APPLICATION OF MICROBIAL OXIDATION OF PYRITE

Thiobacillus ferrooxidans can be self-cultured in the acidic mine water after nourishing treatment.The mine water containing Thiobacillus ferrooxidans has been used in the heap leaching of pyritic-coal-bearing kaolin ore.The kaolin ore has been purified through the oxidation leaching of pyrite to remove the sulfur and iron impurities.     

聚丙烯酸钠-高岭土复合高吸水性树脂的制备及结构表征

采用静态水溶液法制备了高填充比例的聚丙烯酸钠-高岭土复合吸水性树脂(简称复合树脂),考察了聚合温度、丙烯酸单体的含量、丙烯酸中和度、引发剂和交联剂的用量、高岭土含量对复合树脂吸水率的影响,并用傅里叶变换红外光谱、扫描电镜、热重和示差扫描量热法对复合树脂的微观结构进行了表征。实验结果表明,复合树脂的最佳制备条件为:聚合温度70℃,丙烯酸单体的质量分数30%,丙烯酸中和度70%,引发剂占单体的质量分数0.1%,交联剂占单体的质量分数0.08%,高岭土占单体的质量分数50%;在此条件下制备的复合树脂对蒸馏水的吸水率为834 g/g,对质量分数0.9%的NaC l溶液的吸水率为81 g/g。傅里叶变换红外光谱和扫描电镜表征结果表明,复合树脂是一种典型的海-岛结构,丙烯酸和高岭土之间存在接枝聚合反应。     

Electrochemical treatment of anionic surfactants in synthetic wastewater with three-dimensional electrodes

The electrochemical oxidation of anionic surfactants (sodium dodecyl benzene sulfonate, DBS) contained in simulated wastewater treated by three-dimensional electrode system with combined modified kaolin served as packed bed particle electrodes and Ti/Co/SnO(2)-Sb(2)O(3) anode was studied, the chemical oxygen demand (COD) removal of pollutants in the solutions was also investigated. The results showed that the three-dimensional electrodes in combined process could effectively decompose anionic surfactants. The COD removal efficiency can reach 86%, much higher than that of Ti/Co/SnO(2)-Sb(2)O(3) electrodes used singly or modified kaolin employed singly (graphite as anode and cathode) on the same condition of pH 3 and 38.1 mA/cm(2) current density. The current efficiency and kinetic constant were calculated and energy consumption was studied. At the same time the influence of pH and current density on COD removal efficiency with combined three-dimensional electrodes was also investigated, respectively. The optimal initial pH value of degradation is 3 (acid condition), and a minor COD removal increase follows higher current density.     

贵州某硬质高岭土开发利用研究探讨

高岭土由于具有良好的物理化学性能，用途十分广泛，贵州省高岭土矿大部分为含碳硬质高岭土矿，不能直接利用，开发利用贵州硬质高岭土资源，主要在于脱除矿物中铁，碳及锰等，提高白度及综合性能。通过试验研究，贵州硬质高岭土矿适于采用重选－焙烧－化学漂白除铁的工艺流程来加工处理，可以得到不同级别的高岭土产品。     

高岭土选矿工艺研究

广东省高岭土资源非常丰富，本文着重介绍了对四会，成名，靖远，湛江等地高岭土矿所仨的选矿试验研究以及利用高岭土矿石生产刀刀级与刮刀级造泖布土的工艺。     

造纸高岭土增白工艺研究

造纸高岭土要求具备高白度、高纯度及低黏度等良好特性，然而目前我国高岭土增白的研究多针对煤系硬质高岭土，而较少针对软质高岭土。作者选取综合质量较好但白度仍待提高的茂名软质高岭土进行增白研究，通过研磨、连二亚硫酸盐法、酸处理和煅烧等方法，可得到白度〉92％的高岭土精粉。     

Catalytic study for methanol aromatization over hierarchical ZSM-5 zeolite synthesized by kaolin

Hierarchical and conventional ZSM-5 zeolites were synthesized through steam-assisted crystallization approach using acid-treatment kaolin clay as the silica and aluminium sources. The samples were characterized by XRD, SEM, NH₃-TPD, N₂-physisorption and TG techniques. The results showed that hierarchical ZSM-5 had rich mesopores and bigger specific surface. In conversion of methanol to aromatics, hierarchical and conventional ZSM-5 zeolites showed higher selectivity for aromatics compared with commercial ZSM-5. Under the conditions of 450 °C, 0.15 MPa, the synthesized hierarchical ZSM-5 showed longest lifetime of 380 h, which was 2 and 6 times than those of conventional and commercial ZSM-5, respectively.     

高岭土合成Y型分子筛研究进展

综述高岭土合成Y型分子筛研究进展,分别从原位合成、纳米分子筛、高硅分子筛和其他合成方法进行评述,并分析各种合成方法的优缺点。原位合成Y型分子筛是合成性质优良Y型分子筛的重要方法,相关研究不断深化成熟,以此方法合成特殊性能的Y型分子筛成功应用于催化裂化催化剂。合成具有特殊形态和结构组成的分子筛如小晶粒Y型分子筛、高硅Y型分子筛是近年来的研究热点。分别从优化合成条件、加入分散剂和使用微波加热法介绍小晶粒Y型分子筛合成研究进展。高硅Y型分子筛的合成主要分为直接合成和二次改性方法,直接合成法反应条件苛刻,存在原料浪费等问题;二次改性方法工艺流程长,易导致合成成本增加。重点讨论具有特种性能的特种Y型分子筛合成研究进展,对离子液体合成Y型分子筛、干胶转化合成Y型分子筛和高岭土合成复合分子筛等新方法进行综述,并结合其他先进的分子筛合成方法,指出Y型分子筛合成的研究方向和前景。     

在X-射线衍射中与白云母特征峰重合的高岭土矿物组分测算

针对高岭土矿物在X-射线衍射分析过程中,组成矿物之间存在特征峰重合无法定量各组分含量的情形。该测算通过X-射线物相定量分析、化学成分分析、氧化物在矿物中所占比例等参数进行换算,计算出了高岭土各组成矿物的含量。     

光稳定剂对水工闸门用PE-HD/高岭土复合材料性能的影响

采用共混造粒制备含有不同光稳定剂的水工闸门用高密度聚乙烯(PE-HD)/高岭土复合材料,讨论和研究光老化前后复合材料的力学性能变化规律.通过偏光显微镜观察复合材料试样表面形貌、采用傅里叶变换红外光谱和核磁共振氢谱对表面析出物进行分析,讨论比较不同受阻胺光稳定剂的析出原因及抗光老化作用差异.结果表明,添加光稳定剂2020...