从铅阳极泥处理后的渣料中综合回收有价金属的生产实践

叙述了从铅阳极泥回收金银后的渣料中综合回收有价金属的生产实践。根据渣料性质，将火法和湿法工艺相互结合，使渣料中的锑、铋、金、银、铅、铜得以较彻底的分离和回收。     

含氮杂环季铵盐缓蚀剂在CO2-3%NaCl溶液体系中的电化学行为

为控制CO2腐蚀，合成了含氮杂环季铵盐缓蚀剂9912-1，通过电化学实验，研究了该缓蚀剂在CO2-3％NaCl-H2O体系中对碳钢于25℃和90℃下的缓蚀行为。实验结果与挂片失重法测试的结果基本一致。低温下缓蚀效果优于高温下的缓蚀效果。而且该缓蚀剂与硫脲有很好的协同效应。Tafel曲线表明，该缓蚀过程是以控制阴极腐蚀为主，并对其缓蚀机理进行了初步探讨。     

大尺寸氟化铅晶体的生长

描述了不用高真空条件，在通常的Ｂｒｉｄｇｍａｎ－Ｓｔｏｃｋｂａｒｇｅｒ炉中，用高温下的反应方法，消除了原料及生长炉内残存的Ｏ＾２－及ＯＨ＾－，生长出优质，大尺寸的β－ＰｂＦ２晶体。在晶体生长时，出现的主要问题是在晶体中的针状结构及开裂，但可通过控制条件来解决。     

Experimental and mathematical studies of natural convection for solid-salt dissolution in water

The phenomena of natural convection caused by a concentration gradient usually creates currents as a result of buoyancy forces. These forces are formed from the combined effect of a fluid density gradient and the body force (gravitational force). The above phenomenon was studied experimentally in a circular glass column of 0.08 m diameter and 1 m length. This column was erected vertically and filled with distilled water with a salt bag placed on top of it and partially immersed in water. The dissolution mechanism was then modelled and a finite difference method was used to solve the formulated equations by using the implicit scheme of MacCormack (Anderson et al., 1984). The experimental results and the numerical predictions are represented graphically and give compatible agreement.     

Electrochemical Investigation on the Formation of Dy-Fe Alloy in Molten Chlorides

ＥｌｅｃｔｒｏｃｈｅｍｉｃａｌＩｎｖｅｓｔｉｇａｔｉｏｎｏｎｔｈｅＦｏｒｍａｔｉｏｎｏｆＤｙＦｅＡｌｏｙｉｎＭｏｌｔｅｎＣｈｌｏｒｉｄｅｓＬｉｕＧｕａｎｋｕｎ（刘冠昆），ＴｏｎｇＹｅｘｉａｎｇ（童叶翔），ＨｏｎｇＨｕｉｃｈａｎ（洪惠婵），Ｙａｎｇ...     

Hydrothermal Synthesis of Acicular Lead Titanate Fine Powders

A pure, acicular lead titanate (PbTiO₃) fine powder with a white color has been prepared by hydrothermal synthesis. It is a new phase of PbTiO₃ with I 4 symmetry, cell parameters of a = 12.358 Å and b = 14.541 Å, and a density of 6.80 g.cm⁻³. The influences of pH (12.5 to 14.4), Pb/Ti ratio (1.0 to 1.6) in the feedstock, reaction temperature (130° to 230°C), time (0.25 to 4 h), starting materials, and additives on the formation of acicular PbTiO₃ under hydrothermal conditions have been investigated. The acicular PbTiO₃ with I 4 symmetry, referred to as the PX phase, can be converted to the perovskite-type (PE phase) of PbTiO₃ at about 605°C while its acicular morphology is essentially unchanged. The preferable conditions for preparing pure acicular PX-phase PbTiO₃ are that the pH is 13.0 to 14.0, Pb/Ti ratio is >1.3, reaction temperature is 170° to 200°C, time is 0.5 to 1.0 h, titanium butoxide (Ti[O(CH₂)₃CH₃]₄) is the starting material, and poly(vinyl alcohol) is an additive. The acicular grain of the PX phase is usually less than 100 nm in diameter and more than 1000 nm in length.     

Investigation of the Interaction of Sodium Chloride and Two Amino Sulfonic Acids,HEPES and MOPSO,by EMF Measurements

Ionic interactions in the two systems NaCl-HEPES (N-2-hydroxyethylpiperazine-N′-2-ethanesulfonic acid) and NaCl-MOPSO (3-(N-Morpholino)-2-hydroxypropanesulfonic acid) have been studied in terms of their mutual influence on the respective activity coefficients of each component. Activity coefficients for each component of the two systems and for corresponding buffers are calculated from emf measurements of solutions containing NaCl, the aminosulfonic acid, and its conjugate base in a NalSE/solution/AgCl-Ag cell at 5, 15, 25, and 37 °C.     

高压水射流粉碎原盐

高压水射流粉碎技术是近年发展起来的一项新型粉碎技术。文中介绍了水射流粉碎机理和新研制的后混合靶式水射流粉碎装置 ,并通过原盐粉碎实验证明 ,水射流粉碎具有效率高、工艺简单、产品粒度可调等特点 ,是一项具有良好发展前景的粉碎技术。     

醋酸铅在离子液体中溶解机理的研究

通过[bmim]Cl和Pb(OAc)2混合反应后析出PbCl2沉淀,制备得到溶解有醋酸铅的离子液体[bmim]OAc。实验发现,即使使用过量的醋酸铅,PbCl2仍然不能沉淀完全,这表明离子液体中的Pb2+离子并不是以游离形式存在的,而是以配位的形式存在,并且由离子液体包裹着。因此,醋酸铅在离子液体[bmim]OAc中的溶解度得到增加,平均溶解度达到1 1mmol/ml,最大溶解度达到3 0mmol/ml。     

交联型聚醚聚氨酯的表征、力学性能及其碱金属盐络合物的导电性能

采用三羟甲基丙烷（ＴＭＰ）作交联剂与聚乙二醇（ＰＥＯ－１５４０）和甲苯二异氰酸酯（ＴＤＩ）反应，得到了具有较好力学性能的交联型聚醚聚氨酯（ＰＥＵ），该聚合物与ＬｉＣｌＯ４的结合物具有较高的室温电导率（σ３０℃＝１．８７×１０￣（－４）Ｓ／ｃｍ）。采用全反射红外光谱（ＡＴＲ－ＩＲ）对聚合物的结构进行了表征。对聚合物的组成、不同ＴＤＩ类型及络合盐浓度对聚合物力学性能及其络合物电导率的影响进行了探讨。低度交联聚合物的络合物，其电导率与温度的关系符合建立在自由体积理论上的ＶＴＦ方程，表明络合物中离子的传导主要是在无定形区域进行，与自由体积有关。