四川盆地涪陵地区龙马溪组页岩横向各向同性地应力测井评价方法

页岩由于矿物的定向排列等因素呈现出各向异性,基于各向同性模型的地应力计算方法已不适用。综合测井、岩心实验、压裂施工等数据建立涪陵地区龙马溪组页岩横向各向同性地应力测井评价方法,主要包括：建立垂向有效压力与横波速度关系模板,预测地层压力;利用通过岩石物理建模的方法计算求取目的层的Biot系数;采用速度回归拟合的方法求取页岩横向各向同性介质6个刚度系数,计算横向、垂向杨氏模量及泊松比。应用结果表明横向各向同性模型能更好地反映实际地层情况。     

Analysis for surface coke deposition in used Mo-Co/γ-Al2O3 catalyst for diesel hydrodesulfurization

The coked Mo-Co/γ-Al₂O₃ catalysts were Soxhlet extracted with the solvent of tetrahydrofuran. Experimental techniques like FT-IR, GC-MS, XPS, H₂-TPR, BET, etc. were applied for the characterization of coke and catalysts to make a comparison of their physical properties. The results showed that the active components of the catalyst were slightly less after the reaction. The specific surface area and the pore volume had recovered to some degree. These results indicated that the main cause of deactivation of Mo-Co/γ-Al₂O₃ catalysts is carbon deposit. The principal components of the soluble carbon deposit on Mo-Co/γ-Al₂O₃ catalysts were alkyl aromatics with 1–4 rings and C₁₉–C₂₉ long-chain alkane compounds.     

燃用石油焦和煤添加脱硫剂循环流化床锅炉热效率计算

论述了循环流化床锅炉燃用石油焦和煤添加石灰石时对锅炉热效率计算的影响．通过分析循环流化床锅炉燃用石油焦和煤混合燃料添加脱硫剂时的物料平衡和灰平衡。得出采用国标GB10184-88《电站锅炉性能试验规程》计算锅炉热效率时，要对热量、烟气量和灰量进行修正。结合一台220t／h CFB锅炉实例，计算出实际测试工况下的热效率为89．5％。     

焦炭流化床燃烧条件下氧化亚氮生成过程的实验研究

在小型流化床实验台上对一种无烟煤焦炭燃烧过程中氧化亚氮的生成途径进行了实验研究,实验结果表明,在焦炭燃烧过程中HCN的氧化反应是焦炭氮向N2O转化的一条途径。同时,NO与焦炭表面的多相反应也是N2O的一条生成途径。HCN的析出是焦炭燃烧过程中进一步脱挥发份的结果,当焦炭脱挥发份过程结束后,N2O来源于NO和焦炭表面的气固多相反应。     

高硫石油焦在循环流化床锅炉中燃烧应用

进口中东原油炼化的副产品高硫石油焦的出路是石化企业的一个问题。详细地介绍了高硫石油焦作为燃料的应用现状,认为循环流化床锅炉是最佳选择之一。     

Elasto-Thermodiffusive Response in a Spherically Isotropic Hollow Sphere

The present work deals with the investigation of elasto-thermo diffusion interactions inside a spherically isotropic hollow sphere in the context of linear theory of generalized thermoelastic diffusion based on Green and Lindsay theory. The inner and outer boundaries of the body are free from stresses and are subjected to a time-dependent thermal shock and also the chemical shock. Laplace transform techniques are used to write the basic equations in the form of a vector matrix differential equations, which is then solved by the eigenvalue approach. The inversion of the transformed solution is carried out by applying the method of Bellman. The stress, temperature, mass concentration and chemical potential are computed and presented graphically. A comparative study of diffusive medium and thermoelastic medium is carried out, and it was seen that the effect of diffusion is significant on the stresses. A comparison of spherically isotropic body with isotropic body has also been presented, and a significant difference is observed.     

溶剂脱酚装置处理焦化废水的应用

溶剂脱酚法是一种有效的废水脱酚方法.采用溶剂脱酚法处理焦化废水,对后续废水处理装置具有很好的预处理效果.溶剂脱酚法能够有效回收废水中的酚,不但具有显著的环境效益,而且能产生一定的经济效益.针对采用溶剂脱酚装置处理焦化废水的效果和运行状况进行了阐述,描述了溶剂脱酚装置的工艺流程和运行参数.实践表明:溶剂脱酚装置是处理焦化废水中含酚的可行方法,将溶剂脱酚装置作为焦化废水处理的一道工序具有良好的推广价值.     

干熄炉料钟布料焦炭粒度分布的研究

对于干熄焦工艺,为了改善焦炭在干熄炉径向方向上的粒度偏析,采用料钟进行布料。采用实验和理论模拟相结合的分析方法,对布料焦炭在干熄炉预存段粒度偏析机理进行了研究。实验制作了冷态三维半圆料钟布料模型,考察了不同形状的料钟和不同的料线深度对焦炭粒度在干熄炉半径方向上分布的影响。所采用的理论模拟数学模型针对多尺度焦炭颗粒情况,用极少的参数来模拟半径平均尺度分布和每一种颗粒的半径堆积分布。研究结果表明,实验数据和数值分析结果吻合较好,相互验证了实验和理论模拟的正确性与可靠性。