阳离子交换树脂催化合成十三碳二元酸二乙酯

以强酸性阳离子交换树脂为催化剂,十三碳二元酸与乙醇为原料合成十三碳二元酸二乙酯,考察了影响反应的因素。结果表明:醇酸摩尔比为4∶1,催化剂用量为酸质量的2%,在3分子筛脱水的情况下反应7 h,酯化率达98.4%,并且催化剂可重复使用3次。     

Boronic acid-functionalized nanoparticles: synthesis by microemulsion polymerization and application as a re-usable optical nanosensor for carbohydrates

Translucent boronic acid-carrying nanolatexes are prepared by copolymerisation of vinylbenzyl chloride in microemulsion followed by post functionalisation with 3-aminophenylboronic acid. The diol binding capacity and selectivity of the phenylboronic acid remain unchanged after anchoring to polymer nanoparticles (16 nm diameter, 0.22 mmol/g). The binding of a catechol dye, Alizarin Red S (ARS), to the boronic acid-carrying nanoparticles affords a colored, stable, nanolatex which is used for the selective visual detection of fructose in a competitive assay. The binding of fructose at pH 8.2 is readily evidenced by a color change and monitored by UV/Vis spectroscopy. The nanosensor can be regenerated in acidic medium. The entrapment of the nanolatex in a dialysis cell provides a re-usable support for binding and optical detection.     

三氯异氰尿酸生产技术研究

对三氯异氰尿酸合成反应过程中的主要工艺参数进行分析和实验研究,并成功地开发出了连续法生产三氯异氰尿酸的新工艺,该工艺和传统工艺相比,具有生产安全、高效、节能的特点。     

Influence of Phenolic acids on microbial populations in the rhizosphere of cucumber

Experiments were conducted to determine whether changes in soil microbial populations that occur in response to additions of certain allelopathic phenolic acids to bulk soil also occur in the rhizosphere. Cucumber seedlings were transplanted into cups containing a nutrient-enriched mixture of Portsmouth B₁, soil and sand and were watered five times (once every 48 hr) with aqueous solutions of ferulic,p-coumaric, or vanillic acid (each at 0, 0.25, or 0.50ol/g soil material). Nutrient solution was applied on alternate days. Leaf growth was suppressed by up to 42% by phenolic acids, but changes in root growth varied with the compound and concentration in solution. Significant increases (over 600% relative to controls) in populations of fast-growing bacteria in the rhizosphere were detected after two but not after five treatments, and increases (400% relative to controls) in numbers of fungal propagules were detected after five treatments. Such increases suggested that chronic exposure to a phenolic acid might resuit in high populations of rhizosphere microorganisms that could metabolize the compounds and thus alter observable responses by the plant. To test this, plants were watered repeatedly with a low-concentration solution of ferulic acid (chronic treatments; 0.0 or 0.1mol/g soil material in one experiment, 0.000 or 0.025imol/g soil material in a second) and then once with a highconcentration solution (acute treatment; 0.0, 0.5, or 1.0mol/g soil material in the first experiment; 0.000, 0.125, or 0.250mol/g soil material in the second).Paper No. 12385 of the Journal Series of the North Carolina Agricultural Research Service, Raleigh, North Carolina. The use of trade names in this publication does not imply endorsement by the North Carolina Agricultural Research Service or the United States Department of Agriculture of the products named, nor criticism of similar ones not mentioned. Acute treatments and some chronic treatments suppressed leaf growth, but results were inconsistent for root growth. Acute treatments increased numbers of several types of bacteria in the rhizosphere but had inconsistent effects on fungi. Chronic treatments had no effect on numbers of bacteria or fungal propagules in the rhizosphere. Furthermore, chronic treatments did not alter responses of plants or microbial populations to the subsequent acute treatment. Results demonstrated that phenolic acids in soil, which must pass through the rhizosphere before interaction with plant roots can occur, alter the microbial ecology of the rhizosphere. However, microbially mediated acclimation of plants to relatively high concentrations of ferulic acid was not observed.     

硝硫混酸与Ag、Cu反应的动力学

用失重法探讨了硝硫混酸此例、浸出温度和时间等因素对银的溶解和铜的钝化的影响。结果表明:在一定的[HNO_3]范周内,较高温度时,银的溶解符合一级反应规律;求得银的溶解量与时间、HNO_3起始浓度等的关系式和相应的反应活化能;铜在此条件时是钝化的。本实验再一次证实了银的溶解和铜的钝化机理的正确性,也为银、铜的分离提供了实验依据。     

易门铜业公司18kt／a粗铜及硫酸车间的技改工程

介绍了易门铜冶炼厂烟气制酸系统的技术改造工程.从工艺流程、设备复核、工艺参数、设备配置等方面阐述了技改的过程.     

Kelvin Probe measurements of polymer coated gold substrates: Mechanism studies

The origin of work-function changes induced in polymer/metal structures (polyacrylic acid (PAA), ammonium and sodium polyacrylate) upon ammonia exposure is studied. To understand and explain the mechanism systematic measurements of uncoated and polymer coated metals are performed in Kelvin Probe (KP) setups. Additional data have been acquired through gravimetric and electrochemical experiments (cyclic voltammetry (CV)). The results obtained confirm that the field effect sensitive processes are taking place at the metal/polymer interface and allow their modelling. The intrinsic sensitivity of metallic samples upon ammonia exposure is influenced by the presence of coating polymers, by their ability to sorb water and to keep the metal surface wet or dry.     

PTA生产溶剂智能优化控制软件的开发与应用

在.Net开发环境下,利用C++语言开发PTA生产溶剂智能优化控制软件,并介绍了软件包的设计原理和基本框架.利用广义回归神经网络建立PTA过程模型,再采用粒子群智能优化法优化过程操作参数,软件系统操作简单、用户界面友好.该软件在精对苯二甲酸(PTA)生产装置的实用效果良好,降低了醋酸和蒸汽的消耗,并为优化各工艺操作条件提供了指导,产生了一定的经济效益,具有较好的推广价值.     

江河源区高寒嵩草草甸土壤氨基酸成分和含量特征分析

通过高效液相色谱技术分析了青海省果洛州达日县窝赛乡原生嵩草草甸、严重退化草地及人工草地三类植被土壤中各种氨基酸成分及含量。结果表明:(1)三种类型土壤中都检测出19种常见氨基酸:精氨酸、天冬氨酸、丝氨酸、谷氨酸、苏氨酸、丙氨酸、甘氨酸、氨基丁酸、脯氨酸、蛋氨酸、缬氨酸、苯丙氨酸、异亮氨酸、亮氨酸、胱氨酸、组氨酸、鸟氨酸、赖氨酸、酪氨酸;(2)测定结果表明原生嵩草草甸土壤的氨基酸总量显著高于人工恢复重建草地和严重退化土壤氨基酸,而后两者之间差异不显著。原生高寒草地的土壤(6316.28μgg-1)严重退化草地土壤(2977.10μgg-1)人工恢复重建草地土壤(2975.90μgg-1)。(3)原生高寒草地土壤氨基酸总体呈现下降趋势:5月氨基酸含量最高,随后6月7月的显著下降,8月稍微有所回升,9月氨基酸含量到达最低;严重退化草地土壤与人工恢复重建草地土壤氨基酸含量季节变化相似,氨基酸总量在6月份到达最高点,随后7月8月显著下降,9月份稍微有所回升。