全文获取类型
收费全文 | 6235篇 |
免费 | 752篇 |
国内免费 | 95篇 |
专业分类
电工技术 | 21篇 |
综合类 | 77篇 |
化学工业 | 2460篇 |
金属工艺 | 92篇 |
机械仪表 | 116篇 |
建筑科学 | 71篇 |
矿业工程 | 12篇 |
能源动力 | 88篇 |
轻工业 | 2491篇 |
水利工程 | 38篇 |
石油天然气 | 30篇 |
武器工业 | 4篇 |
无线电 | 212篇 |
一般工业技术 | 757篇 |
冶金工业 | 287篇 |
原子能技术 | 75篇 |
自动化技术 | 251篇 |
出版年
2024年 | 57篇 |
2023年 | 253篇 |
2022年 | 433篇 |
2021年 | 490篇 |
2020年 | 322篇 |
2019年 | 326篇 |
2018年 | 295篇 |
2017年 | 279篇 |
2016年 | 256篇 |
2015年 | 264篇 |
2014年 | 285篇 |
2013年 | 439篇 |
2012年 | 295篇 |
2011年 | 327篇 |
2010年 | 247篇 |
2009年 | 256篇 |
2008年 | 225篇 |
2007年 | 215篇 |
2006年 | 228篇 |
2005年 | 230篇 |
2004年 | 155篇 |
2003年 | 150篇 |
2002年 | 125篇 |
2001年 | 113篇 |
2000年 | 81篇 |
1999年 | 74篇 |
1998年 | 103篇 |
1997年 | 77篇 |
1996年 | 64篇 |
1995年 | 64篇 |
1994年 | 56篇 |
1993年 | 48篇 |
1992年 | 39篇 |
1991年 | 31篇 |
1990年 | 22篇 |
1989年 | 22篇 |
1988年 | 14篇 |
1987年 | 15篇 |
1986年 | 19篇 |
1985年 | 22篇 |
1984年 | 17篇 |
1983年 | 10篇 |
1982年 | 8篇 |
1981年 | 8篇 |
1980年 | 4篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1976年 | 2篇 |
1975年 | 2篇 |
1961年 | 2篇 |
排序方式: 共有7082条查询结果,搜索用时 15 毫秒
101.
Photonic Reactions Leading to Fluorescence in a Polymeric System Induced by the Photothermal Effect of Magnetite Nanoparticles Using a 780 nm Multiphoton Laser 下载免费PDF全文
Bum Chul Park Hee‐Dae Kim June Park Yu Jin Kim Young Keun Kim 《Small (Weinheim an der Bergstrasse, Germany)》2017,13(37)
Recently, polymer‐coated magnetite (Fe3O4) nanoparticles (NPs) are extensively studied for applications in therapeutics or diagnostics using photothermal effect. Therefore, it is essential to understand the interactions between Fe3O4 NPs and polymers when optical stimuli are applied. Herein, the photonic reactions of Fe3O4 NPs and polymer composites upon application of a 780 nm multiphoton laser are analyzed. The photonic reactions produce unique results including fluorescence from conformationally changed polymer and low‐temperature phase transformation of Fe3O4 NPs. Typically, π‐conjugated chains are formed, inducing fluorescence through a series of main and side‐chain cleavage reactions of polymers with the aliphatic chain. In addition, fluorescence is detected in the cellular system by photonic reactions between Fe3O4 NPs and biomolecules. After multiphoton laser irradiation, light emission is detected near the intracellular Fe3O4 NPs, and a stronger intensity is observed in large‐sized NPs. 相似文献
102.
A particle‐based moving interface method (PMIM) for modeling the large deformation of boundaries in soft matter systems 下载免费PDF全文
Louis Foucard Franck J. Vernerey 《International journal for numerical methods in engineering》2016,107(11):923-946
The mechanics of the interaction between a fluid and a soft interface undergoing large deformations appear in many places, such as in biological systems or industrial processes. We present an Eulerian approach that describes the mechanics of an interface and its interactions with a surrounding fluid via the so‐called Navier boundary condition. The interface is modeled as a curvilinear surface with arbitrary mechanical properties across which discontinuities in pressure and tangential fluid velocity can be accounted for using a modified version of the extended finite element method. The coupling between the interface and the fluid is enforced through the use of Lagrange multipliers. The tracking and evolution of the interface are then handled in a Lagrangian step with the grid‐based particle method. We show that this method is ideal to describe large membrane deformations and Navier boundary conditions on the interface with velocity/pressure discontinuities. The validity of the model is assessed by evaluating the numerical convergence for a axisymmetrical flow past a spherical capsule with various surface properties. We show the effect of slip length on the shear flow past a two‐dimensional capsule and simulate the compression of an elastic membrane lying on a viscous fluid substrate. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
103.
Cássia A. Glasser Marta M. D. C. Vila Júlio C. Pereira Marco V. Chaud José M. Oliveira Júnior Matthieu Tubino 《Drug development and industrial pharmacy》2016,42(12):1990-2000
The aqueous-core enclosed in lipid nanoballoons integrating multiple emulsions of the type water-in-oil-in-water mimic, at least in theory, the environment within viable cells, thus being suitable for housing hydrophilic protein entities such as bioactive proteins, peptides and bacteriophage particles. This study reports a complete physicochemical characterization of optimized biomimetic aqueous-core lipid nanoballoons housing hydrophilic (BSA) protein entities, evolved from a statistical 23×31 factorial design study (three variables at two levels and one variable at three levels) that was the subject of the first paper of a series of three, aiming at complete stabilization of the three-dimensional structure of protein entities attempted via housing the said molecular entities within biomimetic aqueous-core lipid nanoballoons integrating a multiple (W/O/W) emulsion. The statistical factorial design followed led to the production of an optimum W/O/W multiple emulsion possessing quite homogeneous particles with an average hydrodynamic size of (186.2?±?2.6) nm and average Zeta potential of (?36.5?±?0.9) mV, and exhibiting a polydispersity index of 0.206?±?0.014. Additionally, the results obtained for the diffusion coefficient of the lipid nanoballoons integrating the optimized W/O/W multiple emulsion were comparable and of the same order of magnitude (10?12 m2 s?1) as those published by other authors since, typically, diffusion coefficients for molecules range from 10?10 to 10?7 m2 s?1, but diffusion coefficients for nanoparticles are typically of the order of magnitude of 10?12 m2 s?1. 相似文献
104.
Controlling the molecular interactions through protein nanopores is crucial for effectively detecting single molecules. Here, the development of a hetero‐oligomeric nanopore derived from Nocardia farcinica porin AB (NfpAB) is discussed for single‐molecule sensing of biopolymers. Using single‐channel recording, the interaction of cyclic oligosaccharides such as cationic cyclodextrins (CDs) of different symmetries and charges with NfpAB is measured. Studies of the transport kinetics of CDs reveal asymmetric geometry and charge distribution of NfpAB. The applied potential promotes the attachment of the cationic CDs to the negatively charged pore surface due to electrostatic interaction. Further, the attached CDs are released from the pore by reversing the applied potential in time‐resolved blockages. Release of CDs from the pore depends on its charge, size, and magnitude of the applied potential. The kinetics of CD attachment and release is controlled by fine‐tuning the applied potential demonstrating the successful molecular transport across these nanopores. It is suggested that such controlled molecular interactions with protein nanopores using organic templates can be useful for several applications in nanopore technology and single‐molecule chemistry. 相似文献
105.
Dirk Obergfell Bahman Azarhoushang Andrés Fabián Lasagni 《Advanced Engineering Materials》2023,25(19):2300757
Due to its high corrosion resistance and mechanical properties, stainless steel is commonly used in various industrial applications. Although different types of stainless steel are similar in their chemical composition, they can differ significantly in their thermal diffusivity. This property is relevant in the ability of a material to conduct heat and thus, in laser processing. In this frame, this study compares the ablation efficiency and characteristics of polished stainless steel samples of the alloys AISI 304, AISI 420, and AISI 316Ti. They are irradiated with single ultrashort pulses having pulse durations between 250 fs and 10 ps as well as using GHz burst modii. The goal is to investigate the differences in both the ablation threshold and the ablation rate to improve the ablation efficiency. The results show that shorter pulse durations lead to a more efficient ablation process. On the other hand, GHz bursts are found to be, in general, less efficient. In addition, there is a significant difference in the surface morphology depending on the process parameters. The differences in the thermal diffusivity do not significantly influence the ablation threshold fluence but surface morphology and the ablation rate. 相似文献
106.
Avatars serve for humans immersed in virtual settings as the interface between real and virtual worlds. The avatar-creation process involves numerous choices, including choice of visual representation, and choices to imbue the character with personality. Here, we hypothesised that these choices are not independent, and that a cross-modal talk may occur between the different components of the avatar identity. Specifically, we investigated whether name properties may be affected by the visual aspect (human vs. non-human) of the avatar. We analyzed names structure of players characters from the popular massively multiplayer online role-playing game (MMORPG) World of Warcraft, which display both human and non-human avatars. We selected 1261 names of characters actively engaged in the in-game and out-game social networks. Analysis of the names revealed that female names presented more variability than male names, and contained systematically more vowels than male names. However, the strategy used to enrich the vowel composition of female names differed between human-like and non-human characters, suggesting that a lesser proximity with human regular appearance was compensated by an increase of “feminization” of the name. Altogether, our results suggest that a cross-modal compensation occurs between name and visual aspect in the creation of socially active avatars. 相似文献
107.
Social signal processing: Survey of an emerging domain 总被引:3,自引:1,他引:2
The ability to understand and manage social signals of a person we are communicating with is the core of social intelligence. Social intelligence is a facet of human intelligence that has been argued to be indispensable and perhaps the most important for success in life. This paper argues that next-generation computing needs to include the essence of social intelligence – the ability to recognize human social signals and social behaviours like turn taking, politeness, and disagreement – in order to become more effective and more efficient. Although each one of us understands the importance of social signals in everyday life situations, and in spite of recent advances in machine analysis of relevant behavioural cues like blinks, smiles, crossed arms, laughter, and similar, design and development of automated systems for social signal processing (SSP) are rather difficult. This paper surveys the past efforts in solving these problems by a computer, it summarizes the relevant findings in social psychology, and it proposes a set of recommendations for enabling the development of the next generation of socially aware computing. 相似文献
108.
Local and Global Interactions in an Evolutionary Resource Game 总被引:2,自引:0,他引:2
Conditions for the emergence of cooperation in a spatial common-pool resource game are studied. This combines in a unique
way local and global interactions. A fixed number of harvesters are located on a spatial grid. Harvesters choose among three
strategies: defection, cooperation, and enforcement. Individual payoffs are affected by both global factors, namely, aggregate
harvest and resource stock level, and local factors, such as the imposition of sanctions on neighbors by enforcers. The evolution
of strategies in the population is driven by social learning through imitation, based on local interaction or locally available
information. Numerous types of equilibria exist in these settings. An important new finding is that clusters of cooperators
and enforcers can survive among large groups of defectors. We discuss how the results contrast with the non-spatial, but otherwise
similar, game of Sethi and Somanathan (American Economic Review 86(4):766–789, 1996).
相似文献
109.
In general, peptides do not exhibit a well-defined conformational profile in solution. However, despite the experimental blurred picture associated with their structure, compelling spectroscopic evidence shows that peptides exhibit local order. The conformational profile of a peptide is the result of a balance between intramolecular interactions between different atoms of the molecule and intermolecular interactions between atoms of the molecule and the solvent. Accordingly, the conformational profile of a peptide will change upon the properties of the solvent it is soaked. To get insight into the balance between intra- and intermolecular interactions on the conformational preferences of the peptide backbone we have studied the conformational profile of the alanine dipeptide in diverse solvents using molecular dynamics as sampling technique. Solvents studied include chloroform, methanol, dimethyl sulfoxide, water and N-methylacetamide. Different treatments of the solvent have been studied in the present work including explicit solvent molecules, a generalized Born model and using the bulk dielectric constant of the solvent. The diverse calculations identify four major conformations with different populations in the diverse solvents: the C7eq only sampled in chloroform; the C5 or extended conformation; the polyproline (PII) conformation and the right-handed α-helix conformation (αR). The results of present calculations permit to analyze how the balance between intra- and intermolecular interactions explains the populations of the diverse conformations observed. 相似文献
110.
We present a multi-step computation method to implement the Ewald summation for long-range electrostatic interactions in molecular dynamic simulations on a multi-core machine. Our methodology is based on the OpenMP programming model. It partitions computations of real-space summation among threads so that the global force of a single particle cannot be modified by more than one thread simultaneously. It requires neither a private copy of the force array for each thread nor an inspector at runtime. Compared with some other methods that can parallelise reduction operations on a force-array, our method achieves relatively higher speedups and lower L2 cache miss and bus utilisation ratios. 相似文献