台塑公司高密度聚乙烯专用树脂的开发策略

介绍了台湾塑胶工业股份有限公司高密度聚乙烯(HDPE)树脂的生产装置、工艺技术、生产能力、树脂牌号及新产品开发现状,同时阐述了HDPE专用树脂的开发策略。目前,台塑公司HDPE商品牌号台塑烯的产品包括薄膜专用树脂、中空吹塑专用树脂、挤出专用树脂和注塑等用树脂等,并且产品具有单峰、双峰甚至宽峰相对分子质量分布的特性。2006年,台塑公司将调整台塑烯专用树脂的生产比例,强化产品结构而维持一定的营利水平。     

气相色谱中保留指数随温度变化规律的研究

根据保留指数随温度变化的关系式得出保留指数随温度变化的三种规律,运用气相色谱实验获得了较好的验证;并从色谱热力学函数分析了保留指数随温度变化规律的主要原因是由于在色谱分离过程中不同的熵变和焓变所造成的。     

Quantification of response time in poly(vinyl alcohol)–metal complex thermochromic polymeric systems

Thermochromic poly(vinyl alcohol) (PVA)‐based material was synthesized and an extensive study of its thermochromic behavior with respect to response time was carried out. It was observed that it is possible to manipulate the response time by keeping control over chemical and physical parameters. The response time, which is the most important property of a smart material, has in this case been found to be very much influenced by rate of heat transfer into the material. Different compositions of the thermochromic material and their corresponding response time with respect to rate of heat transfer were studied and correlated. First, a theoretical equation was derived and later on it was experimentally verified to quantify the response time in PVA–metal complex‐based thermochromic systems. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 100: 4832–4834, 2006     

哈氏合金设备的设计与施工

介绍哈氏合金的类型及耐腐蚀性能,从设计、成型、焊接和机械加工等方 面提出了制造哈氏合金设备的有关注意事项。     

铝矾土陶瓷材料的试制

利用丰富的铝矾土原料在1350℃的烧成温度下试制出一种热稳定性极好的陶瓷材料。     

Analysis of the Thermal Explosion in Systems Porous Reagent–Active Gas–Solid Product

The specific features of dynamics of the thermal explosion in systems porous reagent–active gas–solid product under conditions where the heattransfer and masstransfer regions are separated from the ambient medium are considered. In addition to the competition of heat release and heat removal, the process of initiation of exothermal chemical interaction in these systems under normal pressures depends significantly on conditions of filtration transport of the gaseous reagent. The induction and postinduction periods of the thermal explosion are studied. The theoretical analysis of thermalexplosion issues is supplemented by an experimental study of the process for the porous titanium–nitrogen–titanium nitride system.     

Preparation and characterization of new photoactive polyamides containing 4‐(4‐dimethylaminophenyl)urazole units

4‐(4‐dimethylaminophenyl)‐1,2,4‐triazolidine‐3,5‐dione ( DAPTD ) was prepared from 4‐dimethylaminobenzoic acid in five steps. The compound DAPTD was reacted with excess acetyl chloride in N,N‐dimethylacetamide (DMAc) solution and gave 1,2‐bisacetyl‐4‐[4‐(dimethylaminophenyl)]‐1,2,4‐triazolidine‐3,5‐dione as a model compound. Solution polycondensation reactions of monomer with succinyl chloride (SucC), suberoyl chloride (SubC), and sebacoyl chloride (SebC) were performed under conventional solution polymerization techniques in the presence of triethylamine and pyridine as a catalyst in N‐methylpyrrolidone (NMP) and led to the formation of novel aliphatic polyamides. These novel polyamides have inherent viscosities in the range of 0.09–0.21 dL/g in N,N‐dimethylformamide (DMF) at 25°C. Fluorimetric studies of the model compound as well as polymers were performed. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 947–954, 2007     

IFR-2000阻燃聚丙烯热性能研究

研究了用无卤膨胀型阻燃剂IFR-2000作阻燃剂的阻燃聚丙烯的热性能和阻燃性能。     

工业循环冷却水成套节水新技术在天津石化乙烯厂的应用

为解决天津地区水资源短缺的现状，通过应用先进的水处理药剂及自动监控技术，在天津石化公司乙烯厂成功地建成了高浓缩倍率冷却水处理技术示范工程，系统浓缩倍率从3倍提高到5倍以上，年节水量超过60万t。     

甲基偶氮四唑热稳定性和热分解机理的量子化学研究

采用量子化学方法全优化计算了1—甲基—5—偶氮四唑(1—MAT)和2—甲基—5—偶氮四唑(2—MAT)热分解反应位能曲线，探讨了热稳定性和分解机理。热分解活化能计算值分别为245．9，183．2k／mo1，静态分子结构和动态分解性质都显示出1—MAT比2—MAT有更好的热稳定性。裂解优先以开环方式发生。