Synthesis and characterisation of alumina pillared Texas montmorillonite and determination of the effective Keggin ion charge

Controlled calcination of Texas montmorillonite has allowed production of a range of materials of cation exchange capacity from 70 mequiv./100 g dry clay to virtually zero. Pillaring of these with Chlorhydrol precursor solution has then provided a family of materials of pillar density ranging from about one per six unit cells to zero. The analytical technique based on isomorphous metal dilution (IMD) that follows pillaring is validated. The results provide a consistent value for the precursor (Keggin) ion charge, in the conditions normally used, of 3.15±0.10 rather than the formal value of 7. An approach to the attainment of pillar densities consistent with the introduction of shape/size selectivity on pillared layered materials is outlined.     

高收缩共聚酯合成性能与成纤性能研究

通过共聚酯PEIT(间苯二甲酸、对苯二甲酸、乙二醇共聚物)的合成及其全拉伸丝(FDY)纺丝的成功实验,研究了高收缩PEIT共聚物合成工艺中共聚组分间苯二甲酸(IPA)的摩尔百分数对共聚酯PEIT的玻璃化温度、熔点的影响,探讨了该PEIT共聚物的结晶性能及其纺丝工艺条件对高收缩纤维性能的影响。     

细胞分裂素6─BA合成新方法的研究

用医药工业的副产物乙酰基次黄嘌呤（Ⅰ）在弱酸条件下水解，生成次黄嘌呤（Ⅱ），经三氟氧磷在吡啶溶液中缩合，生成６－吡啶盐中间体（Ⅲ），再与苄胺反应，制得高效植物细胞分裂素６－ＢＡ（Ⅳ）。     

Experiences with Mathematical Modeling of Electro- Boost in Glass Furnaces

The goal of the latest strategy in glass companies is to decrease the cost of production while maintaining or increasing the glass quality. One of the perspective ways is to install the electric boosting into the existing furnace or to build the new furnace including the electric boosting. This strategy may be surprising as electric energy is generally more expensive than gas or oil （considering the cost per unit energy） but because of efficiency of use （ direct glass - melt heating by Joulean heat） it is inevitably cost effective. The use of the CFD modeling capability for electro - boost designing is presented in this contribution. The Glass Service Glass Furnace Model （ GS - GFM ） is used for investigating the optimal electrode arrangement and phasing, and moreover, for increasing the glass quality during the electro - boost applying.     

乙烯基-β-紫罗兰醇的合成

以氯乙烯和金属镁为原料,反应制得格氏试剂乙烯基氯化镁;再与β-紫罗兰酮发生加成反应得到合成维生素A的重要中间体乙烯基-β-紫罗兰醇。通过对反应条件和工艺的研究和优化,确定了最佳工艺条件为：金属镁与β-紫罗兰酮的摩尔比为1.3∶1.0,滴加β-紫罗兰酮的温度为0~5℃,在反应温度20~25℃时继续反应3~4h,得到乙烯基-β-紫罗兰醇的收率为98.0%,气相色谱（GC）分析含量为92.5%。该工艺条件得到了实验室放大的验证。     

过硼酸钠在有机合成中的应用

过硼酸钠（ＳＰＢ）是一种安全、稳定、方便、价廉的理想氧化剂，本文综述了它对各类有机化合物的氧化反应。     

二氯喹啉酸氧化工艺探讨

本文提出了二氯喹啉酸氧化工艺的最佳条件。结果表明该法具有反应条件温和，反应时间短，操作成本低，废不减少和收率高等优点。     

2—氨基—4—甲氧基—6—甲基均三嗪的合成

着重介绍了2-氨基-4-甲氧基-6-甲基均三嗪的合成方法。     

石墨化炉的供电特点及发展趋势

通过对石墨化炉的特点及其供电方面的有关问题的分析，论述了石墨化炉供电的特点及其发展的趋势，并对石墨化炉在交、直流电源供电方面提出了看法，以不断提高石墨化炉供电的设计水平．