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991.
992.
采用外加恒电位下腐蚀电流-温度扫描方法研究了在0.5%Cl^-溶液中,SO4^2-浓度对316不锈钢点腐蚀行为的影响.结果表明,随着SO4^2-浓度的增加,钝化电流增加,开路电位降低.当SO4^2-浓度低于0.42%时,316不锈钢的临界点蚀温度比不存在SO4^2-时的临界点蚀温度低;当SO4^2-浓度大于0.42%时,临界点蚀温度比不存在SO4^2-时的临界点蚀温度高.从离子竞争吸附的角度进行分析,对SO4^2-加速与抑制点蚀两种作用规律的形成原因进行了解释. 相似文献
993.
994.
995.
根据煤气管道在线智能切割装置控制系统的需要,采用了PC机与多台MCS-51系列单片机之间通信的硬件实现方法,本文介绍了利用单片机实现多机通信的工作原理及过程,阐明了在Visual C++编程环境中利用MSCOMM控件实现通信的软件设计方法。 相似文献
996.
高密度锂离子电池正极复合材料LiFePO4/C 总被引:2,自引:1,他引:2
以FeC2O4-2H2O、NH4H2PO4、Li2CO3和乙炔黑为原料,采用两步固相反应法制备了高密度LiFePO4/C正极复合材料.利用差热(DSC),热重(TGA)和X射线衍射(XRD)等分析手段具体探讨了第一步固相反应中可能存在的反应过程和中间产物.利用扫描电镜表征了复合材料LiFePO4/C中LiFePO4微粒形貌和接触状态.结果表明,乙炔黑的含量是影响LiFePO4微粒尺寸和微粒间接触界面的重要因素.在一次热处理的基础上,二次球磨和烧结有利于第二次固相反应过程中反应物质的接触和传质,较一步固相法提高了生成的LiFePO4的振实密度.当乙炔黑的含量(质量分数)为0.1%~1.5%时,两步固相法所制正极材料LiFePO4/C的振实密度可达到1.7 g/cm3,初次放电容量达到105 mA.h/g. 相似文献
997.
论述了可移动防腐保温生产线的特点及实际应用情况,对预制企业由工厂化生产转向现场预制具有一定的指导意义。 相似文献
998.
采用一种新型的嵌入式Web模块,开发了一种新型的故障诊断系统,该系统集成传统故障诊断方法中的数据传输、故障逻辑编写及Web发布等功能,可以方便地实现对汽轮机电液控制系统故障信息的提取、诊断及远程发布. 相似文献
999.
The corrosion behavior of 28Cr-7Ni-O-0.34N duplex stainless steels in air-saturated 3.5-wt% NaCl solution at pH 2, 7, 10 and 27 °C was studied by the potentiodynamic method. Two types of microstructures were investigated: the as-forged duplex and microduplex (average austenite grain size 5-16 μm) structures. The austenite volume fractions of the tested steels were between 0.35 and 0.64. The nitrogen effect on corrosion behaviors of both duplex and microduplex stainless steels were the same. At pH 2, the corrosion potential increased when the nitrogen content increased, however, corrosion current density as well as corrosion rate decreased. At pH 7 and 10, the effect of nitrogen on corrosion potential and corrosion rate could not be observed. Corrosion potential at pH 10 was lower than at pH 7. Pitting potential increased when the nitrogen content in the tested steels increased at all tested pH. For the nitrogen effect on the passive current density, it seemed that only at pH 2, the average passive current densities reduced when the nitrogen content increased. Nitrogen may have participated in the passive film or has been involved in the reaction to build up passive film. The ammonium formation and nitrogen enrichment at the interface metal/passive film with adsorption mechanism were discussed. The dissolute nitrogen might have combined with the hydrogen ions in solution to form ammonium ions, resulting in increasing solution pH. The steel could then easily repassivate, hence the corrosion potential and pitting potential would increase. However, the ammonium formation mechanism could not explain the decrease of corrosion potential in basic solution. Nitrogen enrichment at the metal/passive film interface with adsorption mechanism seemed to be an applicable consideration in increasing pitting potential. However, this mechanism did not involve the ammonium ion formation. In general, for the duplex and microduplex stainless steels tested, nitrogen increased the general corrosion resistances in acid solution and pitting corrosion resistance at all solution pH. Metallographic observation in both tested duplex and microduplex steels after pitting corrosion at all tested pH revealed that, the corroded structure in the tested steels without nitrogen alloying was austenite, but those with nitrogen alloying was ferrite. Even though ferrite had a higher chromium content than austenite but higher dissolved nitrogen in austenite than in ferrite may have increased the pitting resistance equivalent number (PRE) of austenite to be higher than that of ferrite. 相似文献
1000.
Plasma surface nitriding of 17-4 PH martensitic precipitation hardening stainless steels was conducted at 350 °C, 420 °C and 500 °C for 10 h using a DC plasma nitriding unit, and the surface properties of the plasma surface engineered samples were systematically evaluated. Experimental results have shown that the surface properties of the plasma nitrided layers in terms of hardness, wear resistance, corrosion behaviour and corrosion-wear resistance are highly process condition dependent, and it is feasible to provide considerable improvement in wear, corrosion and corrosion-wear resistance of 17-4PH steel using optimised plasma treatment conditions. All three treatments can effectively improve the surface hardness and the sliding wear resistance under unlubricated conditions; high temperature (420 °C and 500 °C) treated materials revealed improved corrosion and corrosion-wear properties due to the formation of surface compound layers. 相似文献