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991.
The primary and secondary particle sizes of monoclinic hydrous-ZrO2 particles produced by the hydrolysis of various ZrOCl2 solutions, with and without the addition of NaCl, CaCl2 , or AlCl3 , were measured using X-ray diffraction and transmission electron microscopy in order to clarify the formation mechanisms of primary and secondary particles. The primary particle size of hydrous ZrO2 , under a constant ZrOCl2 concentration, decreased monotonously with increasing Cl− -ion concentration. On the contrary, the secondary particle size increased monotonously with increasing Cl− -ion concentration. The present experimental results revealed that the primary and secondary particle sizes of hydrous ZrO2 are controlled primarily by the concentrations of H+ and Cl− ions produced during hydrolysis, and are independent of the type of added metal ions. The formation mechanisms of the primary and secondary particles of hydrous ZrO2 were determined on the basis of the present experimental results. 相似文献
992.
993.
介绍了一种在常压、无外加相转移催化剂的条件下制备琥珀酸二异辛酯磺酸钠的新方法。研究了合成标题产物中磺化反应的主要影响因素 ,并得出该反应的优惠工艺条件 相似文献
994.
α、β-二氢突厥酮是保加利亚玫瑰油的主要香气物质,云南省化工研究院以环柠檬醛为起始原料,采用新型催化剂得到了这两种二氢突厥酮产品。经专家鉴定,该技术在国内处于领先水平。该文对其中的假性二氢突厥醇的制备条件进行了详细的讨论,并简述了二氢突厥酮产品的精制方法。 相似文献
995.
The activation and dehydrogenation of CH2 on Mo2C and MO2C/ZSM-5 have been investigated under non-oxidizing conditions. Unsupported Mo2C exhibited very little activity towards methane decomposition at 973 K. The main reaction pathway was the decomposition of methane to give hydrogen and carbon with a trace amount of ethane. Mixing Mo2C with ZSM-5 support somewhat enhanced its catalytic activity, but did not change the products of the reaction. A dramatic change in the product formation occurred on partially oxidized Mo2C/ZSM-5 catalyst; besides some hydrocarbons benzene was produced with a selectivity of 70–80% at a conversion of 5–7%. Carburization of highly dispersed MoO3 on ZSM-5 also led to a very active catalyst: the conversion of methane at the steady state was 5–6% and the selectivity of benzene formation was 85%.This laboratory is a part of the Center for Catalysis, Surface and Material Science at the University of Szeged. 相似文献
996.
有机相中壳聚糖-海藻酸固定化脂酶的特性 总被引:8,自引:0,他引:8
研究了壳聚糖 海藻酸固定化脂酶在有机相反应中的稳定性与活性。考察了凝胶时间、壳聚糖浓度及壳聚糖分子质量对固定化脂酶包埋率与活性的影响 ,确定了适宜 pH值与批反应时间。同时讨论了溶剂极性和操作时间对固定化酶稳定性的影响。测定了固定化脂酶水解橄榄油反应的动力学参数。结果表明 ,壳聚糖 海藻酸聚电解质膜可提高固定化酶的包埋率与稳定性 相似文献
997.
N-苯基马来酰亚胺的应用与合成 总被引:11,自引:0,他引:11
叙述了N -苯基马来酰亚胺的用途及合成方法。通过分析ABS及PVC的市场前景 ,提出了在国内开发N -苯基马来酰亚胺的必要性和紧迫性。 相似文献
998.
Dongsen Mao Guanzhong Lu Qingling Chen Zaiku Xie Yuxian Zhang 《Catalysis Letters》2001,77(1-3):119-124
A series of boria catalysts supported on titania–zirconia mixed oxide (B2O3/TiO2–ZrO2) with different boria loadings (8–20 wt%) were prepared and characterized by X-ray diffraction, adsorption of nitrogen, 11B magic angle spinning (MAS) NMR measurements and temperature-programmed desorption (TPD) of ammonia. The catalytic performance of B2O3/TiO2–ZrO2 for vapor-phase Beckmann rearrangement of cyclohexanone oxime to -caprolactam was studied at 300°C. It was found that the lactam selectivity increased with increasing of boria loading, whereas a maximum oxime conversion was obtained at the boria loading of 12 wt%. The acid sites of medium strength on the surface of the catalyst play an important role in the selective formation of lactam. 相似文献
999.
Bo-Hyuk Jang Tae-Hun Yeon Hyun-Sik Han Yong-Ki Park Jae-Eui Yie 《Catalysis Letters》2001,77(1-3):21-28
Barium-containing NO
x
storage catalyst showed serious deactivation under thermal exposure at high temperatures. To elucidate the thermal deterioration of the NO
x
storage catalyst, four types of model catalyst, Pt/Al2O3, Ba/Al2O3, Pt–Ba/Al2O3, and a physical mixture of Pt/Al2O3 + Ba/Al2O3 were prepared and their physicochemical properties such as BET, NO TPD, TGA/DSC, XRD, and XPS were evaluated while the thermal aging temperature was increased from 550 to 1050°C. The fresh Pt–Ba/Al2O3 showed a sorption capacity of 3.35 wt%/g-cat. but the aged one revealed a reduced capacity of 2.28 wt%/g-cat. corresponding to 68% of the fresh one. It was found that this reduced sorption capacity was directly related to the deterioration of the NO
x
storage catalyst by thermal aging. The Ba on Ba/Al2O3 and Pt–Ba/Al2O3 catalysts began to interact with alumina to form Ba–Al solid alloy above 600°C and then transformed into stable BaAl2O4 having a spinel structure. However, no phase transition was observed in the Pt/Al2O3 catalyst having no barium component, even after aging at 1050°C. 相似文献
1000.
两种工艺制备聚醚多元醇ZS-4110Ⅱ的比较 总被引:1,自引:0,他引:1
通过对在两种不同催化合成工艺条件下生产聚醚ZS-4110Ⅱ的研究,比较了该产品在成本、收集、质量指标及应用性能等方面的差异。二甲胺催化生产的聚醚ZS-4110ⅡA在生产效率、制造成本等方面有明显的优势,而氢氧化钾催化生产的聚醚ZS-4110ⅡK在产品的内在质量以及应用性能方面要优于胺工艺聚醚。 相似文献