TEM Studies of High Temperature Corrosion Behaviour of TiAl Intermetallics with Surface Modifications

The oxidation/sulphidation behaviour of a Ti‐46.7Al‐1.9W‐0.5Si alloy with a TiAl₃ diffusion coating was studied in an environment of H₂/H₂S/H₂O at 850^oC. The kinetic results demonstrate that the TiAl₃ coating significantly increased the high temperature corrosion resistance of Ti‐46.7Al‐1.9W‐0.5Si. The SEM, EDX, XRD and TEM analysis reveals that the formation of an Al₂O₃ scale on the surface of the TiAl₃‐coated sample was responsible for the enhancement of the corroison resistance. The Ti‐46.7Al‐1.9W‐0.5Si alloy was also modified by Nb ion implantation. The Nb ion implanted and as received sampels were subjected to cyclic oxidation in an open air at 800^oC. The Nb ion implantation not only increased the oxidation resistance but also substantially improved the adhesion of scale to the substrate.     

时频域自动识别与压制高频噪声

本文在分析张宇等及钱忠平等提出的高频噪声判别准则基础上,利用夏洪瑞等根据在窄档等频距小波分频之后识别、压制高频噪声的思路,提出在时频域将代表地震道主要能量的几个频带的平均振幅绝对值作为正常子波的平均振幅绝对值,以此来识别和压制高频噪声的异常振幅。实际处理结果表明,此法不仅可以压制高频谐振及高频突发噪声,而且可以保护弱地震反射信号不受损害。     

应用时频分析方法辨识时变系统的模态参数

应用Gabor展开及Hilbert变换进行时变线性系统模态参数的辨识。利用非平稳信号的Gabor变换将结构响应信号表示在时频面上，并通过Gabor展开重构分离模态分量，建立每一阶模态的时变线性模型。对单模态时变线性模型应用Hilbert变换来辨识随时间变化的模态频率和阻尼。通过对刚度和阻尼慢变的两自由度系统模态参数的仿真辨识验证辨识方法的有效性。仿真结果表明：本文方法为时变线性系统的模态参数辨识提供了一条新的途径。     

Acquisition and pattern recognition of spectrum information of welding metal transfer

With the creation of a pattern recognition system for metal transfer mode, this article has collected five kinds of spectrum signals in gas metal arc welding (MIG, MAG and CO₂) and take them as training samples. These samples have been pretreated by computer, several key characteristic parameters of the spectrum signal have been creatively extracted, and a corresponding recognition function and a minimum-distance-classifier have been constructed. The results show that the pattern recognition of several kinds of metal transfer modes for the metal gas arc welding can be done successfully, and relative important parameters in welding process, such as the frequency of droplet transfer and the approximate diameter of each droplet, can also be obtained.     

锂离子电池用聚合物电解质的最新进展II.含液聚合物电解质

由于干态聚合物电解质目前还不能满足聚合物锂离子电池的应用要求,人们致力于开发含液体增塑剂的聚合物电解质,包括凝胶型和微孔型两类体系。本文综述了含液聚合物电解质的最新进展,重点论述了各种新体系和新方法。     

Electro-organic synthesis without supporting electrolyte: Possibilities of solid polymer electrolyte technology

The application of ion exchange membranes as solid polymer electrolytes (SPE) in fuel cells is state-of-the-art. This technology needs no supporting electrolyte; consequently it can be applied for electro-organic syntheses in order to save process steps. In this case the process is not predetermined to a maximized energy efficiency so that the selection of the cell design, of the electrode materials and of the operating conditions can be focused on a high selectivity of the electrode reactions. The electro-osmotic stream, which is caused by the solvation shells of the ions during their migration through the membrane, and hence is a typical property of SPE technology, has a significant effect on the electrode reactions. It generates enhanced mass transfer at the electrodes, which is beneficial for reaction selectivity. It can be influenced by the choice of, and possibly by the preparation of, the membrane. An additional remarkable advantage of SPE technology is the exceptional long durability of oxide coated electrodes. By combination of several process engineering methods stable operation of SPE cells has been realized, even for examples of non-aqueous reaction systems. Experiments up to 6000 h duration and in cells of up to 250 cm² membrane area show the potential for industrial application.     

聚乙烯辐照接枝体系中添加金属盐对接技率的影响

采用辐照接枝的方法，在高密度聚乙烯(HDPE)上接枝丙烯酸(AA)和对苯乙烯磺酸钠(SSS)，从而削备出了一种含羧酸基团和磺酸基团的阳离子交换膜。详细研究了接枝体系中引入添加剂醋酸钠或氯化钠对接枝率的变化规律．实验表明，在预辐照接枝和共辐照接枝中，当AA接技PE或AA与SSS共同接枝PE时，强碱弱酸盐醋酸钠通过pH效应同离子效应对接枝率呈现复杂的影响，而中性盐氯化钠经离子对效应显著提高接枝率。     

人工神经网络理论及其应用

简要介绍了人工神经网络的发展过程和基本理论，从神经网络具有自学习功能、联想存储功能和高速寻找优化解的能力三个方面论述了其特点和优越性，详细阐述了在模式识别、信号处理、自动控制、人工智能、自适应的人机接口、优化计算、通信以及其它方面的应用，探讨和分析了其发展前景。     

液态金属离子源发射尖的制备工艺与技术

发射尖是液态金属离子源(LMIS)的关键部件之一，其性能的优劣直接影响到整个离子源的工作稳定性。通过对系统软件和硬件的设计，开发了一套发射尖自动腐蚀装置，该装置可以对发射尖腐蚀过程中的速度和深度以及腐蚀电压进行控制，实现发射尖腐蚀工艺的重复性、可靠性，从而为液态金属离子源以及聚焦离子束系统的研制、开发提供了一个有效的辅助工具。     

灰色信息及其运算研究

本文提出了全真信息、信息的亲善性等概念,讨论了信息的有关性质及运算的关系,得到了信息的运算与普通集合运算之间存在着差异的结论,说明了引起该差异的原因.同时,以认知模式为基础,定义了信息函数,并得到了有关的命题及运算.