。     

Mechanical and morphological properties of carbon fiber reinforced–modified epoxy composites

Epoxy, prepared through aminomethyl 3,5,5‐trimethylcyclohexylamine hardening of diglycidylether of bisphenol‐A (DGEBA) prepolymer, toughened with polycarbonate (PC) in different proportions, and reinforced with carbon fiber, was investigated by differential scanning calorimetry, tensile and interlaminar shear strength testing, and scanning electron microscopy (SEM). A single glass transition temperature was found in all compositions of the epoxy/PC blend system. The tensile properties of the blend were found to be better than that of the pure epoxy matrix. They increased with PC content up to 10%, beyond which they decreased. The influence of carbon fiber orientation on the mechanical properties of the composites was studied, where the fiber content was kept constant at 68 wt %. Composites with 45° fiber orientation were found to have very weak mechanical properties, and the mechanical properties of the blend matrix composites were found to be better than those of the pure epoxy matrix composites. The fracture and surface morphologies of the composite samples were characterized by SEM. Good bonding was observed between the fiber and matrix for the blend matrix composites. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 3529–3536, 2006     

辐照改性聚丙烯拉伸流变行为及其挤出发泡的研究

通过在线形聚丙烯中加入双官能团丙烯酸酯类单体,经小剂量γ射线高能辐照,制备了高熔体强度聚丙烯,研究了其拉伸流变行为及其在挤出发泡方面的应用。Rheotens拉伸流变测试表明,辐照改性后由于形成了长支化分子结构,聚丙烯的熔体强度、拉伸黏度显著提高,具有明显的应变硬化特征。实验表明,ZnO可明显降低AC发泡剂分解温度,缓和分解放热;在辐照改性制备的高熔体强度聚丙烯中加入AC／ZnO复合发泡剂,可挤出发泡得到泡孔尺寸较为均一、分布均匀、具有闭孔结构的发泡材料。     

PE 井口高压滤芯的研究与开发

本文介绍了一种新型的能在较高压力环境下进行细过滤的ＰＥ井口高压滤芯的结构特征、关键技术研究、技术特性，以及应用效果。     

The effect of waste oil-cracking catalyst on the compressive strength of cement pastes and mortars

Epcat, one of the spent fluid catalytic cracking (FCC) catalysts from oil-cracking refineries, shows pozzolanic activity. In this study, pastes and mortars with Epcat were prepared and cured, and their compressive strengths after 3, 7 and 28 curing days were measured. The water/binder (W/B) ratios were 0.2, 0.25 and 0.3, and the replacement levels of cement by Epcat were 0, 5, 10 and 15 wt.%. Proper amount of superplasticizer was added into each mix to ensure similar workability.The results indicate that the presence of Epcat would increase the compressive strength of mortars substantially, but increase the compressive strength of the related pastes only slightly. Epcat mortars with W/B=0.25 show more strength-enhancing effect than those with W/B=0.3, and this effect increases with the catalyst content. Therefore, the mix (W/B=0.25) incorporated 15% Epcat exhibits the greatest compressive strength (92.3 MPa). For mortars with W/B=0.2, the strength-enhancing effect occurs only for those containing 5% catalyst; this effect becomes unclear when mixes containing 10% Epcat or more because high dosage of superplasticizer was added in obtaining proper workability and that affects the strength development. The improvement in the mechanical properties of mortars is attributed to the increase in the hydrated cement paste itself and, more importantly, improved bonds between the cement paste and aggregate.     

SPE-快速分离柱HPLC法测定枸杞样品中的类胡萝卜素

研究了固相萃取(SPE)富集和预分离,快速分离柱高效液相色谱(HPLC)快速测定枸杞样品中类胡萝卜素的新方法;枸杞样品中的类胡萝卜素用W aters Sep-Pak C18固相萃取小柱预分离,然后以ZORBAX Stab leBound(4.6 mm×50 mm,1.8μm)快速分离柱为固定相,甲醇-四氢呋喃为流动相分离,V(甲醇)∶V(四氢呋喃)=80∶20,用二极管矩阵检测器检测,检测波长为450 nm,枸杞样品中的几种类胡萝卜素在5 m in内可达到基线分离,比常规方法节约时间75%左右。方法标准回收率为95%~103%,RSD为1.9%~2.6%。     

一种新的MANET节点—链路稳定度模糊评估模型

利用模糊数学思想,针对MANET提出了一种稳定性评估模型,即节点—链路模糊稳定度模型。该模型通过对位置临界点和速度进行综合模糊建模,用模糊值精确衡量MANET中节点与链路的稳定性高低。理论和模拟分析证明了该模型能更有效地对MANET的稳定性和生存能力进行定量评估。在该模型下,MANET中节点与链路在大尺度时间区间内的稳定性要高于小尺度时间区间内的稳定性。     

基于GPU的快速色阶映射算子实现

为了提高色阶映射计算的效率,设计了基于GPU的快速色阶映射算法.首先结合基本规约算法和GPU的并行运算特征设计了基于两个核函数的最大亮度计算方法,然后通过区域中间值共享计算以像素为中心的区域平均亮度,最后针对视屏处理,提出利用纹理缓存池解决CPU读数据和GPU处理数据速度不匹配的问题,并根据像素子集最大亮度自适应地更新全局最大亮度.实验结果相对相同算法的CPU实现得到了4～5倍的速度提升,表明所提出的算法能够充分利用GPU的并行性,并减少了大量重复运算,满足实时渲染的要求,并且对不同规模的纹理具有良好的适应性.     

用CS－1高效催化剂生产聚丙烯树脂的纺丝试验

研究了用ＣＳ－１高效催化剂生产聚丙烯树脂的纺丝性能，得出采用该催化剂并结合分子量调节剂可以得到熔融指数较大，分子量分布较窄的聚丙烯树脂，其纺丝及力学性能都比较好。     

高速切削技术中刀具的选择与应用

21世纪初，高速切削技术在全球得到普遍应用，正成为切削加工的主流技术，加工中心将数控铣床、数控车床、数控钻床的功能集于一身，具有多种工艺手段，综合加工能力强，工件一次装夹能完成较多的加工内容，如：箱体、复杂曲面、异形工件和盘、套、板类件等。在选择刀具时，必须综合考虑机床的类型工件材料、加工精度以及工艺方案等众多因素，选择合适的加工刀具，达到加工的效果。