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61.
Anne-Cathrine S. Vogt Tasneem Arsiwala Mona Mohsen Monique Vogel Vania Manolova Martin F. Bachmann 《International journal of molecular sciences》2021,22(9)
Iron is a critical metal for several vital biological processes. Most of the body’s iron is bound to hemoglobin in erythrocytes. Iron from senescent red blood cells is recycled by macrophages in the spleen, liver and bone marrow. Dietary iron is taken up by the divalent metal transporter 1 (DMT1) in enterocytes and transported to portal blood via ferroportin (FPN), where it is bound to transferrin and taken up by hepatocytes, macrophages and bone marrow cells via transferrin receptor 1 (TfR1). While most of the physiologically active iron is bound hemoglobin, the major storage of most iron occurs in the liver in a ferritin-bound fashion. In response to an increased iron load, hepatocytes secrete the peptide hormone hepcidin, which binds to and induces internalization and degradation of the iron transporter FPN, thus controlling the amount of iron released from the cells into the blood. This review summarizes the key mechanisms and players involved in cellular and systemic iron regulation. 相似文献
62.
Yangyang Xu Zhaofu Ding Haibin Zhu Yijun Zhang Stephan Knopf Pu Xiao Jacques Lalevée 《大分子材料与工程》2021,306(3):2000720
The introduction of metallic fillers to polymers via the photopolymerization approach can endow the composite materials with some unique properties, but the relevant research is still scarce due to the issue of light penetration and inner filter effect. Herein, for the first time the fabrication of photocomposites based on fine iron powder (i.e., a typical kind of metallic filler) is reported in this work. The free radical polymerization of two different acrylate monomers, poly(ethylene glycol) diacrylate and trimethylolpropane triacrylate, is performed in the presence of iron filler under mild conditions (i.e., light emitting diode (LED)@405 nm irradiation at room temperature under air). And the real-time Fourier transform infrared spectroscopy reveals remarkable photopolymerization kinetics of acrylates with high final conversions and fast polymerization rates despite the increasing contents of iron filler in the composites. Interestingly, the 3D printing technique is applied to the iron filler-based composites to produce tridimensional patterns with excellent spatial resolution. This work not only paves the way for the investigation of photocomposites based on metallic fillers through photochemical methods, but also broadens the potential application prospects. 相似文献
63.
Zewen Chen Zhenhua Wang Boxiang Wang Juntang Yuan Lei Huang Zengbin Yin 《International Journal of Applied Ceramic Technology》2021,18(6):2010-2019
In this study, WC-8Co cemented carbides were prepared by spark plasma sintering. When the samples sintered at 1300℃ were cooled to room temperature, the samples were sintered multiple times at 1250℃. The changes in microstructure and mechanical properties of WC-8Co cemented carbides prepared by multiple spark plasma sintering were studied. The hardness of cemented carbides increased in the first two sintering, reaching 16.5 GPa. However, the hardness decreased seriously in the last two sintering. The attenuation rates of hardness were 6.2% and 2.5% due to the abnormal coarse grains. Furthermore, the crack path along the grain boundary was almost straight, causing a decrease in the indentation fracture toughness of cemented carbides. Additionally, the grains of cemented carbides were abnormally coarsened, and the morphologies of grains became unstable due to multiple sintering. 相似文献
64.
The physical metallurgy underlying the development of cast microstructures in abrasion resistant high chromium cast irons, and their structural modification by thermal treatments is relatively complex. Structural characterisation via electron microscopy therefore has a key role to play in furthering our understanding of the phase transformations that control the microstructures and hence the service performances of these irons as wear parts. This paper shows how both scanning and especially transmission electron microscopy can provide valuable information on the nature of eutectic and secondary carbides and on the matrix structures in these irons. Particular attention is given to current characterisation research on conventionally cast 30%Cr irons that are used for applications involving corrosive wear e.g. slurry pumps and on a semi-solid cast 27%Cr iron that has a potential for applications in industry. 相似文献
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V.V. Pani? V.M. Jovanovi? M.W. Barsoum A.B. Dekanski 《Surface & coatings technology》2007,202(2):319-324
Electroactive oxide coatings on titanium, known in industrial chlorine production as dimensionally stable anodes (DSA), are of limited service life owing to the dissolution of active oxide, but also due to low corrosion stability of titanium, at high anodic potentials and elevated temperatures. In order to improve the anode stability, ternary carbide, Ti3SiC2, could be a promising material for the coating support, since chemical corrosion stability of Ti3SiC2 is significantly higher if compared to Ti. In this work, the possibility of the sol-gel preparation of RuO2-TiO2 coating on Ti3SiC2 is investigated and comparison of the basic characteristics of sol-gel processed oxide coating, Ru0.5Ti0.5O2, applied onto Ti3SiC2 and Ti, is reported. Microscopic investigation of the coating surface showed that considerably less cracked coating is formed onto the Ti3SiC2 support. Slightly higher voltammetric currents are registered for Ti3SiC2-supported coating in H2SO4 and NaCl solution. The activity for chlorine evolution is higher, while the currents of oxygen evolution reaction are lower for Ru0.5Ti0.5O2/Ti3SiC2 anode in comparison to Ru0.5Ti0.5O2/Ti anode. Even though these preliminary results on the basic electrochemical properties of Ru0.5Ti0.5O2/Ti3SiC2 anode and chemical stability of Ti3SiC2 are promising, the accelerated stability test in NaCl solution showed that coated Ti3SiC2 is not anodically stable and lasts considerably shorter than Ru0.5Ti0.5O2/Ti anode prepared and tested under the same conditions. 相似文献
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69.
采用炉前包冲内冲废钢与孕育相结合的方法,研究了炉前包内冲废钢对灰铸铁组织和强度的影响。结果表明:冲废钢可以增加灰铸铁中初生奥氏体的数量,改变初生奥氏体枝晶的分布形态,强化灰铸铁孕育效果,有利于提高灰铸铁的强度。 相似文献
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